• Title/Summary/Keyword: central electrode

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Electrochemical Investigation of Acetaminophen with a Carbon Nano-tube Composite Film Electrode

  • Li, Chunya;Zhan, Guoqing;Yang, Qingdan;Lu, Jianjie
    • Bulletin of the Korean Chemical Society
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    • v.27 no.11
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    • pp.1854-1860
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    • 2006
  • Electrochemical behaviors of acetaminophen at a muti-wall carbon nano-tube composite film modified glassy carbon electrode were investigated by cyclic voltammetry, linear sweep voltammetry and chronocoulometry. Compared with that obtained at the unmodified electrode, the peak currents were enhanced significantly, and the oxidation peak shifted towards more negative potential with the reduction peak shifted positively. The peak-to-peak separation turned narrow, and suggested that the reversibility was improved greatly. Experimental parameters, such as scan rate, pH and accumulation conditions were optimized. It was found that a maximum current response can be obtained at pH = 5.0 after accumulation at -0.50 V for 80 s. The oxidation peak current was found to be linearly related to acetaminophen concentration over the range of $5.0{\times}10^{-7}\;\sim\;1.0{\times}10^{-4}$ mol $L^{-1}$ with a detection limit of $5.0{\times}10^{-8} $mol $L^{-1}$. A convenient and sensitive electrochemical method was developed for the determination of acetaminophen in a commercial paracetamol oral solution. Its practical application demonstrated that it has good selectivity and high sensitivity.

The Ozone Generation and Discharge Noise Characteristics of Superposed Discharge Noise Characteristics of Superposed Discharge Type Ozonizer Using Three-Phase Voltage (3상 전압을 사용한 중첩방전형 오존발생기의 오존생성 및 방전잡음특성)

  • 전병준;송현직;김영훈;최상태;이광식
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.14 no.2
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    • pp.59-67
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    • 2000
  • In this paper, an ozonizer, which can supply individual and superposed silent discharge using three-phase voltage has been designed and manufactured. The ozonizer consists of 3 electrodes(Central Electrode, Internal Electrode and External Electrode and External electrode) and 2 gaps (gap between Central Electrode and Internal Electrode, gap between Internal Electrode and External Electrode). Ozone is generated according to voltage supplying method to each electrode by individual silent discharge and three-phase superposed discharge. The characteristics of ozone generation were investigated with variation of discharge power and the flow rate of supplied gas (O2). In case of individual silent discharge, the maximum values of ozone concentration, ozone generation and ozone yield were obtained between internal electrode and external electrode, and its values were 2300[ppm], 570[mg/h] and 745[g/kWh] respectively. Each maximum value was 5039[ppm], 1773[mg/h] and 851[g/kWh] respectively, when three-phase superposed silent discharge was employed. Therefore, characteristics of ozone generation with three-phase voltage are improved compared with single-phase voltage because silent discharge is generated continuously.

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Intraoperative Neurophysiological Monitoring for Optimal Brain Mapping

  • Park, Sang-Nam;Park, Sang-Ku
    • Korean Journal of Clinical Laboratory Science
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    • v.45 no.4
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    • pp.170-179
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    • 2013
  • There is a correct way to avoid any sequale in the central motor area during neurosurgery procedures. A clear way to find the circumference of the central sulcus, central motor, and sensory areas by giving cortical electrical stimulation to the central motor area immediate after surgery is proposed. Looking at patients who underwent brain surgery September 2009 to July 2013, the central sulcus and speech areas around the central area of the brain was investigated, using the practices of either a localized brain map check or a direct cortical electrical stimulation test. Brain maps localized around the surgical site through functional movement or speech areas were identified. Accurate tests done during surgery without damage to motor neurons or after surgery were conducted smoothly. Although successful brain map test localization can be accomplished, there are some factors that can interfere. The following phenomena can reverse the phase: (1) the first sensory / motor in the case of patients severe nerve damage; (2) placement of the electrode on top of the vessel; (3) presence of a brain tumor near the brain cortex; (4) use of anesthesia if patient cooperation is difficult; and (5) location of the electrode position and stimulus is inappropriate.

