• Title/Summary/Keyword: ceramic composite

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The study on cure behavior and dielectric property of Ceramic (BNT)-Polymer (BCB) composite material (세라믹(BNT)-폴리머(BCB) 복합체의 경화 거동과 유전특성에 대한 연구)

  • Kim, Un-Yong;Chun, Myoung-Pyo;Cho, Jung-Ho;Kim, Byung-Ik;Myoung, Sung-Jae;Sin, Dong-Uk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.6
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    • pp.251-255
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    • 2007
  • We made $(1-x)BCB-xBNT(BaNd_2Ti_4O_{12})$ (x=20, 30, 40, 50 vol%) composite thick film with a high dielectric constant and low loss by the hand casting method. Dielectric constant and dielectric loss of prepared thick film are measured at 1MHz and curing behavior of the film are observed through thermal analysis such as DSC. We investigated the effect of contents of BNT filler and curing behavior of film on dielectric properties of BCB-BNT composite. Dielectric constant increased with increasing BNT filler from 20 to 50 vol% and dielectric loss ($tan{\delta}$) decreased with increasing BNT filler. Dielectric constant and loss ($tan{\delta}$) of composite material was not nearly dependent on the curing behavior. But as a result of TCC (Temperature Characteristics of Coefficient) decreased with increasing the curing temperature, we confirmed that the curing of these composite system is most stable above $250^{\circ}C$.

Small-Scale Wind Energy Harvester Using PZT Based Piezoelectric Ceramic Fiber Composite Array (PZT계 압전 세라믹 파이버 어레이 복합체를 이용한 미소 풍력 에너지 하베스터)

  • Lee, Min-Seon;Na, Yong-Hyeon;Park, Jin-Woo;Jeong, Young-Hun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.5
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    • pp.418-425
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    • 2019
  • A piezoelectric ceramic fiber composite (PCFC) was successfully fabricated using $0.69Pb(Zr_{0.47}Ti_{0.53})O_3-0.31[Pb(Zn_{0.4}Ni_{0.6})_{1/3}Nb_{2/3}]O_3$ (PZT-PZNN) for use in small-scale wind energy harvesters. The PCFC was formed using an epoxy matrix material and an array of Ag/Pd-coated PZT-PZNN piezo-ceramic fibers sandwiched by Cu interdigitated electrode patterned polyethylene terephthalate film. The energy harvesting performance was evaluated in a custom-made wind tunnel while varying the wind speed and resistive load with two types of flutter wind energy harvesters. One had a five-PCFC array vertically clamped with a supporting acrylic rod while the other used the same structure but with a five-PCFC cantilever array. Stainless steel (thickness: $50{\mu}m$) was attached onto one side of the PCFC to form the PZT-PZNN cantilever. The output power, in general, increased with an increase in the wind speed from 2 m/s to 10 m/s for both energy harvesters. The highest output power of $15.1{\mu}W$ at $14k{\Omega}$ was obtained at a wind speed of 10 m/s for the flutter wind energy harvester with the PZT-PZNN cantilever array. The results presented here reveal the strong potential for wind energy harvester applications to supply sustainable power to various IoT micro-devices.

Analysis of Glass Composition on Low k Materials (저유전율 소재에서의 유리조성에 대한 분석)

  • Na, Yoon-Soo;Hwang, Jong-Hee;Lim, Tae-Young;Shin, Hyo-Soon;Kim, Jong-Hee;Cho, Yong-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.177-177
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    • 2008
  • The effect of several $SiO_2-B_2O_3-Al_2O_3$-R(R;Ca, Sr, Ba) borosilicate glass system on sintering behavior, dielectric properties and mechanical properties of glass/ceramic composites were investigated. The amount of '+2 valency' metal elements(Ca, Sr, Ba) were examined in LTCC composite of low k glass with cordierite filler. It was sintered for 60minutes in temperature range from 850C to 950. Properties of frit and glass/ceramic composites were analyzed by DTA, XRD, SEM, Network Analyzer, UTM and so on. Dielectric constant ($\varepsilon_r$) and $Q{\times}f_0$ (Q) of the composite with 50% glass contents demonstrated $\varepsilon_r$ = 5.4 $Q{\times}f_0$ = 1600 GHz. Sintering was complete and maximum bending strength of 160MPa was obtained.

