• Title/Summary/Keyword: chemical age

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Influence of Chemical Admixture on the Strength Development of Concrete at Early Age (콘크리트의 초기 강도발현에 미치는 혼화제의 영향)

  • 황인성;나운;이승훈;류현기;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.741-744
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    • 2003
  • In this study, the influence of chemical admixture on early strength development of concrete is discussed. According to the results, fluidity with variation of kinds of chemical admixture is lower in the case of acceleration type than in the case of normal type. Setting time of naphthalene acceleration type is shortened by I hour, and that of melamine is nearly same, but that of polycarbonic acid is somewhat retarded in comparison with that of naphthalene normal type. Early compressive strength gains 5MPa in about 18hours regardless of the kinds of chemical admixture. But as time elapses, compressive strength is higher in order of polycarbonic acid, naphthalene and melamine type. The relativity between compressive strength and the rebound value of P-type schmidt hammer is also favorable at early age, and compressive strength of 5MPa is estimated at the rebound value of 22.

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The Impact of Capital Structure on Firm Value: A Case Study in Vietnam

  • LUU, Duc Huu
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.5
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    • pp.287-292
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    • 2021
  • The article analyzes the impact of capital structure on the firm value of chemical companies listed on the stock market of Vietnam. Data was collected from the financial statements of 23 chemical firms listed on the Vietnam stock market from 2012 to 2019. Quantitative research method with regression model according to OLS, FEM, REM method is used; FGLS method is used to overcome the model's defects. In this research, firm value (Tobin's Q) is a dependent variable. Capital structure (DA), Return on assets (ROA), Asset turnover (AT), fixed assets (TANG), Solvency (CR), Firm size (SZ), Firm Age (AGE), and revenue growth rate (GR) are independent variables in the study. The analysis results show that the capital structure of firms in the chemical industry listed on the Vietnam stock market has an inverse correlation with firm value. Besides, firms with greater asset turnover, business size, and number of years of operation have lower firm value. This article helps corporate executives improve corporate value by adjusting their capital structure properly. Chemical firms adjusted their capital structure in the direction of gradually decreasing the debt ratio and gradually increasing equity. Firms use high debt, which has the effect of reducing the firm value of firms in the chemical industry.

Zircon chemical age of the Precambrian gneisses from Gimcheon area in the central Yeongnam massif, Korea (중부 영남육괴 김천일대 선캠브리아기 편마암의 저어콘 화학연대)

  • 이호선;송용선;박계헌
    • The Journal of the Petrological Society of Korea
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    • v.11 no.3_4
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    • pp.157-168
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    • 2002
  • In Gimcheon area of the central Yeongnam massif granite gneiss occurrs with intercalated biotite gneiss at xenolith or restite. In order to understand the evolution of the central Yeongnam massif, it is essential to have absolute age information, but not many age data are available yet. Furthermore the previous age determinations from the study area are not compatible with the outcrop relationship. In this study we determined chemical ages from the zircon grains. We obtained ages of $1970\pm$ 78(l$\sigma$)Ma from the granite gneiss, $1814\pm$77(l$\sigma$)Ma from the outer rim of a rounded zircon and 1973$\pm$97(l$\sigma$)Ma from a longish zircon, both from the biotite gneiss. These ages seem to indicate the timing of granitic magma intrusion and subsequent metamorphism. Ages of $2954\pm$ 158($l\sigma$)Ma, 2440$\pm$58(l$\sigma$)Ma, and 2219$\pm$36($l\sigma$)Ma obtained from zoned core of the rounded zircon grain from the biotite gneiss suggest various geological events before such metamorphism of the biotite gneiss. Ages in the range of 1450~1670 Ma observed in zircons of both gniesses suggest later metamorphism that the granite gneiss and the biotite gneiss experienced together. The chemical age determination by electron probe micro-analyzer of this study utilized 1$\mu\textrm{m}$ beam diameter and it seems to be a very useful age determination from the zircons with complex growth history because of superior spatial resolution.

