• 제목/요약/키워드: cesium iodine

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Removal of cesium(137Cs) and iodide(127I) by microfiltration·nanofiltration·reverese osmosis membranes (정밀여과·나노여과·역삼투 막에 의한 세슘과 요오드의 제거)

  • Chae, Seon-Ha;Kim, Chung-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.5
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    • pp.549-554
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    • 2014
  • This study was evaluated the applicability of the membrane filtration process (Micro Filtration (MF), nanofiltration membranes (NF), reverse osmosis (RO)) on the major radioactive substances, iodine ($I^-$) and cesium ($Cs^+$) using membranes produced in Korea and domestic raw water. Iodine ($I^-$) or cesium ($Cs^+$) in the microfiltration membrane (MF) process could not be expected removal efficiency by eliminating marginally at the combined state with colloidal and turbidity material. At the domestic raw water (lake water, turbidity 1.2 NTU, DOC 1.3 mg/L) conditions, nanofiltration membrane (NF) and reverse osmosis (RO) showed a high removal rate of about 88 ~ 99% for iodine ($I^-$) and cesium ($Cs^+$) and likely to be an alternative process for the removal of radioactive material.

Initial Release of Nuclides from Spent PWR Fuels

  • Kim, S. S.;K. S. Chun;Kim, Y. B.;Park, J. W.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.238-244
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    • 2004
  • The relationship between the leaching and gap inventory of spent fuel has been studied. When a specimen of J44H08 spent PWR fuel with 38 GWD/MTU has been leached in the synthetic granitic groundwater in Ar atmosphere, the released fraction of cesium was increased rapidly up to 0.7% at around 500 days and stayed below 0.8% until 3 years. This 0.7% of cesium might be released from the gap in this fuel. The measurement of gap inventory with C15I08 spent PWR fuel, having 35 GWD/MTU and 0.22% of fission gas release, was also determined near 0.6% for the cesium, which is a similar fraction of cesium released from the leaching experiment with J44H08 fuel. Its gap inventories of strontium and iodine were about 0.03 and less than 0.2% respectively. Respective fractions of cesium and strontium in grain boundary of C15I08 were 0.78, 0.09%.

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Contribution of production and loss terms of fission products on in-containment activity under severe accident condition for VVER-1000

  • Jafarikia, S.;Feghhi, S.A.H.
    • Nuclear Engineering and Technology
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    • v.51 no.1
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    • pp.125-137
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    • 2019
  • The purpose of this paper is to study the source term behavior after severe accidents by using a semi-kinetic model for simulation and calculation of in-containment activity. The reactor containment specification and the safety features of the containment under different accident conditions play a great role in evaluating the in-containment activity. Assuming in-vessel and instantaneous release of radioactivity into the containment, the behavior of in-containment isotopic activity is studied for noble gasses (Kr and Xe) and the more volatile elements of iodine, cesium, and aerosols such as Te, Rb and Sr as illustrative examples of source term release under LOCA conditions. The results of the activity removal mechanisms indicates that the impact of volumetric leakage rate for noble gasses is important during the accident, while the influence of deposition on the containment surfaces for cesium, mainly iodine isotopes and aerosol has the largest contribution in removal of activity during evolution of the accident.

Investigation of Geometrical Properties on Deposition Rate in Cesium Iodine Film (증착속도에 따른 CSI layer의 기하학적 특성 연구)

  • Lee, Kyu-Hong;Park, Ji-Koon;Kang, Sang-Sik;Cha, Byung-Yul;Cho, Sung-Ho;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.415-417
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    • 2003
  • CsI 형광체는 X선에 대한 분해능 및 변환효율이 우수한 물질이다. 최근 대면적 평판형 X선 영상검출기의 변환층으로 이용하기 위해 CsI 형광체의 대면적 제조에 대한 연구가 활발히 진행되고 있다. 본 논문은 진공 열증착법을 이용하여 증착속도(3, 3.8, $4.5\;{\mu}m/min$)에 따라 $20\;{\mu}m$ 두께의 CsI 필름을 제조하였고, XRD 및 SEM 분석을 통해 CsI 필름의 기하학적 구조를 조사하였다. 증착된 CsI 필름은 증착속도에 관계없이 복잡한 다결정 구조를 가지며, $3\;{\mu}m/min$의 증착속도에서 약 $1\;{\mu}m$ 크기로 needle-like 한 columnar structure를 가졌다. As results, about 3um/min evaporation rate formed as good geometry characteristics CsI layer.