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Low k Materials for High Frequency High Integration Modules

  • Na, Yoon-Soo;Lim, Tae-Young;Kim, Jin-Ho;Shin, Hyo-Soon;Hwang, Jong-Hee;Cho, Yong-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.413-418
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    • 2009
  • Glass systems based on Ca, Sr, Ba, and Zn modified alumino-boro silicates were investigated in order to improve the dielectric and mechanical properties of a typical LTCC (low temperature co-fired ceramic) which was developed for high frequency highly-integrated modules. The glass was prepared by a typical melting procedure and then mixed with cordierite fillers to fabricate glass/ceramic composite-type LTCC materials. The amount of cordierite filler was fixed at 50 volumetric%. For an optimal glass composition of 7.5% CaO, 7.5% BaO, 5% ZnO, 10% $Al_2O_3$, 30% $B_2O_3$, and 40% $SiO_2$ in mole ratio, the resultant LTCC composite showed a dielectric constant of 5.8 and a dielectric loss ($tan{\delta}$) of 0.0009 after firing at $900^{\circ}C$. An average bending strength of 160MPa was obtained for the optimal composition.

Fabrication of 3D Aligned h-BN based Polymer Composites with Enhanced Mechanical Properties for Battery Housing (3차원으로 정렬된 h-BN을 이용한 향상된 기계적 특성을 가지는 배터리 하우징용 고분자 복합소재 제작)

  • Kiho Song;Hyunseung Song;Sang In Lee;Changui Ahn
    • Journal of Powder Materials
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    • v.31 no.4
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    • pp.329-335
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    • 2024
  • As the demand for electric vehicles increases, the stability of batteries has become one of the most significant issues. The battery housing, which protects the battery from external stimuli such as vibration, shock, and heat, is the crucial element in resolving safety problems. Conventional metal battery housings are being converted into polymer composites due to their lightweight and improved corrosion resistance to moisture. The transition to polymer composites requires high mechanical strength, electrical insulation, and thermal stability. In this paper, we proposes a high-strength nanocomposite made by infiltrating epoxy into a 3D aligned h-BN structure. The developed 3D aligned h-BN/epoxy composite not only exhibits a high compressive strength (108 MPa) but also demonstrates excellent electrical insulation and thermal stability, with a stable electrical resistivity at 200 ℃ and a low thermal expansion coefficient (11.46×ppm/℃), respectively.

Development of Ceramic Composite Membranes for Gas Separation: IV. Permeation Characteristics of ${\gamma}$-Alumina Membranes (기체분리용 세라믹 복합분리막의 개발 : IV. ${\gamma}$-알루미나 분리막의 투과 특성)

  • 현상훈;강범석;최두진
    • Journal of the Korean Ceramic Society
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    • v.29 no.12
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    • pp.970-980
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    • 1992
  • ${\gamma}-alumina$ membranes were prepared by sol-gel dip coating or pressurized coating of boehmite sols on slipcasted ${\gamma}-alumina$ support tubes. The particle size of sols synthesized via the modified Yoldas-method could be controlled below 5 mn according to the mole ratio of nitric acid/aluminumtri-sec-butoxide (0.07~1.0). The reproducible crack-free composite membranes were produced by the 2nd dip coating or the pressurized coating technique using very stable sols with the particle size of 45 nm. Nitrogen gas permeability through the top-layer in the composite membrane was about $70~55{\times}10^{-7}\;mol/m^2{\cdot}s{\cdot}Pa$. The thermal stability of the top layer was proved to be good enough upto the heat-treatment temperature of $500^{\circ}C$.

