• 제목/요약/키워드: charge transport

검색결과 473건 처리시간 0.027초

Modeling of pentacene MIS capacitors with admittance measurements and the effects of dispersive charge transport

  • Jung, Keum-Dong;Lee, Cheon-An;Park, Dong-Wook;Park, Byung-Gook;Shin, Hyung-Cheol;Lee, Jong-Duk
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.67-69
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    • 2006
  • Capacitance and loss values of pentacene MIS capacitors with different thicknesses are measured as a function of frequency for the modeling of the devices. The equivalent circuit for the ideal MIS capacitor is adopted to model the obtained admittance, so the values of $C_i,\;C_d,\;C_b$, and $R_b$ are determined for each pentacene thickness. In the loss curve, broader loss peaks are observed in measurement than the modeling results regardless of the pentacene thickness. By considering the effects of dispersive charge transport in bulk semiconductor, more accurate modeling results are obtained.

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ITO/PEDOT:PSS/TPD/$Alq_3$/LiAl 구조에서 온도 변화에 따른 전압-전류 특성 (Current-voltage characteristics of ITO/PEDOT:PSS/TPD/$Alq_3$/LiAl device with temperature variation)

  • 김상걸;정동회;홍진웅;정택균;김태완;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
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    • pp.114-117
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    • 2002
  • We have studied the dependence of current-voltage characteristics of Organic Light Emitting Diodes(OLEDs) on temperature-dependent variation. The OLEDs have been based on the molecular compounds. N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1, 1'- biphenyl-4, 4'-diamine (TPD) as a hole transport. tris(8-hydroxyquinolinoline) aluminum (III) ($Alq_3$) as an electron transport and Poly(3,4-ethylenedioxythiophene) (PEDOT:PSS) as a buffer layer. The current-voltage characteristics were measured in the temperature range of 10K and 300K. A conduction mechanism in OLEDs has been interpreted in terms of space-charge-limited current(SCLC) and tunneling region.Ā᐀會Ā᐀衅?⨀頱岒ᄀĀ저會Ā저?⨀⡌ឫഀĀ᐀會Ā᐀㡆?⨀쁌ឫഀĀ᐀會Ā᐀遆?⨀郞ග瀀ꀏ會Ā?⨀〲岒ऀĀ᐀會Ā᐀䁇?⨀젲岒Ā㰀會Ā㰀顇?⨀끩Ā㈀會Ā㈀?⨀䡪ഀĀ᐀會Ā᐀䡈?⨀Ā᐀會Ā᐀ꁈ?⨀硫Ā저會Ā저?⨀샟ගऀĀ저會Ā저偉?⨀栰岒ഀĀ저會Ā저ꡉ?⨀1岒ഀĀ저會Ā저J?⨀惝ග؀Ā؀會Ā؀塊?⨀ග䈀Ā切

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나노유체의 열전도도 향상에 관한 새로운 메커니즘 (A New Mechanism for Enhanced Beat Transport of Nanofluid)

  • 이동근;김재원
    • 대한기계학회논문집B
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    • 제30권6호
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    • pp.560-567
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    • 2006
  • Although various conjectures have been proposed to explain abnormal increase in thermal conductivity of nanofluids, the detailed mechanism could not be understood and explained yet. The main reason is primarily due to the lack of knowledge on the most fundamental factor governing the mechanisms such as Brownian motion, liquid layering, phonon transport, surface chemical effects and agglomeration. By applying surface complexation model for the measurement data of hydrodynamic size, zeta potential, and thermal conductivity, we have shown that sulfate charge state is mainly responsible for the increase in the present condition and may be the factor incorporating all the mechanisms as well. Moreover, we propose a new model including concepts of fractal and interfacial layer. The properties such as thickness and thermal conductivity of the layer are estimated from the surface charge states and the concept of electrical double layer. With this, we could demonstrate the pH dependences of the layer properties and eventually of the effective thermal conductivity of the nanofluid.

