• Title/Summary/Keyword: chemical acidification

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Long-Term Preservation Measures of Paper Records of Special Preserving Organization (특수 보존 기관의 종이 기록물 장기 보존 대책)

  • Shin, Jong-Soon;Lee, Jae-Soo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.30 no.1
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    • pp.59-69
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    • 2012
  • This study is Long term preservation measures which is closely related to preserving paper records, record condition evaluation, preservation measure and is conducted as follows. As for Means to Evaluate the Deterioration and Damaged Conditions of Records, research and analysis has been made on the contamination and deterioration examples such as damage, dry, stapler, metal, contamination, acidification which are the characteristics of paper record damage types. The of Paper record is one of the key procedures to evaluate the record material and its physi-chemical status in many criteria and to suggest the best preservation method. Between 1970 and 2000, the main record materials was fine paper and OMR paper along with partly newspaper and coarse paper, whereas the main recording material was ball point pen. Overall damage and deterioration status is, for record materials between 1940 and 1960, high deterioration was found and in urgent need for preservation measure and more damages are caused by tapes, staplers and metals. As for records after 1970, there is light deterioration but needs preservation process. There are approximately 3 million records produces before 2000, and assuming that there are 30 pages per record and that 30% has been damaged or deteriorated, 27 million pages are subject to preservation process. Among damaged or deteriorated records, there are large number of records impossible to go through deacidification process so manual preservation and restoration process is necessary as well. Securing manpower having preservation and restoration skills as well as preservation equipment(deacidification process, preservation and restoration) is in urgent need.

Effects of Salts on Rheological Behaviour of Salvia Hydrogels

  • Yudianti, Rike;Karina, Myrtha;Sakamoto, Masahiro;Azuma, Jun-ichi
    • Macromolecular Research
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    • v.17 no.5
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    • pp.332-338
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    • 2009
  • Rheological behavior of natural hydrogel produced from seeds of three Salvia spp. (S. miltiorrhiza (SM), S. sclarea (SS), S. viridis (SV)) was investigated by using a Rheometer equipped with a cone and plate geometry measuring system under never-dried condition. Different chemical contents of such hydrogels give significant effects on their rheological properties. Because of incomplete penetration of water inside the hydrogels after drying before-dried hydrogels were used for rheological analysis. To know molecular interactions which predominated in the gel formation, some constituents were externally added to the 1.0% (w/w) hydrogel. Addition of urea to disrupt hydrogen bonds reduced 3.4-67% viscosity of the untreated hydrogels and changed viscoelastic properties from gel to liquid-like behavior. Neutral salts added to the hydrogel solution at 0.1 M also lowered the viscosity in a manner related with increase in size of cations and temperature. Changing from gel state to liquid-like state was also easily confirmed by oscillation measurement (storage, G', and loss, G", modulii) typically observed in the cases of potassium sulfate and potassium thiocyanate. Influence of pH variation on the viscosity explained that weak alkaline condition (pH 8-9) creates a higher resistance to flow due to increasingly electrostatic repulsions between negative charges ($COO^-$) Importance of calcium bridges was also demonstrated by recovery of viscosity of the hydrogels by addition of calcium after acidification. The summarized results indicate that electrostatic repulsion is a major contributor for production of hydrogel structure.

A Study on Adsorption of Heavy Metal Ions Using Water-soluble Chitosan Derivative (수용성 Chitosan 유도체를 이용한 중금속 이온 흡착에 관한 연구)

