• Title/Summary/Keyword: characterization study

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Characterization of fine organic aerosols from biomass burning emissions using FTIR method (분광학적 방법을 이용한 바이오매스 연소 배출 유기 입자의 화학적 특성)

  • Son, Se-Chang;Park, Tae-Eon;Park, Seungshik
    • Particle and aerosol research
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    • v.17 no.4
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    • pp.125-132
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    • 2021
  • Fresh PM2.5 smokes emitted from combustion of four biomass materials (pellet, palm fruit fiber (PFF), PKS, and sawdust) in a laboratory-controlled environment were characterized using an attenuated total reflectance-fourier transform infrared (ATR-FTIR) technique. In smoke samples emitted from combustion of pellets, PFF and PKS, which is being used as boiler fuels for greenhouses in rural areas, the organic carbon/elemental carbon (OC/EC) ratios in PM2.5 were very high (14.0-35.5), whereas in sawdust smoke samples they were significantly low (<4.0) due to the combustion method close to flaming combustion. ATR-FTIR analysis showed that OH(3400-3250 cm-1), CH3(2958-2840 cm-1), CH2(2910 cm-1 and 2850 cm-1), ketone(1726-1697 cm-1), C=C(1607-1606 cm-1 and 1515-1514 cm-1), lignin (1463-1462 cm-1 and 1430-1428 cm-1) and -NO2(1360-1370 cm-1) peaks were identified in all biomass burning (BB) smoke samples. However, additional peaks appeared depending on the type of biomass. Among the four types of biomass materials, an additional peak of the methylene group CH3(2872-2870 cm-1) appeared only in PFF and PKS smoke samples, and a peak of C=O(1685 cm-1) was also confirmed. And in the case of PKS smoke samples, a peak of aromatic C=C(1593 cm-1 and 1476 cm-1) that did not appear in other BB samples was also observed. This indicates that the molecular structure of organic compounds emitted during BB differs depending on the type of biomass materials. The results of this study are expected to provide valuable information to more specifically reveal the effect of BB on PM2.5 collected in the atmospheric environment.

Preparation and Characterization of Jochung, a Grain Syrup, with Onion (옥총(玉葱) 첨가 조청의 제조 및 특성)

  • Kim, D.H.;Kim, Y.B.;Koo, H.J.;Baek, H.J.;Chang, K.J.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.22 no.1
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    • pp.145-152
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    • 2020
  • Onion is a perennial herb of the lily family that has a long history and has long been widely used throughout the world as it is one of the most important condiments in our diet, along with chili peppers and garlic. It has been used for cooking and processing food with its unique flavor and aroma. Because of the nature of onions, long-term storage can lead to spoilage. Research was done to increase profits through processing and expand various onion products. A low temperature extraction method was used to study the physiological activation effect and onion processing method of flavonoid component weak to heat.

Research on Attribute of Postdramatic Theatre from (2019) by Theater Group "Mul-Kyul" (극단 '물결'의 <밑바닥에서>(2019)에 나타난 포스트드라마 연극 특성 연구)

  • Ra, Kyung-Min
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.3
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    • pp.295-306
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    • 2020
  • In 21st century, theater evolves into a complex aspects. Advanced visual media, such as photography and movies has brought crisis to theater's position, and that crisis led contemporary theater seek for distinctive strategy by repeatedly pondering over the format in which it can be more competitive than other arts. And postdramatic theatre is one of distinctive characteristics of this trend in contemporary theater. Among these flows, The aim of thesis is to study the phenomenon of postdramatic theatre and its practical application in the recently performed (2019) by Theater Group "Mul-Kyul". (2019) puts the body at the front, one of the features of the postdramatic theatre. When creating stage, or developing narratives, the process of characterization, or even highlighting dramatic themes, non-verbal focused theatrical expressions hold a dominant position over verbal expressions. Also, by combining various non-verbal elements like object, with body language, it builds a complex Scenography and creates a metaphorical expression. In this regards, I would like to classify the postdramatic theatre phenomenon shown in the (2019) into 'Disorganization of text through Scenography' and 'Collage of Body Language and Object' and consider its characteristics and meanings.

