• 제목/요약/키워드: chemical

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Encapsulation of 2,4-Dihydroxybenzophenone into Dodecylbenzenesulfonate Modified Layered Double Hydroxide for UV Absorption Properties

  • Li, Shifeng;Shen, Yanming;Liu, Dongbin;Fan, Lihui;Wu, Keke
    • Bulletin of the Korean Chemical Society
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    • 제35권2호
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    • pp.392-396
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    • 2014

  • New organic-inorganic composite of 2,4-dihydroxybenzophenone (BP-1) encapsulation into dodecylbenzenesulfonate (DBS) modified layered double hydroxide (LDH) was successfully prepared. The surface, structural, thermal and absorption properties of the BP-1/DBS-LDH nanohybrid was characterized by BET analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TG) and diffuse reflectance UV-Vis absorbance spectra (DRUV-vis). The interlayer configuration of composite and the adsorption mechanism of BP-1 on MgAl-DBS-LDH were discussed. It was suspected that DBS anions located in the form of monolayer arrangement with a $75^{\circ}$ anti parallel angle between dodecylbenzenesulfonate chain axis. The diffuse reflectance UV-Vis absorbance results revealed that the UV absorbing wavelength of BP-1/DBS-LDH evidently extends to about 400 nm, which shows that the BP-1/DBS-LDH has the potential application as a UV absorber.

  • https://doi.org/10.5012/bkcs.2014.35.2.392 인용 PDF KSCI KPUBS HTML

화학물질관리법상 화학사고 정의에 관한 소고 (A Brief Review of the Legal Definition of Chemical Accident under the Current Chemical Substances Control Act)

  • 박지훈;박선오;박효진;권혜옥
    • 한국환경보건학회지
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    • 제49권4호
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    • pp.179-182
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    • 2023

  • The Chemical Substances Control Act has been legislated to counter the risks posed by chemical substances to public health and the environment, but a number of small- and large-scaled incidents related to hazardous chemicals continue to occur every year. The Korean Ministry of Environment takes legal responsibility for prevention, preparedness, and response to nationwide chemical accidents under the Chemical Substances Control Act. The determination of chemical accidents that occur during hazardous chemical handling processes is based on the Article 2 (Definitions) of the law and the administrative criteria for judgement of chemical accidents. However, there are certain ambiguities in the scientific basis for determining chemical accidents under the current regulations. Whether or not a chemical accident has a direct influence on penalties and administrative measures for a workplace where an accident occurred, it is necessary to find reasonable criteria for determining chemical accident based on legal and scientific evidence.

  • https://doi.org/10.5668/JEHS.2023.49.4.179 인용 PDF