Li:Al cathode layer and its influence on interfacial energy level and efficiency in polymer-based photovoltaics

  • 박순미;전지혜;박오옥;김정원
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.72-72
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    • 2010
  • Recent development of organic solar cell approaches the level of 8% power conversion efficiency by the introduction of new materials, improved material engineering, and more sophisticated device structures. As for interface engineering, various interlayer materials such as LiF, CaO, NaF, and KF have been utilized between Al electrode and active layer. Those materials lower the work function of cathode and interface barrier, protect the active layer, enhance charge collection efficiency, and induce active layer doping. However, the addition of another step of thin layer deposition could be a little complicated. Thus, on a typical solar cell structure of Al/P3HT:PCBM/PEDOT:PSS/ITO glass, we used Li:Al alloy electrode instead of Al to render a simple process. J-V measurement under dark and light illumination on the polymer solar cell using Li:Al cathode shows the improvement in electric properties such as decrease in leakage current and series resistance, and increase in circuit current density. This effective charge collection and electron transport correspond to lowered energy barrier for electron transport at the interface, which is measured by ultraviolet photoelectron spectroscopy. Indeed, through the measurement of secondary ion mass spectroscopy, the Li atoms turn out to be located mainly at the interface between polymer and Al metal. In addition, the chemical reaction between polymer and metal electrodes are measured by X-ray photoelectron spectroscopy.

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FE Analysis of Plasma Discharge and Sheath Characterization in Dry Etching Reactor

  • Yu, Gwang Jun;Kim, Young Sun;Lee, Dong Yoon;Park, Jae Jun;Lee, Se Hee;Park, Il Han
    • Journal of Electrical Engineering and Technology
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    • 제9권1호
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    • pp.307-312
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    • 2014
  • We present a full finite element analysis for plasma discharge in etching process of semiconductor circuit. The charge transport equations of hydrodynamic diffusion-drift model and the electric field equation were numerically solved in a fully coupled system by using a standard finite element procedure for transient analysis. The proposed method was applied to a real plasma reactor in order to characterize the plasma sheath that is closely related to the yield of the etching process. Throughout the plasma discharge analysis, the base electrode of reactor was tested and modified for improving the uniformity around the wafer edge. The experiment and numerical results were examined along with SEM data of etching quality. The feasibility and usefulness of the proposed method was shown by both numerical and experimental results.

비정질 박막에 대한 도핑 조건의 영향 및 미세구조와 I-V 연구 (Effect of Dopping Conditions on a-Se Thin-Films : Microstructural and I-V Study)

  • 박성광;박지군;강상식;공현기;김진섭;남상희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.492-496
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    • 2001
  • Due to their better photosensitivity in X-ray, the amorphous selenium based photoreceptor is widely used on the X-ray conversion materials. It was possible to control the charge carrier transport of amorphous selenium by suitably alloying a-Se with other elements(e,g. As, Cl). In this paper, We investigated dopants(As, Cl) composition rate to improve dark resistivity and transport properties of charge carrier in amorphous selenium using by direct X-ray conversion material. Alloying a-Se with As inhibits the recrystallization of a-Se but introduces undesirable deep hole traps. then doping with Cl(in the ppm range) compensates for the deep hole traps. We investigated their composition rate in various doping conditions and then obtained optimum dopant composition rate. The result was Se-As 0.3%-c] 30 ppm and X-ray Sensitivity was 0.57 pC/$pixel{\cdot}mR$ at $137{\mu}m{\times}137{\mu}m$ Pixel area.