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Synthesis and Characterization of Alumina Composite Membrane by Al Evaporation and Thermal Oxidation (알루미늄의 진공증발과 열산화에 의한 알루미나 복합분리막의 제조 및 특성분석)

  • 이동호;최두진;현상훈
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.349-358
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    • 1995
  • The ceramic composite membrane was synthesized by thermal oxidation after evaporation of Al on the support prepared by slip casting process. Oxidation was performed at $700^{\circ}C$ and 80$0^{\circ}C$ under dry oxygen atmosphere. It was considered as optimum oxidation condition that the membrane showed a knudsen behaviro. A further oxidation resulted in an increase of gas permeability because top layer became densified. Then, a multi-layered composite membrane was synthesized through a sol-gel method, evaporation and thermal oxidation of Al coating processes. While the membrane was thermally stable up to 80$0^{\circ}C$, gas permeability was rapidly decreased even at a slight amount of deposition of Al.

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Fabrication and Biomechanical Characteristics of Composite Ceramic Bone Scaffolds for Bone Tissue Engineering (골 생체조직공학을 위한 복합 세라믹 골 지지체의 제조와 생체역학적 특성)

  • Kim E. S.;Chung J. H.
    • Journal of Biosystems Engineering
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    • v.29 no.5 s.106
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    • pp.457-466
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    • 2004
  • Novel porous composite ceramic bone scaffolds composed of biodegradable PHBV(polyhydroxybutyrate-co-hydroxyvalerate) and TA(toothapatite) have been fabricated for bone tissue engineering by a modified solvent casting and particulate leach-ing method with salt-contained heat compression technique. The results of this study suggest that the PHBV-TA composite scaffold, especially the scaffold containing 30 weight$\%$ of TA may be a good candidate far bone tissue engineering of non-load bearing area in oral and maxillofacial region.

Numerical and Experimental Evaluation of Tensile Failure in Continuous Fiber Reinforced Ceramic Composite

  • Kwon, Oh Heon;Park, Keyoung Dong;Watanabe, Katsuhiko
    • International Journal of Safety
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    • v.2 no.1
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    • pp.23-27
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    • 2003
  • Recently, continuous fiber reinforced ceramic composite(CFCC) has attracted attention to a number of engineers because of its significant benefit for several industrial area. This work was conducted to provide a basic characteristic of CFCC for tensile loading condition. The numerical analysis by general purpose finite element program was accomplished and compared with an experimental tensile test. The stress strain curves were expressed well by the numerical analysis and the first matrix cracking stress was in accordance with that of the experimental result. Moreover, fracture pattern was shown by kill command graphically.

Tribological Properties of Raction-Bonded SiC-Graphite Composites (반응소결 SiC-graphite 복합체의 마찰마모특성)

  • 백용혁;신종윤;곽효섭;박용갑
    • Journal of the Korean Ceramic Society
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    • v.33 no.5
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    • pp.479-484
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    • 1996
  • The tribological properties of ceramics are very important in the application to engineering ceramic parts such as mechanical seal slurry valve disc and so on. In this study the effect of graphite addition on the mechanical and tribological properties of RBSC/graphite composites were investigated. The composites were prepared by adding graphite powder to the mixture of SiC powder metallic siliconcarbon black and alumina. Bending strength water absorption friction coefficient the amount of worn out material at a certain time and maximum surface roughness(Rmax) of the prepared composites were measured and crystalline phases were examined with XRD. The composite containing 5 vol% graphite powder showed improved bending strength due to high green density and decreased friction coefficient and wear resistance. The friction coefficient and the wear resistance of the composite were increased by adding graphite powder up to 10 vol% They decreased however as increasing the amount of graphite powder more that 10vol% There was no linear relationship between the tribological properties and bending strength of the composites.

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