  • Lee, Kwang-Il;Kwak, Chun-Geun;Kim, Young-Ju;Jang, Buyng-Man;Kim, Sang-Ho;Lee, Ki-Chang
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.2
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    • pp.85-92
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    • 1996
  • Chitosan itself has been prepared using chitin, one of the most abundant compounds in nature, as a starting material. We have synthesized the water-soluble chitosan derivative, N-dithiocarboxy chitosan sodium salt, through the reaction of water-soluble chitosan with carbon disulfide in the presence of alkali metal hydroxide. To elucidate this natural polymer capacity of adsorbing heavy metal ions, we have performed adsorption experiments using the water-soluble chitosan derivative various average molecular weight and of different percent contents of sulfur. The effect of pH, adsorption time and temperature on adsorption efficiency was also studied. The adsorbent derived from water-soluble chitosan of average molecular weight ranging $9,000{\sim}120,000$ was shown to have the highest capacity of adsorbing heavy metal ions. On the whole, adsorbing efficiency was increased as the reaction time goes longer and also increased as the reaction temperture goes higer in temperture range of $15^{\circ}C{\sim}45^{\circ}C$. The adsorption capacity at various pH, however, was appeared to vary depending on the heavy metal ions studied Judging from these finding, water-soluble N-dithiocarboxy chitosan sodium salt, a derivative of a biodegradable nature polymer, is believed to be a potential adsorbent for heavy metal ions since it not only is shown to lower the concentration of heavy metal ions to below the drainage quality standard, but also it would not cause acidification and hardening of soil which is one of the detrimental effects of synthetic macromolecular adsorbents present.

Assessing Soil Fertility Status of Edible Wild Plants Fields in Ulleung Island

  • Park, Sang-Jo;Park, Jun-Hong;Kim, Byung-Sung;Chung, Yun-Hak;Lee, Dong-Jun;Kwon, Oh-Heun;Park, So-Deuk;Lee, Suk-Hee
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.4
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    • pp.368-374
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    • 2016
  • The perennial edible wild plants such as Aster glehnii, Solidago virgaurea subsp. gigantean, Allium ochotense, Athyrium acutipinnulum, Aruncus dioicus var. kamtschaticus and Codonopsis lanceolata have cultivated as the main income crops introduced into the fields about 30 years ago in Ulleung island. Soil samples were collected from 190 fields and assessed the effects of management practices on soil chemical properties at wild edible plant fields under no-till system. The strong acidic soils of pH 5.4 or less were detected in 45% of the soil samples. The level of soil organic matter was being held at mean $63{\pm}28g\;kg^{-1}$, 2.7 times higher than upland soils in Korea. Available phosphate and exchangeable potassium showed more than recommended levels of upland crops as $680{\pm}489mg\;kg^{-1}$ and $1.94{\pm}1.7cmol_c\;kg^{-1}$, respectively. The fields of Solidago and Aster showing strong soil acidity and high level of available phosphate and water soluble $NO_3{^-}$ were distinguished from other crops in analysis of variance and principal component analysis of soil chemicals. These results suggested that high frequency of acidic soil and high levels of available $P_2O_5$, exchangeable $K_2O$ and water soluble $NO_3{^-}$ were accompanied with the use of urea and NPK-fertilizer based on nitrogen in the field. However, further research is needed to understand the appropriate management of fertilization and the prevention of soil acidification for wild edible plants.

Compressibility Characteristics of the Lime Treated Clay (생석회 혼합토의 압축특성에 관한 연구)

  • 민덕기;황광모;오미희
    • Journal of the Korean Geotechnical Society
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    • v.19 no.6
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    • pp.23-29
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    • 2003
  • In this paper, effects of the acidification of ground and the chemical additive materials-ferric oxide, calcium chloride and calcium sulphate on the compressibility characteristics of the marine clay treated with quick lime were investigated. The rapid inflection point method was carried out. Results showed that the compression index of the untreated marine clay increased as the pH of pore water decreased. Also, the preconsolidation pressure, the coefficient of consolidation and the coefficient of permeability of the untreated marine clay decreased with pH of pore water. In the case of the marine clay treated with the quick lime-calcium chloride, the compression index decreased and the coefficient of consolidation and the coefficient of permeability increased. Specially, the preconsolidation pressure of sample treated with the quick lime-ferric oxide was higher than that of another samples.