Research Status of Satellite-based Evapotranspiration and Soil Moisture Estimations in South Korea (위성기반 증발산량 및 토양수분량 산정 국내 연구동향)

  • Choi, Ga-young;Cho, Younghyun
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1141-1180
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    • 2022
  • The application of satellite imageries has increased in the field of hydrology and water resources in recent years. However, challenges have been encountered on obtaining accurate evapotranspiration and soil moisture. Therefore, present researches have emphasized the necessity to obtain estimations of satellite-based evapotranspiration and soil moisture with related development researches. In this study, we presented the research status in Korea by investigating the current trends and methodologies for evapotranspiration and soil moisture. As a result of examining the detailed methodologies, we have ascertained that, in general, evapotranspiration is estimated using Energy balance models, such as Surface Energy Balance Algorithm for Land (SEBAL) and Mapping Evapotranspiration with Internalized Calibration (METRIC). In addition, Penman-Monteith and Priestley-Taylor equations are also used to estimate evapotranspiration. In the case of soil moisture, in general, active (AMSR-E, AMSR2, MIRAS, and SMAP) and passive (ASCAT and SAR)sensors are used for estimation. In terms of statistics, deep learning, as well as linear regression equations and artificial neural networks, are used for estimating these parameters. There were a number of research cases in which various indices were calculated using satellite-based data and applied to the characterization of drought. In some cases, hydrological cycle factors of evapotranspiration and soil moisture were calculated based on the Land Surface Model (LSM). Through this process, by comparing, reviewing, and presenting major detailed methodologies, we intend to use these references in related research, and lay the foundation for the advancement of researches on the calculation of satellite-based hydrological cycle data in the future.

Preparation and Characterization of Tungsten Carbide Using Products of Hard Metal Sludge Recycling Process (초경합금 슬러지 재활용 공정 산물을 활용한 텅스텐 탄화물 제조 및 특성 평가)

  • Kwon, Hanjung;Shin, Jung-Min
    • Resources Recycling
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    • v.31 no.4
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    • pp.19-25
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    • 2022
  • In this study, tungsten carbide (WC) powder was prepared using a novel recycling process for hard metal sludge that does not use ammonium paratungstate. Instead of ammonia, acid was used to remove the sodium and crystallized tungstate, resulting in the formation of tungstic acid (H2WO4). The WC powder was successfully synthesized by the carbothermal reduction of tungstic acid through H2O decomposition, reduction of WO3 to W, and formation of WC. The carbon content and holding time at the carbothermal reduction temperature were optimized to remove free carbon from the WC powder. As a result, most of the free carbon in the WC powder prepared from sludge was removed, and the content of free carbon in the synthesized WC powder was lower than that in commercial WC powder. Moreover, the crystallite size of WC prepared from H2WO4 was much smaller than that of commercial micron-sized WC powder produced from APT. The small crystallite size of WC induces grain growth during the sintering of the WC-Co composite; thus, a WC-Co composite with large WC grains was fabricated using the WC powder prepared from H2WO4. The large WC grains affected the mechanical properties of the WC-Co composite. Further, due to the large grain size, the WC-Co composite fabricated from H2WO4 exhibited a higher toughness than that of the WC-Co composite prepared from commercial WC powder.