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Polypyrrole-Glucose Oxidase 효소전극에 대한 효소 고정화의 정성적 평가 (Qualitative Analyses of Porypyrrole-Glucose Oxidase Enzyme Electrode for Immobilization)

  • 김현철;구할본;사공건
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 추계학술대회 논문집 학회본부 C
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    • pp.984-986
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    • 1999
  • In the case of immobilizing of glucose oxidase in organic polymer using electrosynthesis, the glucose oxidase obstructs charge transfer and mass transport during the film growth. This may lead to short chained polymer and make charge-coupling weak between the glucose oxidase and the backbone of the polymer. That is mainly due to insulating property and net chain of the glucose oxidase. Such being the case, it is useless to increase in amount of glucose oxidase more than reasonable in the synthetic solution. We establish by means of qualitative analysis that amount of immobilized glucose oxidase can be improved by adding a hole ethyl alcohol in the synthetic solution. As ethyl alcohol was added by 0.1mol $dm^{-3}$ in the synthetic solution, the faradic impedance of resultant electrode was increased about five times as much as the case of ethyl alcohol free in the solution, and mass transport was limited more than over. That is due to insulating property and net chain of the glucose oxidase. Moreover, in ultraviolet spectra of the synthetic solution, the adsorption peak at 285nm corresponding to glucose oxidase was decreased. It suggests increase in amount of immobilized glucose oxidase.

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이온 전송 및 고주파 유전 흡수 (Ion Transport and High Frequency Dielectric Absorption)

  • 윤주호;최용성;황종선;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.379-380
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    • 2008
  • Molecular Dynamics (MD) simulations have been used to model the dynamics of the charge-compensating sodium ions in the non-stoichiometric hollandite Nax$(Ti_{8-x}Cr_x)O_{16}$. These interstitial ions reside in 'tunnels' in the crystal structure and move under the forces of both the ions making up the cage structure and the many body interactions of the other sodium ions in the tunnel. The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6\times10^{12}$ Hz that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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비전도성 매질 내 이온성 액체 액적의 충전 현상 (Charging of an Ionic Liquid Droplet in a Dielectric Medium)

  • 임도진
    • 청정기술
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    • 제20권4호
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    • pp.354-358
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    • 2014
  • 이온성 액체는 상온에서 액체로 존재하는 이온성염으로 최근 청정 공정에 사용될 수 있는 용매, 전해질, 촉매로써 주목받고있다. 본 연구에서는 비전도성 매질 내 액적의 접촉 충전 현상을 이용하여 여섯 가지 서로 다른 이온성 액체에 대한 충전 거동을 고찰하였다. 이온성 액체 액적의 충전 현상은 이전 수용 액적의 충전 현상과 유사한 특징을 나타내었으며 기본적으로 완전 도체 이론으로 설명이 가능하였다. 하지만 이온 종류에 따른 상세 거동은 다소의 변화가 관찰되었다. 본 연구의 결과는 청정 용매 및 촉매로 각광 받고 있는 이온성 액체의 전기화학적 특성을 이해하고 분석하는데 유용하게 활용될 수 있을 것으로 기대된다.

Application of Atomic Layer Deposition to Electrodes in Solid Oxide Fuel Cells

  • Kim, Eui-Hyeon;Hwang, Heui-Soo;Ko, Myeong-Hee;Bae, Seung-Muk;Hwang, Jin-Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.319.1-319.1
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    • 2013
  • Solid oxide fuel cells (SOFCs) have been recognized as one of emerging renewable energy sources, due to minimized pollutant production and high efficiency in operation. The performance of SOFCs is largely dependent on the electrode polarization which involves the oxidation/reduction in cathodes and anodes along with the charge transport of ions and electronic carriers. Atomic layer deposition is based on the alternate chemical surface reaction occurring at low temperatures with high uniformity and superior step coverage. Such features can be extended into the coating of metal oxide and/or metal layer onto the porous materials. In particular, the atomic layer deposition is can manipulated in controlling the charge transport in terms of triple phase boundaries, in order to control artificially the electrochemical polarization in electrodes of SOFC. The current work applied atomic layer deposition of metal oxides intro the electrodes of SOFCs. The corresponding effect was monitored in terms of the electrochemical characterization. The roles of atomic layer deposition in solid oxide fuel cells are discussed towards optimized towards long-term durability at intermediate temperature.

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