• 제목/요약/키워드: chemical agents

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Alumina Sol의 제조 시 사용되는 해교제 종류가 코팅 도막의 물성에 미치는 영향 (Effect of Types of Peptizing Agents Used for Preparation of Alumina Sols on the Properties of Coating Films)

  • 이병화;임형준;이인표;안치용
    • Korean Chemical Engineering Research
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    • 제54권6호
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    • pp.767-774
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    • 2016
  • 졸-겔법에 의해 출발물질로 aluminum isopropoxide를 사용하여, 메탄올용매 내에서 가수분해 시킨 후 해교제인 초산, 질산 또는 염산을 각각 첨가하여 해교 시켜 3종류의 alumina sol을 제조하였다. 또한 이 sol에 실란커플링제인(3-glycidyloxypropyl) trimethoxysilane을 첨가하여 코팅 용액을 제조한 후, 이용액을 polycarbonate 기재 위에 담금 코팅 후 열 경화시켜 코팅 도막을 형성하였다. 이 과정 중 해교제의 종류 변화가 코팅 도막의 물성에 미치는 영향을 연구하였다. 그 결과 해교제로서 강산인 염산이나 질산을 사용한 코팅 도막은 H나 2H의 연필경도와 5B의 부착력을 나타내어 우수한 물성을 나타내었다. 반면에 해교제로서 약산인 초산을 사용한 경우에는 HB의 연필경도와 3B의 부착력을 보여 좋지 못한 물성을 나타내었다.

유-무기 하이브리드 코팅 용액을 이용한 고굴절 하드코팅 막의 제조 (Preparation of Hard Coating Films with High Refractive Index using Organic-Inorganic Hybrid Coating Solutions)

  • 최진주;김남우;안치용;송기창
    • Korean Chemical Engineering Research
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    • 제52권3호
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    • pp.388-394
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    • 2014
  • 출발물질인 TTIP로부터 이산화티탄 졸을 합성하여 무기물로 사용하고 유기물로서 실란커플링제인 methacryloxypropyl trimethoxysilane (MPTMS), aminopropyl triethoxysilane (APS), glycidoxypropyl trimethoxysilane (GPTMS), vinyltriethoxysilane (VTES)을 2종 혹은 3종씩 복합 사용하여 유-무기 하이브리드 코팅 용액을 제조하였다. 그 후 코팅 용액을 기재인 PC시트 위에 스핀 코팅시키고, 열경화 시켜 하드코팅 막을 제조하였다. 2종 실란커플링제를 혼합하여 제조된 코팅 막들은 기재와의 부착력과 연필경도가 우수하지 못했으나, 3종 실란커플링제를 혼합하여 제조한 코팅 막은 2H~4H의 향상된 연필경도와 5B의 우수한 부착력을 나타내었다. 이산화티탄 졸의 첨가량이 20 g인 코팅 막의 굴절률은 550 nm에서 1.56을 나타내었으나 이산화티탄 졸의 첨가량을 20 g에서 30 g으로 증가시킨 경우, 코팅 막의 굴절률이 1.63으로 향상되었다.

Development of Anti-Ischemic Agents

  • Yoo, Sung-Eun;Yi, Kyu-Yang;Lee, Sung-Kyung;Kim, Nak-Jeong;Suh, Jee-Hee;Shin, Hwa-Sup;Lee, Byung-Ho;Kim, Sun-Ok
    • 대한약학회:학술대회논문집
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    • 대한약학회 2000년도 NEW STRATEGY FOR DRUG DEVELOPMENT IN POST-GENOMIC ERA(대한약학회)
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    • pp.123-123
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    • 2000
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아크릴 공중합체와 지방산 카르바미드의 블렌딩에 의한 내구유연발수제의 제조에 관한 연구;IV. P/C 혼방직물에의 발수가공 (A Study on the Preparation of Durable Softening Water-repellent by Blending Acrylic Copolymer and Fatty Carbamide;IV. Water-repellent Finish of P/C Blended Fabrics)