Critical Review and Alternatives to the Decriminalization of Tattooing (문신시술의 비범죄화에 대한 비판적 검토와 대안)

  • Shim, YoungJoo;Lee, Sang-Han
    • The Korean Society of Law and Medicine
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    • v.23 no.1
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    • pp.149-176
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    • 2022
  • South Korean law strictly prohibits engagement in medical activities by non-medical practitioners. In the country, tattooing is classified as a medical practice, and non-medical practitioners who engage in it are penalized because they are unauthorized to carry out this procedure. In reality, however, people rarely seek tattooing services from medical personnel. Arguing that their freedom of job selection is violated, non-medical personnel who make a living as tattoo artists reject the characterization of the procedure as a form of medical treatment and demand the decriminalization of tattooing by non-medical practitioners. Nevertheless, tattooing can cause health- and hygiene-related dangers when it is not performed by medical professionals because it involves penetration into the skin using needles. Hence, stringent management is necessary for infection prevention. The gap between reality and the law gives rise to the need for proactive thinking about the institutionalization of tattoo practice by non-medical personnel. Policymakers should reflect on the fact that only minimal tattooing services are currently performed by medical staff while also accounting for health and safety. On this basis, this study examined tattoo-related legislation in South Korea to determine whether the procedure corresponds to medical practice and identify ways to solve problems that occur from the perspective of health care. As a response that promotes safety and reflects reality, this research proposed a three-phase approach.

Isolation of Simiduia sp. SH-2 and Characterization of Its β-Agarase (한천분해세균 Simiduia sp. SH-2 균주의 분리 및 β-agarase의 특성조사)

  • Lee, Dong-Geun;Kim, Geun-Dae;Lee, Sang-Hyeon
    • Journal of Life Science
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    • v.32 no.10
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    • pp.778-783
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    • 2022
  • This study isolated a new agarase-producing bacterium and characterized its agarase. A new agar-degrading strain was isolated from the seashore of Namhae in Gyeongnam province, Korea, and was purely cultured using the Marine Agar 2216 media. The isolated bacterium was identified as Simiduia sp. SH-2 after 16S rRNA gene sequencing. The crude agarase was obtained from the culture medium of the Simiduia sp. SH-2 strain, and the agar-degrading activity was measured. The highest level of activity of the Simiduia sp. SH-2-derived agar-degrading enzyme was 625 U/l. Agar degradation activity was most significant at 40℃ and pH 7.0. Compared to the activity at 40℃, the relative activity was 31% at 20℃ and 71% at 30℃. Compared to the activity at pH 7.0, the relative activity was 94% and 89% at pH 6.0 and pH 8.0, respectively. Residual activity was greater than 96% after exposure to 20℃ and 30℃ for 2 hr and more than 49% after exposure to 40℃ for 2 hr. Simiduia sp. SH-2 was identified as a strain producing β-agarase that creates neoagarooligosaccharides, such as neoagarotetraose and neoagarohexaose. Therefore, the Simiduia sp. SH-2 strain and its β-agarase are expected to be useful functional material producers in the food, cosmetic, and pharmaceutical industries.

Characterization of Materials and Color Formation for Black Potteries from the Proto-Three Kingdoms Period in Ulsan, Korea (울산지역 원삼국시대 흑색토기의 재질 및 발색 특성)

  • Kim, Su Kyoung;Jang, Sungyoon;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.37 no.2
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    • pp.77-89
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    • 2021
  • In this study, materials and color formation techniques were assessed for black potteries excavated from the Janghyeon-dong, Jungsan-dong and Gyodong-ri sites during the Proto-Three Kingdoms period in Ulsan, Korea. Although the black potteries were black superficially, the inner cores were either black or reddish yellow. Microscopy analysis identified that body clay was used for reddish iron oxide rich soils with quartz, alkali feldspar and mica, along with grains of myrmechite texture. Additionally, as marginal differences exist in the contents of SiO2, Fe2O3 and CaO, the composition of the host rock and clay distributed around the sites was affected. Thus, we can deduce that pottery was made by soiling at a short distance. Raman spectroscopy results revealed that the black layer of the black pottery was used as amorphous combustion carbon. In addition, as a transparent layer of brown lacquer was observed on the substrate that was in contact with the surface layer, the black layer of the pottery induced black color development by a combination of combustion carbon and lacquer. Based on the mineral composition and microtexture of the body clay, the firing temperature of the potteries seemed to range from 750 to 850℃, whereas the lacquer layer was pyrolyzed at 468℃ by thermal analysis. Therefore, a combined layer of combustion carbon and lacquer, which formed the black color, was painted after the body clay was fired.

