DOI QR코드

DOI QR Code

Structural, morphological, optical, and photosensing properties of Cs2TeI6 thin film synthesized by two-step dry process

  • Hoat, Phung Dinh (School of Materials Science and Engineering, Kyungpook National University (KNU)) ;
  • Van Khoe, Vo (School of Materials Science and Engineering, Kyungpook National University (KNU)) ;
  • Bae, Sung-Hoon (School of Materials Science and Engineering, Kyungpook National University (KNU)) ;
  • Lim, Hyo-Jun (School of Materials Science and Engineering, Kyungpook National University (KNU)) ;
  • Hung, Pham Tien (Department of Physics, Le Quy Don Technical University) ;
  • Heo, Young-Woo (School of Materials Science and Engineering, Kyungpook National University (KNU))
  • Received : 2021.09.06
  • Accepted : 2021.09.22
  • Published : 2021.09.30

Abstract

Recently, cesium tellurium iodine (Cs2TeI6) has emerged as an inorganic halide perovskite material with potential application in optoelectronic devices due to its high absorption coefficient, suitable bandgap and because it consists of nontoxic and earth-abundant elements. However, studies on its fabrication process as well as photoresponse characteristics are limited. In this study, a simple and effective method is introduced for the synthesis of Cs2TeI6 thin films by a two-step dry process. A Cs2TeI6-based lateral photosensor was fabricated, and its photoresponse characteristics were explored under laser illuminations of four different wavelengths in the visible range: 405, 450, 520, and 655 nm. The initial photosensing results suggest potential application and can lead to more promising studies of Cs2TeI6 film in optoelectronics.

Keywords

Acknowledgement

The work was financially supported by Kyungpook National University Development Project Research Fund, 2018.