  • 고재용;홍의석;박홍수
    • 한국응용과학기술학회지
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    • 제13권2호
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    • pp.39-46
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    • 1996
  • Durable softening water-repellenting agent such as PODCW, PDDCW and PEDCW were prepared by blending cationized compound such as poly(octadecyl methacrylate-co-2-diethylaminoethyl methacrylate)[PODC], poly(2-dodecyl methacrylate-co-2-diethyl-aminoethyl methacrylate)[PDDC] and poly(2-ethylhexyl methacrylate-co-2-diethyl-aminoethyl methacrylate)[PEDC], and cationized compound of fatty carbamide, of which synthetic methods were reported in the previous paper, waxes, and emulsifiers. The results of physical tests of the P/C blended fabrics treated with PODCW, PDDCW and PEDCW with and without textile finishing resin, showed a remarkable improvement of the physical properties. The prepared water-repellenting agents, PODCW-6 and PDDCW-1, were treated on P/C blended fabrics with and without resin. For any cases, there are a little changes between initial water repellency and repellency after 3 times washing of the fabrics. Therefore, the water-repellenting agents proved to be a durable agents, and initial water $100^{+}$ and $90^{+}$ point, respectively.

Improvement of Thermal Stability of Electrospun PAN Fibers by Various Additives

  • Lee, Young-Seak;Kim, Min-Il;Im, Ji-Sun;In, Se-Jin
    • Carbon letters
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    • 제9권3호
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    • pp.200-202
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    • 2008
  • In order to improve the thermal stability of PAN-based electrospun fibers, AP-PER-MEL and $TiO_2$ were added in to the fibers as additives. The polymer composite with uniformly mixed additional agents was obtained. In case of non-treated sample, the fibers were burn off completely with high rate within $620^{\circ}C$. But in case of treated samples (EF-M and EF-MT), it is sure that the thermal stability was improved by studying TGA data and ISO flammability test about 20 and 30%, respectively. A synergy effect of adding two kinds of agents (AP-PER-MEL and $TiO_2$) into PAN-based electrospun fibers was confirmed. Through SEM images, it is confirmed that the fiber shape can be kept even after addition of agents (AP-PER-MEL and $TiO_2$). Finally the thermal stability of fibers was largely developed with keeping the nature of PAN-based fibers effectively.

Efficacy evaluation on whitening cosmetics in Japan

  • Funasaka, Yoko
    • 대한화장품학회지
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    • 제28권3호
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    • pp.91-108
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    • 2002
  • 미백제는 기미와 태양광선노출에 의한 색소침착반과 같은 색소불균형이 주로 나타나는 동양 여성들에 특히 관심이 많다. 이러한 색소침착의 불균형은 UV에 의해 더 심해지기 때문에 미백제는 멜라닌합성을 억제시키거나 UV에 의해 활성화된 signal을 억제함으로써 효과가 나타난다. Eumelanin은 UV에 의해 유도된 DNA 손상을 보호하므로 UV에 의해 유도된 DNA손상을 감소시키는 물질이 이상적인 미백제가 된다. 새롭게 합성된 항산화제인 $\alpha$-tocophenyl ferulate의 효과는 UV에 의해 손상된 DNA damage에 의한 보호 효과와 멜라닌 합성을 억제시킴으로서 나타난다. Chemical peeling과 복합적으로 색소 반점을 치료하는 lightning agent의 효과에 대한 결과를 보고하였으며 색소 반점의 개선을 정량적으로 평가하는 새롭게 개발된 facial image analyzer를 소개할 것이다.

Effect of Different Carrier Agents on Physicochemical Properties of Spray-dried Pineapple (Ananas comosus Merr.) Powder

  • Quoc, Le Pham Tan
    • 대한화학회지
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    • 제64권5호
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    • pp.259-266
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    • 2020
  • The main purpose of this study is to examine the different physicochemical properties of spray-dried products. The carrier agents and powders after the spray-drying process were analyzed for encapsulation yield, moisture content, color parameters, total polyphenol content (TPC), antioxidant capacity (AC), bulk density, flowability, wettability, hygroscopicity, water solubility index (WSI), particle size and microstructure. The spray-drying process was carried out with different carrier agents including maltodextrin (MD) and the combination of maltodextrin and gum arabic (MD-GA) with MA/GA ratio of 70/30, dried at the inlet/outlet air temperature of 160 ℃/70 ℃, 4 bar, airflow rate of 70 ㎥·h-1 and feed flow rate of 750 mL·h-1. The results showed that the different carrier agents have significant influences on the physicochemical properties of the powder produced by the spray-drying method. In there, while the values of recovery efficiency and flowability of spray-dried products from MD are higher than those of spray-dried products from MD-GA combination, the opposite is true for the values of TPC, AC, bulk density and wettability, whereas hygroscopicity and WSI values are equally represented in both products.

