• Title/Summary/Keyword: chemical analysis

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Numerical Study of Chemical Performance of 30 tonf -class LRE Nozzle of KARI

  • Kang, Ki-Ha;Lee, Dae-Sung;Cho, Deok-Rae;Choi, H.S.;Choi, J.Y.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.448-451
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    • 2008
  • Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were used to rocket nozzle flow, those were coupled with the methods of computational fluid dynamics code. For a design of high temperature rocket nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be an efficient design tool for predicting maximum thermodynamic performance of the nozzle. Frozen fluid analysis presents the minimum performance of the nozzle because of no consideration for the energy recovery. On the other hand, the case of chemical-equilibrium analysis is able to forecast the maximum performance of the nozzle due to consideration for the energy recovery that is produced for the fast reaction velocity compared with velocity of moving fluid. In this study, using the chemical equilibrium flow analysis code that is combined the modified frozen-equilibrium and the chemical-equilibrium. In order to understand the thermochemical characteristic components and the accompanying energy recovery, shifting-equilibrium flow analysis was carried out for the 30 $ton_f$-class KARI liquid rocket engine nozzle together with frozen flow. The performance evaluation based on the 30 $ton_f$-class KARI LRE nozzle flow analyses will provide an understanding of the thermochemical process in the nozzle and performances of nozzle.

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Seismic Analysis of Chemical Pump Using Automatic Mesh Generation System (자동요소생성 시스템을 이용한 케미컬 펌프의 지진해석)

  • Jang, Hyun-Seok;Lee, Joon-Seong
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.24 no.6
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    • pp.685-690
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    • 2011
  • This paper describes a seismic analysis of chemical pump using automated mesh generation system. The use of an automated analysis system, involving FE codes together with CAD systems and FE pre- and post-processors, has provided an important step towards shortening the design process and structural optimization. The FE model, which is a FE mesh accompanied with the analysis condition, is automatically converted from the analysis model. The FE models are then automatically analyzed using the FE analysis code. This integrated FE simulation system is applied to an analysis of three-dimensional complex solid structures such as a chemical pump.

The Research on the Real-time Emergency Response Plan for the Company based on Consequence Analysis for Chemical Accidents (화학사고 발생 시 피해예측 모델과 연계된 사업장의 실시간 비상대응 체계에 관한 연구)

  • Jun Ho Ha;Chang Jun Lee
    • Journal of the Korean Society of Safety
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    • v.39 no.2
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    • pp.28-37
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    • 2024
  • The recent surge in the production and handling of hazardous materials in Korea necessitates developing and implementing robust emergency response plans. These plans are crucial in safeguarding the well-being of workers and residents in the event of an incident. The consequence analysis methodology outlined in the KOSHA guidelines provides a foundation for designing emergency response plans in the event of chemical accidents. However, the consequence analysis is evaluated based on assumed accident cases or worst-case scenarios. Consequently, the emergency response plan based on the consequence analysis may overestimate the damage area, complicating rescue efforts and unnecessarily increasing costs. More information and parameters become available after an accident, enabling more accurate consequence analysis. This implies that the results of consequence analysis based on this detailed information provide more realistic results than those based on assumed accidents. This study attempts to optimize the resource allocation and cost-effectiveness of emergency response plans for chemical accidents. Existing procedures and manuals are revised to elucidate the proposed model and conduct real-time consequence analysis. The existing emergency response plan is compared to verify the proposed model's efficacy. The obtained results indicate that the proposed model can exhibit better performance.

The Effect of Filter Paper on the Results of Trace Analysis (거름종이가 미량 분석 결과에 미치는 영향)

  • Lim, Heon-Sung;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.16 no.2
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    • pp.174-178
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    • 2003
  • Analytical chemists frequently use filter papers during the course of experiments without any hesitation. However, the results of analysis could be deteriorated by the various ions which are extracted from filter papers. In some filter paper made for qualitative use, about $300{\mu}g$ sodium and many other cations were detected. Although the quantities of contaminants was low in the filter paper made for quantitative use, significant amount of Fe, Si, Al, Cu and Zn was detected as well as alkali element. Many cations and anions were also detected in the filtrate obtained from the glass fiber filter.

THE USE OF MULTIVARIATE STATISTICS TO EVALUATE THE RESPONSE OF RICE STRAW VARIETIES TO CHEMICAL TREATMENT

  • Vadiveloo, J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.9 no.1
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    • pp.83-89
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    • 1996
  • Multivariate statistical procedures were used to analyse data on the chemical composition and in vitro digestibility of four varienties of rice straw after treatment with 4% NaOH solution, 4% urea solution or distilled water (control) for 48 hours. For each treatment, stepwise discriminant analysis identified the variables which maximized differences between varieties and the eigenvectors from principal component analysis quantified the contribution of these criterion variables to varietal differences. The overall response of varieties to chemical treatment was demonstrated qualitatively, by cluster analysis, and quantitatively, from the magnitude of the principal component scores. The analysis revealed that the urea and control treatments elicited the same response whereas NaOH had the greatest effect on the poorest straw variety. Similar analyses conducted on the botanical fractions of the varieties showed that the relative response of the inflorescence, stem, leaf blade and leaf sheath fractions was not altered by chemical treatment.