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The Characteristics of Ozone Generation Synergy Effect for 3 Electrode-1 Discharge Gap Silent Discharge Type Ozonizer using Frequency-Vacuum (주파수-진공도를 이용한 3전극-1방전간극 무성방전형 오존발생기의 오존생성 상승 효과 특성)

  • Song, Hyun-Jig
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.8
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    • pp.94-101
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    • 2005
  • The silent discharge type ozonizer with three electrodes(central electrode, internal electrode, and external electrode) and one discharge gap(discharge gap between internal electrode and external electrode) has been designed and manufactured. It is a silent discharge type ozonizer for which the AC high frequency voltages applied to the central electrode within vacuum discharge tube and the internal electrode for which the external electrode is a ground Ozone is generated by silent discharge in discharge gap. At the moment, discharge characteristics and ozone generation characteristics were investigated in accordance with vacuum of discharge tube, frequency of AC power source, discharge power of ozonizer, and quantity of supplied oxygen gas. In consequence, ozone characteristics proportional to vacuum of discharge tube and frequency of AC power source. The maximum value of ozone can be obtained 7,700[ppm], 460[mg/h] and 70[g/kwh].

Voltammetric Investigation of Vitamin B_6 at a Glassy Carbon Electrode and Its Application in Determination

  • Wu, Yun-Hua;Song, Fa-Jun
    • Bulletin of the Korean Chemical Society
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    • v.29 no.1
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    • pp.38-42
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    • 2008
  • The voltammetic behavior of Vitamin B6 (VB6) was studied at a glassy carbon electrode in phosphate buffers using cyclic, linear sweep and differential pulse voltammetry. The oxidation process was shown to be irreversible over the entire pH range studied (4.0-10.0) and was adsorption controlled. The adsorption amount of VB6 on the glassy carbon electrode was examined by chronocoulometry and the value of n, product of transfer coefficient and number of electrons transferred in the rate determining step, was determined from Tafel plot. VB6 was determined by differential pulse voltammetry and the peak current was found linearly with its concentration in the range of 3 10-7-2 10-4 mol L-1. The detection limit was 1 10-7 mol L-1. The procedure was successfully applied for the assay of VB6 in tablets.

The Characteristics of the Complex Discharge Type Ozonizer using Applied Voltage of a Inverse-Polarity and a Screw Type Electrode (역극성 전압인가와 나사형 전극을 이용한 복합방전형 오존발생기의 특성)

  • Song, Hyun-Jig
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.9
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    • pp.80-85
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    • 2011
  • In this paper, complex discharge type ozonizer with a screw type electrode has been designed and manufactured for environmental improvement using low power and high efficency ozoniazer. The complex discharge type ozonizer is equipped with three electrodes{central electrode(CE), internal electrode(IE) and external electrode(EE)}. Ozone of the complex discharge type ozonizer is generated by superposition of silent discharge and surface discharge in discharge space as a screw type CE and IE are respectively applied to AC high voltage of inverse-polarity has $180[^{\circ}]$ phase difference, EE is common electrode. In this time, when oxygen has been used as supplied gas, the maximum values of ozone concentration, ozone generation and ozone yield were obtained as 8,334[ppm], 3,249[mg/h] and 65.3[g/kwh].

Study on the Evaluation of TRS-398 Quality Factors with Central Electrode Corrections for Small Cylindrical Chambers (소형 전리함에 대한 TRS-398 선질인자 계산과 중심전극 보정에 관한 연구)

  • Kang, Yeong-Rok;Lee, Chang-Yeol;Kim, Jin-Ho;Moon, Young-Min;Kwak, Dong-Won;Kang, Sang-Koo;Kim, Jeung-Kee;Yang, Kwang-Mo;Jeong, Dong-Hyeok
    • Progress in Medical Physics
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    • v.22 no.3
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    • pp.148-154
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    • 2011
  • The quality factors ($k_{Q,Q_0}$) were evaluated by appling the results recently studied for the effect of central electrode in TRS-398 protocol. The PTW-31010 and IBA-CC13 chambers were used in this study. The quality factors were calculated as a function of beam quality for high energy electron and photon beams and compared with data currently used in TRS-398 protocol. In the PTW-31010 chamber using aluminium electrode, appling the new central electrode collections, the quality factors were 0.4% and 0.9% higher than current TRS-398 data for high energy photon and electron beams respectively. In the IBA-CC13 chamber using C-552 electrode, there are no variations in quality factors compared to TRS-398 data currently used.