Construction of forest environmental information and evaluation of forest environment (산림환경 정보구축 및 산림환경 평가)

  • Chang, Kwan-Soon
    • Journal of Environmental Impact Assessment
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    • v.7 no.2
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    • pp.37-51
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    • 1998
  • This study was carried out to lead the scientific management of the urban forest by estimating the forest environment. Forest environmental information was constructed using IDRISI system based on survey data, soil, plant, and digital elevation data. Forest environmental information was consisted of soil depth, soil organic content, soil hardness and parent rock as a soil environmental factor, and forest community, tree age, crown density as a plant environmental factor. Plant activity and topographic environment also were analyzed by using remote sensing data and digital elevation data. Environmental function of urban forest was estimated based on results of soil conservation and forest productivity. 70% of urban forest is located in elevation of lower than 200m and 55% of forest area have the slope of lower than 15 degree. Analyzed soil conservation status and forest productivity were almost the same as the soil chemical properties of collected soil sample and the vegetation index estimated using remote sensing data, respectively. Thus, the constructed forest environmental information could be useful to give some ideas for management of urban forest ecosystem and establishment of environmental conservation planning, including forests, in Taejon. The best forest environmental function was appeared at the natural ecology preservation zone. Current natural parks and urban parks were appeared to establish the environmental conservation plan for further development. The worst forest environmental function was appeared at the forest near to the industrial area and an overall and systematic plan was required for the soil management and high forest productivity because these forest was developing a severe soil acidification and having a low forest productivity.

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Changes on the Quality of Safflower Seed Products Coated with Edible Films during Storage (가식성 필름 코팅에 따른 홍화씨 가공제품의 품질 변화)

  • Kim Nam-Woo;Ju Eung-Young
    • Food Science and Preservation
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    • v.12 no.1
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    • pp.17-22
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    • 2005
  • This study analyzed the change of physical and chemical characteristics on the safflower seed produce coated edible film. L and a value of safflower seed product coated edible film were slowly increased during storage, while b value decreased. Moisture content were increased during storage. Acid valus welt less increased when edible film was ased. Peroxide values were also increased during storage, but peroxide value in products coated sodium caseinate or k-carraggenan was $50\%$ in the control after 30 days of storage. The value of sensual test was higher in products coated sodium caseinate or k-carraggenan than those of control. Coating with sodium caseinate or k-carraggenan was effective for acidification retardation and quality improvement of safflower seed products.

Mineral Distribution of Soil at Different Depth in a Fairway Slope (훼어웨이 경사의 토양 깊이별 무기성분 분포)

  • Choi, B. J.;Ju, Y. H.;Park, H.
    • Asian Journal of Turfgrass Science
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    • v.11 no.2
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    • pp.89-95
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    • 1997
  • Soil chemical properties were investigated to elucidate vertical movement of mineral nutrients in a fairway slope of 27 year-old golf course. Soil samples were taken at every 10cm depth to 4Ocm on 4 sites 20m apart each along two parallel lines 60m apart on the slope(15˚) in August. Accord-ing to the similarity of vertical distribution pattern they could be classified into 6 distinctive groups(magnesium, nitrate, phosphorus, ammonium, manganese and copper) and the slope tended to affect the vertical movement of minerals. The contents of Ca and Mg increased with depth while NO$_3$-N and Zn decreased and correlated positively. Soil pH showed significant positive correlation with depth, Ca and Mg. Phosphorus content was highest in 10~20cm depth and decreased resulting in relatively high content in 30~40cm depth of the bottom site of slope. Iron distribution pattern was similar to phosphorus. Potassium and $NH_4$showed various(irregular) patterns. Mn was highest in the deep layer at the lower sites of slope but it was reverse at the upper sites and negatively correlated with Fe. Cu content incresed with depth and heighest in 20~30cm depth. Electroconductivity showed significant positive correlation with $NO_3$-N. Magnesium, cal-cium and copper seem to be prone to defficiency due to fast leaching, and nitrate and phosphorus prone to excess problem. Preventive measures on acidification of surface soil should be taken.

