• 콘크리트학회논문집
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• 제26권3호
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• pp.369-375
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• 2014

이 연구에서는 RC기둥의 내화실험 후 콘크리트 시멘트 매트릭스의 구성성분의 변화를 조사하였다. 표준화재곡선에 따라 내화실험을 수행하고 상온에서 기둥을 식힌 후, 표면과 깊이 40 mm, 80 mm, 단면중심(175 mm) 지점에서의 샘플을 채취하였다. 수화된 시멘트의 대표적인 구성성분인 칼슘-실리케이트 수화물(C-S-H)와 수산화칼슘의 구성성분 변화를 열중량분석기(TGA)와 X선 회절분석기(XRDA)를 이용하여 분석하였다. 핵자기공명기(NMR)를 이용하여, C-S-H의 실리케이트 중합도변화를 관찰하였다. 세 가지 분석 결과를 종합해 본 결과 내하실험에서 $236^{\circ}C$를 경험한 중심부(175 mm)에서의 시멘트 매트릭스의 상태가 $618^{\circ}C$를 경험한 깊이 40 mm에서의 시멘트 매트릭스의 상태와 유사하며, 가장 건전하다고 판단되는 시멘트 매트릭스는 $419^{\circ}C$를 경험한 깊이 80 mm 지점에서의 시멘트 매트릭스였다. 이는 콘크리트의 경험 온도와 철근의 온도제한에 의한 내화규정은 RC구조물의 내화성능을 과대평가할 수 있음을 나타내며, 향후 내화규정의 마련에 유용하게 활용될 것으로 판단된다.

• 대한치과보철학회지
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• 제36권6호
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• pp.789-805
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• 1998

The purpose of this study was to compare the microleakage of the IPS Empress ceramic crown according to 1) margin types such as rounded shoulder and bevel, 2) margin locations such as enamel and dentine, 3) resin cement types such as Variolink and Bistite. For this study, 80 extracted premolar teeth were used. After 10 experimental dies were prepared for each group, the IPS Empress ceramic crowns were fabricated on the dies and cemented with one of two types of resin cement. After 1,000 cycles of thermal changes were given with the thermocycling unit, each specimen was sectioned with a low speed diamond saw in both the buccolingual and the mesiodistal direction. The microleakage was then measured with a stereo microscope. The obtained results were as follows : 1. Every experimental group showed microleakage. The microleakage of the crowns which had a rounded shoulder on enamel cemented with Variolink was the lowest of all. The resulting rank of the mean microleakage was rounded shoulder on enamel using Variolink(0.601mm), rounded shoulder on enamel using Bistite (0.794mm), bevel on enamel using Variolink (0.826mm), rounded shoulder on dentine using Variolink(1.054mm), bevel on enamel using Bistite(1.087mm), rounded shoulder on dentine using Bistite(1.176mm), bevel on dentine using Variolink(1.258mm), and bevel on dentine using Bistite(1.467mm). 2. The statistically significant differences in the microleakage were found in 4 cases: rounded shoulder on enamel using Variolink and bevel on dentine using Variolink, rounded shoulder on enamel using Variolink and bevel on dentine using Bistite, rounded shoulder on enamel using Bistite and bevel on dentine using Bistite, bevel on enamel using Variolink and bevel on dentine using Bistite. 3. The microleakage of rounded shoulder finish line was lower than that of bevel finish line. The statistically significant differences were found with respect to the type of finish lines. 4. The microleakage of the finish line on enamel was lower than that of finish line on dentine. The statistically significant differences were found with respect to the location of the finish lines. 5. The microleakage of the Variolink cement was lower than that of the Bistite cement. The statistically significant differences were found with respect to the resin cements.