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Ion-Pair Extraction of Cs Radionuclides by Dicyclohexyl-24-crown-8 and Tetraphenylborate for Their Determination in Reactor Coolant (Dicyclohexyl-24-crown-8과 Tetraphenylborate에 의한 원자로 냉각수로부터 세슘 핵종의 이온쌍 용매추출)

  • Ihn-Chong Lee;Si-Joong Kim;Chul Lee
    • Journal of the Korean Chemical Society
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    • v.27 no.4
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    • pp.262-267
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    • 1983
  • A study has been carried out for a scheme of the selective extraction and determination of cesium, sodium and nuclides by the ion association with dicyclohexyl-24-crown-8 and sodium tetraphenylborate from primary coolant of a pressurized water reactor. For that purpose, the effects of hydrogen, cesium and borate ions on the extraction have been investigated. Interferences of iodine and xenon nuclides were found but could be removed by reducing with sodium thiosulfate and back extraction with 1 N hydrochloric acid solution, respectively.

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Effect analysis of ISLOCA pathways on fission product release at Westinghouse 2-loop PWR using MELCOR

  • Kim, Seungwoo;Park, Yerim;Jin, Youngho;Kim, Dong Ha;Jae, Moosung
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2878-2887
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    • 2021
  • As the amount of fission product released from ISLOCA was overestimated because of conservative assumptions in the past, several studies have been recently conducted to evaluate the actual release amount. Among several pathways for the ISLOCA, most studies were focused on the pathway with the highest possibility. However, different ISLOCA pathways may have different fission product release characteristics. In this study, fission product behavior was analyzed for various pathways at the Westinghouse two-loop plant using MELCOR. Four pathways are considered: the pipes from a cold leg, from a downcomer, from a hot leg to the outlet of RHR heat exchanger, and the pipe from the hot leg to the inlet of RHR pump (Pathway 1-4). According to the analysis results, cladding fails at around 2.5 h in Pathways 1 and 2, and on the other hand, about 3.3 h in Pathways 3 and 4 because the ISLOCA pathways affect the safety injection flow path. While the release amount of cesium and iodine ranges between 20 and 26% in Pathways 1 to 3, Pathway 4 allows only 5% to the environment because the break location is submerged. Also, as more than 90% of cesium released to the environment passes through the personnel door, reinforcing the pressure capacity of the doors would be a significant factor in the accident management of the ISLOCA.

Structural, morphological, optical, and photosensing properties of Cs2TeI6 thin film synthesized by two-step dry process

  • Hoat, Phung Dinh;Van Khoe, Vo;Bae, Sung-Hoon;Lim, Hyo-Jun;Hung, Pham Tien;Heo, Young-Woo
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.279-285
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    • 2021
  • Recently, cesium tellurium iodine (Cs2TeI6) has emerged as an inorganic halide perovskite material with potential application in optoelectronic devices due to its high absorption coefficient, suitable bandgap and because it consists of nontoxic and earth-abundant elements. However, studies on its fabrication process as well as photoresponse characteristics are limited. In this study, a simple and effective method is introduced for the synthesis of Cs2TeI6 thin films by a two-step dry process. A Cs2TeI6-based lateral photosensor was fabricated, and its photoresponse characteristics were explored under laser illuminations of four different wavelengths in the visible range: 405, 450, 520, and 655 nm. The initial photosensing results suggest potential application and can lead to more promising studies of Cs2TeI6 film in optoelectronics.

Paper Electrophoretic Separation of Fission Products (여과지 전기영동에 의한 핵분열 생성물 분리)

  • Byung Hun Lee;Jong Du Lee;Young Kuk Kim
    • Nuclear Engineering and Technology
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    • v.13 no.4
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    • pp.254-263
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    • 1981
  • Paper electrophoretic separation of fission products has been carried out by using the specially designed migration apparatus. In general, the isolation of rubidium, strontium, zirconium, ruthenium, cesium, cerium, molybdenum, and some short-lived fission products is more efficient under 0.1M HCl electrolyte as compared with 0.1M NaOH electrolyte. In addition to Np-239, 1-131∼135 were, in particular, observed with different iodine chemical species obtained by the paper-electrophoretic separation of short, neutron-irradiated uranyl nitrate solution.

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STUDY ON THE ELECTRON GENERATION BY A MICRO-CHANNEL PLATE BASED ON EGS4 CALCULATIONS AND THE UNIVERSAL YIELD CURVE

  • Moon, B.S.;Han, S.H.;Kim, Y.K.;Chung, C.E.
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.177-181
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    • 2001
  • The conversion efficiency of a cesium iodine coated micro-channel plate is studied. We use the EGS4 code to transport photons and generated electrons until their energies become less than 1keV and 10keV respectively. Among the generated electrons, the emission from the secondary electrons located within the escape depth of 56nm from the photo-converter boundary is estimated by integrating the product of the secondary electrons with a probability depending only on their geometric locations. The secondary electron emission from the generated electrons of energy higher than 100eV is estimated by the 'universal yield curve'. The sum of these provides an estimate for the secondary electron yield and we show that results of applying this algorithm agree with known experimental results. Using this algorithm, we computed secondary electron emissions from a micro-channel plate used in a gas electron multiplier detector that is currently being developed at Korea Atomic Energy Research Institute.

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