Characterization of intrinsic molecular structure spectral profiles of feedstocks and co-products from canola bio-oil processing: impacted by source origin

  • Alessandra M.R.C.B., de Oliveira;Peiqiang, Yu
    • Animal Bioscience
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    • v.36 no.2
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    • pp.256-263
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    • 2023
  • Objective: Feed molecular structures can affect its availability to gastrointestinal enzymes which impact its digestibility and absorption. The molecular spectroscopy-attenuated total reflectance Fourier transform infrared vibrational spectroscopy (ATR-FTIR) is an advanced technique that measures the absorbance of chemical functional groups on the infrared region so that we can identify and quantify molecules and functional groups in a feed. The program aimed to reveal the association of intrinsic molecular structure with nutrient supply to animals from canola feedstocks and co-products from bio-oil processing. The objective of this study was to characterize special intrinsic carbohydrate and protein-related molecular structure spectral profiles of feedstock and co-products (meal and pellets) from bio-oil processing from two source origins: Canada (CA) and China (CH). Methods: The samples of feedstock and co-products were obtained from five different companies in each country arranged by the Canola Council of Canada (CCC). The molecular structure spectral features were analyzed using advanced vibrational molecular spectroscopy-ATR-FTIR. The spectral features that accessed included: i) protein-related spectral features (Amide I, Amide II, α-helix, β-sheet, and their spectral intensity ratios), ii) carbohydrate-related spectral features (TC1, TC2, TC3, TC4, CEC, STC1, STC2, STC3, STC4, TC, and their spectral intensity ratios). Results: The results showed that significant differences were observed on all vibrationally spectral features related to total carbohydrates, structural carbohydrates, and cellulosic compounds (p<0.05), except spectral features of TC2 and STC1 (p>0.05) of co-products, where CH meals presented higher peaks of these structures than CA. Similarly, it was for the carbohydrate-related molecular structure of canola seeds where the difference between CA and CH occurred except for STC3 height, CEC and STC areas (p>0.05). The protein-related molecular structures were similar for the canola seeds from both countries. However, CH meals presented higher peaks of amide I, α-helix, and β-sheet heights, α-helix:β-sheet ratio, total amide and amide I areas (p<0.05). Conclusion: The principal component analysis was able to explain over 90% of the variabilities in the carbohydrate and protein structures although it was not able to separate the samples from the two countries, indicating feedstock and coproducts interrelationship between CH and CA.

Synthesis and characterization of PPG-based urethane-modified epoxy resin for enhancing impact resistance of epoxy composite resin (에폭시 복합수지의 내충격성을 향상을 위한 PPG 기반 우레탄 변성 에폭시 합성 및 특성 분석)

  • Hwang, Chiwon;Jeon, Jaehee;Ahn, Dowon;Yu, Youngchang;Lee, Wonjoo
    • Journal of Adhesion and Interface
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    • v.23 no.2
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    • pp.44-52
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    • 2022
  • Epoxy resin has the disadvantage of being easily destroyed by instantaneous impact due to its high crosslinking density despite its high glass transition temperature (Tg) and excellent properties. To compensate for this, in this study, polyol was synthesized by ring opening polymerization of propylene glycol (PPG) diamine, Jeffamine D 2000 and propylene carbonate, and urethane modified epoxy was synthesized using this. The properties of the synthesized urethane modified epoxy were confirmed by FT-IR, H-NMR. To confirm the degree of improvement in impact resistance as an adhesive, a urethane modified epoxy adhesive was prepared by mixing a digylcidyl ether bisphenol A (DGEBA) with curing agent and curing accelerator. Properties test of urethane modified epoxy were shear strength, tensile strength and impact strength. As a result, excellent results were obtained in all test when the ratio of DGEBA : urethane modified epoxy was 8:2.