• 대한치과보철학회지
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• 제37권5호
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• pp.658-671
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• 1999

The major influencing factors on the strength of all-ceramic crowns are types of dental ceramics, fabrication techniques, methods of abutment preparation and cementation modes of all-ceramic restorations. Zinc phosphate cement and glass-ionomer cement were used as an early lot-ing media for all-ceramic crowns. Recently many studies have reported that resin cements have more advantages in increasing the fracture strength of restorations comparing with zincphosphate cement and glass-ionomer cement. The purpose of this study is to investigate the effect of etching, silane treatment, sandblasting and dentin bonding agents on fracture strengths of dental ceramics. 40 flat dentin specimens and 40 ceramic discs of 1.5mm thickness and 8mm diameter were fabricated, and divided into 4 groups according to surface treatments. Surface treatments before cementation were as follows Group I : (ceramic) : HF etching - silane treatment - application of bonding resin (dentin) : application of dentin bonding agent Group II : (ceramic) : sandblasting - application of bonding resin (dentin) : application of dentin bonding agent Group III : (ceramic) : application of bonding resin (dentin) : application of dentin bonding agent Group IV : (ceramic) : HF etching - silane treatment - application of bonding resin (dentin) : no dentin bonding procedure Dentin specimens and ceramic discs were cemented with dual cure resin cement, and went through thermocycling. Compressive stress es were loaded on the centers of ceramic discs with Instron test-ing machine, and fracture strengths resistance for catastrophic fracture were measured The results were as follows. 1. The group I showed the highest fracture resistance. The next was group II And group III, IV followed. 2. There was a significant difference in the mean value of fracture strengths between group I and group III (p<0.05), but no significant differences between group I and group II, and group II and group III (p>0.05). 3. There was a significant difference in the mean value of fracture strengths between group I and group IV (p<0.05).

• Journal of Korean Dental Science
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• 제8권2호
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• pp.82-88
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• 2015

Purpose: To evaluate the effect of light-curing on the immediate and delayed micro-shear bond strength (${\mu}SBS$) between yttria-tetragonal zirconia polycrystal (Y-TZP) ceramics and RelyX Ultimate when using Single Bond Universal (SBU). Materials and Methods: Y-TZP ceramic specimens were ground with #600-grit SiC paper. SBU was applied and RelyX Ultimate was mixed and placed on the Y-TZP surface. The specimens were divided into three groups depending on whether light curing was done after adhesive (SBU) and resin cement application: uncured after adhesive and uncured after resin cement application (UU); uncured after adhesive, but light cured after resin cement (UC); and light cured after adhesive and light cured resin cement (CC). The three groups were further divided depending on the timing of ${\mu}SBS$ testing: immediate at 24 hours (UUI, UCI, CCI) and delayed at 4 weeks (UUD, UCD, CCD). ${\mu}SBS$ was statistically analyzed using one-way ANOVA and Student-Newman-Keuls multiple comparison test (P<0.05). The surface of the fractured Y-TZP specimens was analyzed under a scanning electron microscope (SEM). Result: At 24 hours, ${\mu}SBS$ of UUI group ($8.60{\pm}2.06MPa$) was significantly lower than UCI group ($25.71{\pm}4.48MPa$) and CCI group ($29.54{\pm}3.62MPa$) (P<0.05). There was not any significant difference between UCI and CCI group (P>0.05). At 4 weeks, ${\mu}SBS$ of UUD group ($24.43{\pm}2.88MPa$) had significantly increased over time compared to UUI group (P<0.05). The SEM results showed mixed failure in UCI and CCI group, while UUI group showed adhesive failure. Conclusion: Light-curing of universal adhesive before or after application of RelyX Ultimate resin cement significantly improved the immediate ${\mu}SBS$ of resin cement to air-abrasion treated Y-TZP surface. After 4 weeks, the delayed ${\mu}SBS$ of the non-light curing group significantly improved to the level of light-cured groups.

• 대한치과보철학회지
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• 제49권1호
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• pp.49-56
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• 2011