Cycloaddition of Carbon Dioxide to Allyl Glycidyl Ether Using Silica-supported Ionic Liquid as a Catalyst (실리카에 고정화된 이온성액체를 촉매로 이용한 알릴글리시딜에테르와 이산화탄소의 부가반응)

  • Shim, Hye-Lim;Lee, Mi-Kyung;Yu, Jeong-In;Park, Dae-Won
    • Clean Technology
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    • v.14 no.3
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    • pp.166-170
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    • 2008
  • In this study, imidazolium salt ionic liquid on amorphous silica was prepared and its catalytic performance in the cycloaddition of $CO_2$ with allyl glycidyl ether (AGE) to produce heterocyclic carbonate was investigated. The ionic liquid was generated on chloropropyl functionalized silica through the immobilization of imidazole. The prepared catalyst was characterized using a number of instrumental analysis including XRD, BET, $^{29}Si$ MAS-NMR and SEM. $^{29}Si$ MAS-NMR showed that the ionic liquid formed adduct with the chloropropyl groups attached to the silica surface. The immobilized ionic liquid showed very good catalytic activity for the cycloaddition of $CO_2$ with AGE, showing 55-61% of AGE conversion with over 85% of the carbonate selectivity at $80-120^{\circ}C$. Its AGE conversion and selectivity to the carbonate were even higher than the homogeneous analog, 1-n-butyl-3-methyl imidazolium bromide (BMImBr).

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Evaluating Early Age Shrinkage Behavior of Ultra High Performance Cementitious Composites (UHPCC) with CSA Expansive Admixture and Shrinkage Reducing Agent (CSA계 팽창재 및 수축 저감제의 혼입에 따른 UHPCC의 초기 수축 거동 평가)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.23 no.4
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    • pp.441-448
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    • 2011
  • In this study, experimental tests of chemical and autogenous shrinkage were performed to evaluate the early age shrinkage behaviors of ultra high performance cementitious composites (UHPCC) with various replacement ratios of silica fume (SF), shrinkage reducing agent (SRA), expansive admixture (EA), and superplasticizer (SP). Starting time of self-desiccation, was analyzed by comparing the setting times and the deviated point of chemical and autogenous shrinkage strains. The test results indicated that both SF and SRA augment the early age chemical shrinkage, whereas SP delays the hydration reaction between cement particles and water, and reduces chemical shrinkage. About 49% of autogenous shrinkage was depleted by synergetic effect of SRA and EA. The hardening of UHPCC was catalyzed by containing EA. Self-desiccation of UHPCC occurred prior to the initial setting due to the high volume fraction of fibers and low water-binder ratio (W/B).

Studies on the Small Body Size Mouse Developed by Mutagen N-Ethyl-N-nitrosourea

  • Zhang, Qian-Kun;Cho, Kyu-Hyuk;Cho, Jae-Woo;Cha, Dal-Sun;Park, Han-Jin;Yoon, Seok-Joo;Zhang, ShouFa;Song, Chang-Woo
    • Toxicological Research
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    • v.24 no.1
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    • pp.69-78
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    • 2008
  • Mutant mouse which show dwarfism has been developed by N-ethyl-N-nitrosourea (ENU) mutagenesis using BALB/c mice. The mutant mouse was inherited as autosomal recessive trait and named Small Body Size (SBS) mouse. The phenotype of SBS mouse was not apparent at birth, but it was possible to distinguish mutant phenotype from normal mice 1 week after birth. In this study, we examined body weight changes and bone mineral density (BMD), and we also carried out genetic linkage analysis to map the causative gene(s) of SBS mouse. Body weight changes were observed from birth to 14 weeks of age in both affected (n = 30) and normal mice (n = 24). BMD was examined in each five SBS and normal mice between 3 and 6 weeks of age, respectively. For the linkage analysis, we produced backcross progeny [(SBS${\times}$C57BL/6J) $F_1{\times}$ SBS] $N_2$ mice (n = 142), and seventy-four microsatellite markers were used for primary linkage analysis. Body weight of affected mice was consistently lower than that of the normal mice, and was 43.7% less than that of normal mice at 3 weeks of age (P < 0.001). As compared with normal mice at 3 and 6 weeks of age, BMD of the SBS mice was significantly low. The results showed 15.5% and 14.1 % lower in total body BMD, 15.3% and 8.7% lower in forearm BMD, and 29.7% and 20.1% lower in femur BMD, respectively. The causative gene was mapped on chromosome 10. The map order and the distance between markers were D10Mit248 - 2.1 cM - D10Mit51 - 4.2 cM - sbs - 0.7 cM - D10Mit283 - 1.4cM - D10Mit106 - 11.2cM - D10Mit170.