Facile Electrodeposition Technique for the Fabrication of MoP Cathode for Supercapacitor Application

  • Samanta, Prakas;Ghosh, Souvik;Murmu, Naresh Chandra;Lee, Joong Hee;Kuila, Tapas
    • Composites Research
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    • v.34 no.6
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    • pp.345-349
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    • 2021
  • The continued environmental pollution caused by fossil fuel consumption has prompted researchers around the world to develop environmentally friendly energy technologies. Electrochemical energy storage is the significant area of research in this development process, and the research significance of supercapacitors in this field is increasing. Herein, a simple electrodeposition synthetic route was explored to develop the MoP layered cathode material. The layered structure provided a highly ion-accessible surface for smooth and faster ion adsorption/desorption. After Fe was doped into MoP, the morphology of MoP changes and the electrochemical performance was significantly improved. Specific capacitance value of the binder-free FeMoP electrode was found to be 269 F g-1 at 2 A g-1 current density in 6 M aqueous KOH electrolyte. After adding Fe to MoP, an additional redox contribution was observed in the redox conversion from Fe3+ to Fe2+ redox pair, and the charge transfer kinetics of MoP was effectively improved. This research can provide guidance for the development of supercapacitor electrode materials through simple electrodeposition technology.

Anodal Effects of Transcranial Direct Current Stimulation on the Excitability of Central Neuron (양극 경두개 직류 전기 자극이 중추신경원의 흥분성에 미치는 영향)

  • Lim, Young-Eun;Jung, Jin-Sun;Lee, Jeong-Woo
    • Journal of the Korean Academy of Clinical Electrophysiology
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    • v.9 no.2
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    • pp.19-24
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    • 2011
  • Purpose : This study is to examine the effects of transcranial direct current stimulation on the excitability of the central neuron. Methods : This study selected 24 suitable women in their twenties. A positive electrode of transcranial direct current stimulation was placed on the primary motor area (M1) C4 and a negative electrode was placed on the left supraobital. A stimulation of 0.04mA/$cm^2$ was applied for 20 minutes. H-reflex and V wave used diagnostic electromyography. An active electrode was placed at the muscle belly of the medial gastrocnemius muscle at a prone posture. An electrical stimulation was given to the posterior tibial nerve. Measurements were made before and after the stimulation. All data were analyzed with SPSS 12.0 and between each measuring before and after the change of the H-reflex and V wave amplitude. Results : There were no significant differences in all H wave, M wave, and V wave amplitude before and after transcranial direct current stimulation. There were no significant differences in the change of H/M ratio and V/M ratio before and after transcranial direct current stimulation. Conclusion : We know that transcranial direct current stimulation cannot have an influence on a normal grown-up person's central neuron.

Fabrication and Characterization of Multi-Channel Electrode Array (MEA) (다중 채널 전극의 제작 및 특성 평가)

  • Seong, Rak-Seon;Gwon, Gwang-Min;Park, Jeong-Ho
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.51 no.9
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    • pp.423-430
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    • 2002
  • The fabrication and experimentation of multi-channel electrodes which enable detecting and recording of multi-site neuronal signals have been investigated. A multi-channel electrode array was fabricated by depositing 2000${\AA}$ thick Au layer on the 1000${\AA}$ thick Ti adhesion layer on a glass wafer. The metal paths were patterned by wet etching and passivated by depositing a PECVD silicon nitride insulation layer to prevent signals from intermixing or cross-talking. After placing a thin slice of rat cerebellar granule cell in the culture ring located in central portion of the multi-channel electrode plate, a neuronal signal from an electrode which is in contact with the cerebellar granule cell has been detected. It was found that the electrode impedance ranges 200㏀∼1㏁ and the impedance is not changed by cleaning with nitric acid. Also, the impedance is inversely proportion to the exposed electrode area and the cross-talk is negligible when the electrode spacing is bigger than 600$\mu\textrm{m}$. The amplitude and frequency of the measured action potential were 38㎷ and 2㎑, which are typical values. From the experimental results, the fabricated multi-channel electrode array proved to be suitable for multi-site neuronal signal detection for the analysis of a complicated cell network.