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Bacterial Stringent Signal Directs Virulence and Survival in Vibrio cholerae.

  • Oh, Young Taek;Kim, Hwa Young;Yoon, Sang Sun
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.10a
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    • pp.8-8
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    • 2019
  • The stringent response (SR) is characterized as a bacterial defense mechanism in response to various growth-inhibiting stresses. It is activated by accumulation of a small nucleotide regulator, (p)ppGpp, and induces global changes in bacterial transcription and translation. Recent work from our group has shown that (p)ppGpp plays a critical role in virulence and survival in Vibrio cholerae. The genes, relA and relV, are involved in the production of (p)ppGpp, while the spoT gene encodes an enzyme that hydrolyzes it in V. cholerae. A mutant strain defective in (p)ppGpp production (i.e. ${\Delta}relA{\Delta}relV{\Delta}spoT$ mutant) lost the ability to produce cholera toxin (CT) and lost their viability due to uncontrolled production of organic acids, when grown with extra glucose. In contrast, the ${\Delta}relA{\Delta}spoT$ mutant, a (p)ppGpp overproducer strain, produced enhanced level of CT and exhibited better growth in glucose supplemented media via glucose metabolic switch from organic fermentation to acetoin, a neutral fermentation end product, fermentation. These findings indicates that (p)ppGpp, in addition to its well-known role as a SR mediator, positively regulates CT production and maintenance of growth fitness in V. cholerae. This implicates SR as a promising drug target, inhibition of which may possibly downregulate V. cholerae virulence and survival fitness. Therefore, we screened a chemical library and identified a compound that induces medium acidification (termed iMAC) and thereby loss of wild type V. cholerae viability under glucose-rich conditions. Further, we present a potential mechanism by which the compound inhibits (p)ppGpp accumulation. Together, these results indicate that iMAC treatment causes V. cholerae cells to produce significantly less (p)ppGpp, an important regulator of the bacterial virulence and survival response, and further suggesting that it has a therapeutic potential to be developed as a novel antibacterial agent against cholera.

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Effects of sodium diacetate and microbial inoculants on fermentation of forage rye

  • Yan Fen Li;Eun Chan Jeong;Li Li Wang;Hak Jin Kim;Farhad Ahmadi;Jong Geun Kim
    • Journal of Animal Science and Technology
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    • v.65 no.1
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    • pp.96-112
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    • 2023
  • Rye (Secale cereale L.) is a valuable annual forage crop in Korea but there is limited information about the impact of chemical and biological additives on fermentation characteristics of the crop. This experiment was conducted to investigate fermentation dynamics of wilted forage rye treated with the following six additives; control (no additive), sodium diacetate applied at 3 g/kg wilted forage weight (SDA3), 6 g/kg wilted forage weight (SDA6), inoculations (106 CFU/g wilted forage) of Lactobacillus plantarum (LP), L. buchneri (LB), or LP+LB. The ensiled rye sampled at 1, 2, 3, 5, 10, 20, 30, and 45 days indicated that the acidification occurred fast within five days of storage than the rest of the storage period. The microbial inoculants decline the pH of ensiled forage, more rapidly than the control or SDA treated, which accompanied by the decrease of water-soluble carbohydrates and increase of lactic acid. Compared with the control silage, all treatments suppressed ammonia-nitrogen formation below to 35 g/kg DM throughout the sampling period. Suppression of total microbial counting occurred in SDA6, LP, and LP + LB. The lactic acid production rates were generally higher in microbial inoculation treatments. Acetic acid concentration was lowest in the LP-treated silage and highest in the SDA- and LB-treated silages. The in vitro dry matter (DM) digestibility and total digestible nutrients were the highest in the silage treated with SDA (6 g/kg) at day 45 of ensiling. Based on lower ammonia-nitrogen concentrations and higher feed value, ensiling forage rye treated with SDA at 6 g/kg is promising through enhanced silage quality.