Effect of Panax ginseng Extract on Passive Avoidance Retention in Old Rats

  • Jaenicke, Bernhard;Kim, Eun-Joo;Ahn, Jong-Woong;Lee, Hye-Sook
    • Archives of Pharmacal Research
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    • v.14 no.1
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    • pp.25-29
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    • 1991
  • Female rats of two groups (6 and 27 months) were tested in the passive avoidance test to investigate the age-dependency of the learning ability. The results showed a significantly better avoidance behavior in the young adult animals compared to the older ones. The influence of a 13-day treatment with Panax ginseng (30 mg/kg/d, oral) on 27 month old rats caused a considerably prolonging of the latency time in comparison to the untreated control group of the same age. In the open field the treated rats exhibited neither an altered locomotion nor exploration nor a changed emotional reactivity which could explain the improved avoidance reaction.

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De-emulsification of Petroleum Emulsion Using Nocardia amarae (Nocardia amarae를 이용한 석유 유상액의 탈유화)

  • Lee, Ki-Young;Lee, Jin-Jong;Kim, Dong-Won;Na, Kun;Lee, Jae-Chan
    • KSBB Journal
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    • v.13 no.2
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    • pp.209-213
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    • 1998
  • The characteristics of de-emulsification of pertroleum emulsion by Nocardia amarae were investigated. Insoluble medium containing n-hexadecane was more effective than soluble medium in de-emulsification of emulsion containing diesel and bunker C as the organic phase. Emulsion made by the addition of xanthan or bioemulsifier was de-emulsified by N. amarae, and longer culture age was effective. In low viscosity range, organic phase with longer carbon chain was more effective. The contact, angle between bacterial film and water droplet in air increased from 16 degree for 4 day culture age to 26 degree for 15 day. The contact angle between bacterial film and water droplet in kerosene, n-heyxane or n-hexadecane also increased to greater than 100 degree after 3 day culture age. The hydrophobicity of bactgerial film increased according to the culture age.

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Assessment of Seed Viability and Vigour in Neem (Azadirachta indica A. Juss.)

  • Kumar, Devendra
    • Journal of Forest and Environmental Science
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    • v.29 no.4
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    • pp.282-291
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    • 2013
  • Rapid loss in viability of neem (Azadirachta indica A. Juss.) seed is a major problem. Present effort was undertaken for developing a set pattern for assessing of viability and vigour in seed of various mother tree age of neem (Age I-06 years, Age II-15 years, Age III-25 years and Age IV->30 years old). Various viability test viz. triphenyle tetrazolium chloride test, electrical conductivity, excised embryo test, and germination test have been performed on seeds obtained from mother tree age classes. Inconsistency was observed with the TTC and EC test in germination of seed in laboratory as well as nursery. While various vigour tests viz. cold test, chemical stress test (methanol stress test), and accelerated ageing test alongwith ageing index, germination test (G%, MGT and GV) and various seedling growth parameters like seedling length (cm), number of leaves, collar diameter (cm), total biomass (g) alongwith mathematical indices i.e. vigour index, sturdiness quotient, volume index, quality index, root shoot ratio in nursery as well have been taken for study and showed better consistency. On the basis present study results of various viability and vigour test indicated that mother tree age class II performed better in comparison to others and it can be recommended for seed collection. Further it is also recommended that viability of neem seed may be assessed using various laboratory tests like excise embryo test and germination test (G%, MGT and GV) and vigour test may be taken preferably by cold germination test, chemical (methanol) stress test, accelerated ageing test in laboratory and germination alongwith various seedling growth parameters seedling length (cm), number of leaves, collar diameter (cm), total biomass (g) alongwith mathematical indices like Vigour Index, Sturdiness quotient, Volume Index, Quality index, root shoot ratio in nursery as discussed in this study.