References

  1. W. S. Yang, B. W. Park, E. H. Jung, N. J. Jeon, Y. C. Kim, D. U. Lee, S. S. Shin, J. Seo, E. K. Kim, J. H. Noh, and S. I. Seok, "Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells", Science, Vol. 356, No. 6345, pp. 1376-1379, 2017. https://doi.org/10.1126/science.aan2301
  2. L. Zhang, L. Xu, M. Zhu, C. Li, L. Li, J. Su, and Y. Gao, "Pink all-inorganic halide perovskite nanocrystals with adjustable characteristics: Fully reversible cation exchange, improving the stability of dopant emission and light-emitting diode application", J. Alloys Compd., Vol. 818, pp. 152913(1)-152913(11), 2020.
  3. Y. Wang, Y. Zhang, T. Pang, K. Sun, Z. Hu, and Y. Zhu, "Organolead halide perovskite-based metal-oxide-semiconductor structure photodetectors achieving ultrahigh detectivity", Sol. Energy, Vol. 183, pp. 226-233, 2019. https://doi.org/10.1016/j.solener.2019.03.024
  4. S. Ullah, J. Wang, P. Yang, L. Liu, J. Khan, S. Yang, T. Xia, H. Guo, and Y. Chen, "Lead-free Cs2SnI6 perovskites for optoelectronic applications: Recent developements and perspectives", Sol. RRL, Vol. 5, No. 5, pp. 2000830(1)-2000830(26), 2021.
  5. M. A. Ali, A. H. Reshak, G. Murtaza, M. A. Anazy, H. Althib, T. H. Flemban, and J. Bila, "Optoelectronic and transport properties of Rb/Cs2TeI6 defective perovskites for green energy applications", Int. J. Energy Res., Vol. 45, No. 6, pp. 8448-8455, 2021. https://doi.org/10.1002/er.6378
  6. D. Liu, Q. Li, Z. Zhang, K. Wu, "Stable lead-free te-based double perovskites with tunable band gaps: A first-principles study", New J. Chem., Vol. 43, No. 37, pp. 14892-14897, 2019. https://doi.org/10.1039/C9NJ03660A
  7. J. Guo, Y. Xu, W. Yang, B. Zhang, J. Dong, W. Jie, M. G. Kanatzidis, "Morphology of X-ray detector Cs2TeI6 perovskite thick films grown by electrospray method", J. Mater. Chem. C, Vol. 7, No. 28, pp. 8712-8719, 2019. https://doi.org/10.1039/C9TC02022E
  8. Y. Xu, B. Jiao, T. B. Song, C. C. Stoumpos, Y. He, I. Hadar, W. Lin, W. Jie, M. G. Kanatzidis, "Zero-dimensional Cs2TeI6 perovskite: Solution-processed thick films with high X-ray sensitivity", ACS Photonics, Vol. 6, No. 1, pp. 196-203, 2019. https://doi.org/10.1021/acsphotonics.8b01425
  9. I. Vazquez-Fernandez, S. Mariotti, O. S. Hutter, M. Birkett, T. D. Veal, T. D. C. Hobson, L. J. Phillips, L. Danos, P. K. Nayak, H. J. Snaith, W. Xie, M. P. Sherburne, M. Asta, and K. Durose, "Vacancy-ordered double perovskite Cs2TeI6 thin films for optoelectronics", Chem. Mater., Vol. 32, No. 15, pp. 6676-6684, 2020. https://doi.org/10.1021/acs.chemmater.0c02150
  10. A. E. Maughan, A. M. Ganose, M. M. Bordelon, E. M. Miller, D. O. Scanlon, J. R. Neilson, "Defect tolerance to intolerance in the Vacancy-ordered double perovskite semiconductors Cs2SnI6 and Cs2TeI6", J. Am. Chem. Soc., Vol. 138, No. 27, pp. 8453-8464, 2016. https://doi.org/10.1021/jacs.6b03207
  11. Y. Cai, W. Xie, H. Ding, Y. Chen, T. Krishnamoorthy, L. H. Wong, N. Mathews, S. G. Mhaisalkar, M. Sherburne, and M. Asta, "Computational study of halide perovskite-derived A2BX6 inorganic compounds: Chemical trends in electronic structure and structural stability", Chem. Mater., Vol. 29, No. 18, pp. 7740-7749, 2017. https://doi.org/10.1021/acs.chemmater.7b02013
  12. E. Y. Peresh, O. V. Zubaka, V. I. Sidei, I. E. Barchii, S. V. Kun, and A. V. Kun, "Preparation, stability regions, and properties of M2TeI6 (M = Rb, Cs, Tl) crystals", Inorganic Materials, Vol. 38, No. 8. pp. 859-863, 2002. https://doi.org/10.1023/A:1019747432003
  13. H. Fujiwara, M. Kato, M. Tamakoshi, T. Miyadera, M. Chikamatsu, "Optical characteristics and operational principles of hybrid perovskite solar cells", Phys. Status Solidi A, Vol. 215, No. 12, pp. 1-10, 2018.
  14. P. D. Hoat, H. H. Ha, P. T. Hung, V. X. Hien, S. Lee, J. H. Lee, and Y. W. Heo, "Synthesis of Cs2SnI6 perovskite thin film by low-pressure chemical vapor deposition method", Thin Solid Films, Vol. 732, pp. 138799(1)-138799(8), 2021.
  15. M. Shahid, Y. Wang, J. Yang, T. Li, Y. Xing, J. Cheng, M. Zhang, C. Wan, and W. Pan, "Indium-doped SnO2 nanobelts for high- performance transparent and flexible photosensors by a facile assembly", Nanotechnology, Vol. 28, No. 33, pp. 335705(1)-335705(13), 2017. https://doi.org/10.1088/0957-4484/28/33/335705
  16. W. Tian, T. Zhai, C. Zhang, S. L. Li, X. Wang, F. Liu, D. Liu, X. Cai, K. Tsukagoshi, D. Golberg, and Y. Bando, "Low-cost fully transparent ultraviolet photodetectors based on electrospun ZnO-SnO2 heterojunction nanofibers", Adv. Mater., Vol. 25, No. 33, pp. 4625-4630, 2013. https://doi.org/10.1002/adma.201301828
  17. X. Han, J. Liang, J. H. Yang, K. Soni, Q. Fang, W. Wang, J. Zhang, S. Jia, A. A. Marti, Y. Zhao, and J. Lou, "Lead-free double perovskite Cs2SnX6: Facile solution synthesis and excellent stability", Small, Vol. 15, No. 39, pp. 1-7, 2019.
  18. S. Ghosh, S. Paul, S. K. De, "Control synthesis of Air-stable morphology tunable Pb-free Cs2SnI6 perovskite nanoparticles and their photodetection properties", Part. Part. Syst. Charact., Vol. 35, No. 9, pp. 1800199(1)-1800199(6), 2018.
  19. V. K. S. Hsiao, S. F. Leung, Y. C. Hsiao, P. K. Kung, Y. C. Lai, Z. H. Lin, K. N. Salama, H. N. Alshareef, Z. L. Wang, and J. H. He, "Photo-carrier extraction by triboelectricity for carrier transport layer-free photodetectors", Nano Energy, Vol. 65, pp. 103958(1)-103958(9), 2019.
  20. M. I. Saidaminov, M. A. Haque, J. Almutlaq, S. Sarmah, X. H. Miao, R. Begum, A. A. Zhumekenov, I. Dursun, N. Cho, B. Murali, O. F. Mohamed, T. Wu, and O. M. Bakr, "Inorganic lead halide perovskite single crystals: Phase-selective low-temperature growth, carrier transport properties, and self-powered photodetection", Adv. Opt. Mater., Vol. 5, No. 2, pp. 1600704(1)-1600704(7), 2017.
  21. P. Zhu, S. Gu, X. Shen, N. Xu, Y. Tan, S. Zhuang, Y. Deng, Z. Lu, Z. Wang, and J. Zhu "Direct conversion of perovskite thin films into nanowires with kinetic control for flexible optoelectronic devices", Nano Lett., Vol. 16, No. 2, pp. 871-876, 2016. https://doi.org/10.1021/acs.nanolett.5b03504
  22. X. Tang, Z. Zu, H. Shao, W. Hu, M. Zhou, M. Deng, W. Chen, Z. Zang, T. Zhu, and J. Xue, "All-inorganic perovskite CsPb(Br/I)3 nanorods for optoelectronic application", Nanoscale, Vol. 8, No. 33, pp. 15158-15161, 2016. https://doi.org/10.1039/c6nr01828a