Analysis of Damaged Instance and Forming Fault for Disc Part in Automotive Steel Wheel (자동차용 스틸휠 디스크부품의 성형불량 및 파손사례분석)

  • Lee, Sung-Hee;Kim, M.Y.;Kim, T.G.;Yun, H.Y.;Kang, S.W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.234-238
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    • 2006
  • In this research, an analysis of damaged instance and forming fault for disc part in automotive steel wheel was performed. Rolled steel material, which had been used in the manufacturing of the damaged disc part, was prepared for tensile test, quantitative analysis of chemical component and acquirement of scanning electron microscope images. Although the results of mechanical properties and chemical component ratio for the material satisfied the suggested specification, some material inherent problem was found in the scanning electron microscope images. Finally, in an analysis of chemical component for the damaged disc part used in road condition, mismatching of chemical component ratio between the suggested specification and test result was found.

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Raman Chemical Imaging Technology for Food and Agricultural Applications

  • Qin, Jianwei;Kim, Moon S.;Chao, Kuanglin;Cho, Byoung-Kwan
    • Journal of Biosystems Engineering
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    • v.42 no.3
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    • pp.170-189
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    • 2017
  • Purpose: This paper presents Raman chemical imaging technology for inspecting food and agricultural products. Methods The paper puts emphasis on introducing and demonstrating Raman imaging techniques for practical uses in food analysis. Results & Conclusions: The main topics include Raman scattering principles, Raman spectroscopy measurement techniques (e.g., backscattering Raman spectroscopy, transmission Raman spectroscopy, and spatially offset Raman spectroscopy), Raman image acquisition methods (i.e., point-scan, line-scan, and area-scan methods), Raman imaging instruments (e.g., excitation sources, wavelength separation devices, detectors, imaging systems, and calibration methods), and Raman image processing and analysis techniques (e.g., fluorescence correction, mixture analysis, target identification, spatial mapping, and quantitative analysis). Raman chemical imaging applications for food safety and quality evaluation are also reviewed.

Synthesis and Structural Analysis of the Diaquabis(ethylenediamine)nickel(II) Bis(p-toluenesulfonate) Monohydrate (Diaquabis(ethylenediamine)nickel(II) Bis(p-toluenesulfonate) Monohydrate 층상 화합물의 합성과 구조 분석)

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.15 no.3
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    • pp.317-320
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    • 2002
  • The layer structure of the title compound, $[Ni(en)_2(H_2O)_2](CH_3C_6H_4SO_3)_2(H_2O)$ (en = ethylenediamine), consists of discrete cations, anions, and solvate water molecules linked by a hydrogen bonding network. The central Ni atom of the cation layer has a slightly distorted octahedral coordination geometry with the ethylenediamine ligands functioning as a N,N'-bidentate and the water ligands bonding through oxygen in a trans arrangement. The p-toluenesulfonate of the anion layer has an alternate sulfonate group directed toward opposite side of the cation layer. This layer structure is stabilized by a hydrogen bond involving the O atoms of the sulfonate, the water ligand, solvate water molecule, and the N atoms of the ethylenediamine.

Synthesis and Structural Analysis of a New Layered Cobalt(II) Compound with p-Toluenesulfonic Acid : $[Co(H_2O)_6](CH_3C_6H_4SO_3)_2$ (p-Toluenesulfonate를 가진 새로운 코발트(II) 층상 화합물의 합성과 구조 분석)

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.13 no.4
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    • pp.534-538
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    • 2000
  • The title compound, $[Co(H_2O)_6](CH_3C_6H_4SO_3)_2$, has been prepared and characterized by X-ray crystallography. The crystal structure of the compound demonstrates a layered material constituted by hexaaquacobalt (II) cations and p-toluenesulfonate anions. Geometrical environment of the cobalt atom is octahedrally coordinated by water molecules. The p-toluenesulfonate anions are arranged with the sulfonate groups turned toward opposite side of the layer, alternately. The layered structure is stabilized by the hydrogen bondings between the ligated water molecules and the anionic sulfonate oxygen atoms.

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The Adsorption Effect of Filter Paper on the Results of Trace Analysis (거름종이에 의한 흡착이 미량 분석 결과에 미치는 영향)

  • Lim, Heon-Sung;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.17 no.1
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    • pp.82-84
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    • 2004
  • The quantitative trace analysis of ions could be deteriorated by filter papers because of the effect of adsorption. Generally the adsorption of anions on filter paper did not occurred. Instead, $Cl^-$ and $NO{_3}^-$ ions were extracted from the filter papers. However, most metal ions were adsorbed on the filter papers by the formation of hydroxide in neutral solution. The adsorption of metal ions except $Ag^+$ ion could be avoided depend on the acid concentrations.