Iopamidol과 Ioversol 제제 조영제의 사용 후 보관 기간에 따른 1H-NMR 분석 (1H-NMR Analysis according to the Storage Period after the Use of Iopamidol and Ioversol Formulations Contrast Agents)

  • 한범희
    • 대한방사선기술학회지:방사선기술과학
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    • 제44권3호
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    • pp.239-245
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    • 2021
  • Since the side effects of contrast agents occur in many ways, hospitals must clearly identify the contrast agents and know how to manage them. Storage of contrast media It is common practice to store contrast media in a warm room to reduce viscosity and improve patient comfort. However, it is important to recognize that long-term storage at high temperatures can shorten the shelf life of a product. Therefore, in this study, the presence or absence of chemical changes according to the storage period after using the contrast medium was analyzed. As the analysis equipment, a 500 MHz Nuclear Magnetic Resonance Spectrometer of Bruker Avance (Germany) possessed by Korea Basic Science Institute (KOREA BASIC SCIENCE INSTITUTE; KBSI) was used. For the X-ray iodide contrast medium, Pamiray contrast medium of Iopamidol and Optiray contrast medium of Ioversol, samples remaining after 7 days, 20 days, 30 days, and 1 year were collected, By acquiring the spectrum from the 1H-NMR spectrometer of the contrast medium stimulated by It was compared and analyzed with the standard sample. In conclusion, depending on the storage period of the contrast medium, no peaks of physical and chemical changes were observed in both the Pamiray contrast medium of Iopamidol and the Optiray contrast medium of Ioversol after 7 days, 20 days, 30 days, and 1 year after use.

고농도 세균, 독소, 바이러스 모의 생물 작용제에 대한 제독제 4종 효과 연구 (A Study on the Efficacy of Four Chemical Decontaminants against High-concentration Surrogates of Bacteria, Toxin, and Virus Biological Agents)

  • 박한울;서영환;이홍석;김성주
    • 한국군사과학기술학회지
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    • 제27권5호
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    • pp.642-648
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    • 2024
  • If a nation or a terrorist organization produced biological agents, they are likely stored in a form of liquid concentrate. In the present study, four chemical reagents, hydrogen peroxide, sodium dichloroisocyanurate (NaDCC), Perasafe, and DF200, were investigated on their potentials as safe, efficient and eco-friendly decontaminants for biological agents. Escherichia coli, α-amylase, and bacteriophage T4 were used as surrogate strains for biological agents. Hydrogen peroxide and DF200 showed drawbacks of a rapid heat evolution upon neutralization and thick foam building up, respectively. Perasafe was effective against E. coli and T4, but it did not inactivate α-amylase while the others were able to inactivate all three types of the surrogates. NaDCC was the most suitable decontaminant for its effectiveness against all three types of surrogates at low concentrations and being able to be neutralized without aforementioned problems.

Biopile을 이용한 유류 오염토양의 복원에 관한 연구

  • 박종천;오재영;정용욱;이우범
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 추계학술발표회
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    • pp.310-314
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    • 2002
  • To investigate the effect of on-site bioremediation in soil that have been contaminated by hydrocarbon fuel spills, petroleum-degrading bacteria isolated from soil around petroleum chemical industry and microbial agents were constructed. We investigated biopiles for on-site bioremediation of soil contaminated (5000 mg per kg) with bunker A fuel in five independent lab-scale experiments. Five biopile units constituting the following treatments: (1) control with no nutrients and microbial agents (2) microbial agent M plus nutrients (3) microbial agent C plus nutrients (4) only microbial agent C (5) control with only nutrients. The results were highly different one another. After 30 days in treatments with optimal condition, total petroleum hydrocarbons were reduced to below 10 mg per kg of soil at the biopile units mixed with microbial agents, but control biopile units show that were reduced from 1,105 to 2,588 mg per kg of soil. Our results show that microbial agents at on-site bioremediation of fuel-contaminated soil is highly effective.

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