연구 목적: 최근 지르코니아가 전부도재관의 코어로 많이 사용되고 있다. 지르코니아와 레진 시멘트의 결합 강도를 높이기 위한 기계적, 화학적인 표면 처리 방법들이 연구되고 있다. 이 연구에서 여러 표면 처리 방법에 따른 지르코니아와 레진 시멘트의 전단결합강도를 알아보고자 한다. 연구 재료 및 방법: 80개의 지르코니아 (Lava, 3M ESPE, St. Paul, MN, USA) 시편과 80개의 지르코니아/알루미나 복합체 (Zirace, Acucera Co Inc, Korea) 시편을 디스크형태로 제작하여 에폭시레진에 매립하였다. 이들을 각각 4개의 군으로 나누어 $50\;{\mu}m$ $Al_2O_3$ sandblasting, $110\;{\mu}m$ $Al_2O_3$ sandblasting, $50\;{\mu}m$ $Al_2O_3$ sandblasting과 프라이머 (Z-PRIME Plus, Bisco Inc, Schaumburg, IL, USA) 사용, $110\;{\mu}m$ $Al_2O_3$ sandblasting과 프라이머 (Z-PRIME Plus) 사용 군으로 나누었다. 표면 처리한 지르코니아 표면에 2가지 레진 시멘 (Calibra, Panavia F)으로 접착하였다. 그 후 증류수 ($37^{\circ}C$)에 24시간 보관 후 전단 결합 강도 실험을 시행하였고, SEM을 사용하여 표면 처리한 표면과 전단강도 실험 후 파절양상을 관찰하였다. 결과: ANOVA분석에 따르면, 두 가지 종류의 시편 모두에서, 프라이머 (Z-PRIME Plus)를 사용하여 표면 처리한 군들이 전단 결합 강도가 높았다 (P < .05). 결론: 기계적 결합 강도와 함께 새로운 프라이머를 사용하는 것이 지르코니아와 레진 시멘트의 접착 강도를 증가시킨다.

• The Journal of Advanced Prosthodontics
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• 제10권2호
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• pp.79-84
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• 2018

PURPOSE. All-ceramic restorations required extensive tooth preparation. The purpose of this in vitro study was to investigate a minimally invasive preparation and thickness of monolithic zirconia crowns, which would provide sufficient mechanical endurance and strength. MATERIALS AND METHODS. Crowns with thickness of 0.2 mm (group 0.2, n=32) or of 0.5 mm (group 0.5, n=32) were milled from zirconia and fixed with resin-based adhesives (groups 0.2A, 0.5A) or zinc phosphate cements (groups 0.2C, 0.5C). Half of the samples in each subgroup (n=8) underwent thermal cycling and mechanical loading (TCML)(TC: $5^{\circ}C$ and $55^{\circ}C$, $2{\times}3,000cycles$, 2 min/cycle; ML: 50 N, $1.2{\times}10^6cycles$), while the other samples were stored in water ($37^{\circ}C/24h$). Survival rates were compared (Kaplan-Maier). The specimens surviving TCML were loaded to fracture and the maximal fracture force was determined (ANOVA; Bonferroni; ${\alpha}=.05$). The fracture mode was analyzed. RESULTS. In both 0.5 groups, all crowns survived TCML, and the comparison of fracture strength among crowns with and without TCML showed no significant difference (P=.628). Four crowns in group 0.2A and all of the crowns in group 0.2C failed during TCML. The fracture strength after 24 hours of the cemented 0.2 mm-thick crowns was significantly lower than that of adhesive bonded crowns. All cemented crowns provided fracture in the crown, while about 80% of the adhesively bonded crowns fractured through crown and die. CONCLUSION. 0.5 mm thick monolithic crowns possessed sufficient strength to endure physiologic performance, regardless of the type of cementation. Fracture strength of the 0.2 mm cemented crowns was too low for clinical application.

• 대한소아치과학회지
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• 제27권2호
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• pp.237-245
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• 2000

최근의 심미적 수복재료는 단순히 글래스아이오노머나 레진으로 구분되지 않는다. 대신에, 이들은 두 가지 전통적 재료 사이의 광범위한 한 범주 내에 위치한다. 유치 수복 재료를 선택함에 있어 임상가는 각각의 상황에 적합한 몇 가지 항목들을 고려해야 한다. 이들 중 한가지가 결합력이다. 이 연구는 특별히 상아질과 법랑질과의 상대적 인장강도를 재료별로 비교해보고자 하였다. 실험재료로는 resin-modified glass ionomer로 Fuji II LC-I와 Vitremer를, compomer로는 Dyract AP, Compoglass F 2000등이 사용되었다. 140개의 발거된 유치를 실험대상으로 각 재료의 시편을 평활하게 연마된 법랑질과 상아질 표면에 제조회사의 지시대로 부착한 후 상아질과 법랑질에 대한 상대적 전단결합강도를 측정하였다. 파절편은 실패유형 평가를 위해 주의깊게 검사되었다. 실험결과는 one-way ANOVA& Sheffe's test와 student t-test(p=0.05)로 검증하였다. 본 연구의 결과는 다음과 같았다. 1. 유치 법랑질과 상아질에 대한 전단결합강도를 측정한 결과, 법랑질에 대해서는 Z100과 Fuji II LC-I에서, 상아질에 대해서는 Z100과 Dyract AP에서 가장 높은 결합력이 나타났으며 다른 재료간에는 유의한 차이를 관찰할 수 없었다(P>0.05). 2. 각 재료내의 법랑질과 상아질에 대한 상대적 결합력을 비교평가한 결과, Dyract AP와 Vitremer를 제외한 모든 재료에서 법랑질에서 보다 높은 결합력이 관찰되었으며, Dyract AP에서는 상아질에 대한 결합력이 법랑질에 대해서보다 높게 관찰되었다(P<0.05). 3. 각 재료들의 결합실패가 일어난 파절단면을 조직학적으로 관찰한 결과, 대부분 cohesive failure를 보였고, 파절면은 치면과 매우 근접해 있었다. 일부 화학중합형 glass ionomer cement와 Vitremer에서 adhesive failure가 관찰되었다.

• 대한치과보철학회지
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• 제33권4호
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• pp.611-633
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• 1995

The pupose of this study was to compare the fracture strength of five kinds of all-ceramic crowns(Vintage, Dicor Empress-staining, Empress-layering, In-Ceram) luted with glass ionomer cerment and composite resin cement and to evaluate the effect of cements on the fracture stregth of all ceramic crowns. Five groups of twelve uniform sized all-ceramic crown specimens were fabricated. Six specimens of each group were cemented with glass ionomer cement(Fuji G.I. Cement) and the remaining six specimens of each group were etched, silane-treated, and cemented with composite resin cement(Bistite resin cement). The crowns were stored in water$(37^{\circ}C)$ for 1 day prior to loading in an Instron, using a steel ball(diameter 4mm) at a crosshead speed of 0.5mm/min. The crowns were angled $30^{\circ}$, so the steel ball contacted with the crowns 2mm lingual from the mid-incisal edge. The results obtained were summarized as follows ; 1. With G.I. cement, mean fracture load(Kg) Were : Intage : $18.33{\pm}1.47$ ; Empress-staining : $23.92{\pm}6.67$ ; Dicor : $24.0{\pm}5.81$ ; Empress-layering : $26.92{\pm}2.80$ ; In-Ceram : $51.58{\pm}6.87$ ; ANOVA revealed a significant difference existed(p<0.05) between the group A(Vintage, Dicor, Empress-staining, Empress-layering) and group B(In-Ceram). 2. With Resin cement, mean fracture load(Kg) were : Intage : $22.75{\pm}4.97$ ; Dicor : $42.75{\pm}7.07$ ; Empress-staining : $44.08{\pm}7.99$ ; Empresslayering : $50.42{\pm}5.43$ ; In-Ceram : $52.58{\pm}6.51$ ; ANOVA revealed a significatnt difference existed(p<0.05) between the group A(Vintage) and B(Dicor, Empress-staining Empress-alyering, In-Ceram). 3. Resin cement significantly increased the fracture strength of the all-ceramic crowns for Dicor(156%), Empress-staining(185%), Empress-alyering(187%)(p<0.05); but did not increase the fracture strength of Vintage(128%) and In-Ceram(101%)(p>0.05). 4. Majority of the all-ceramic crowns show a wedge fracture extending through proximal surfaces to an apex, usually apical third(with G.I. cement) or middle third(with Resin cement) of the facial surface.

• Restorative Dentistry and Endodontics
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• 제19권2호
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• pp.473-484
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• 1994

To investigate the effect of resin cement, which had been known to increase the adhesive capacity of the cast gold inlay, on the gingival marginal fit and whether the tin-planting of the beveled area affects the marginal fit, Class II cast gold inlays were made on the 25 sound molars. Control group(ZPC goup) was cemented with the ZPC by conventional method. Experimental groups were cemented with the resin cement(Super-hond & $Panavia_{EX}$) and subdivided further by the existence or nonexistence of the tin-plating of the beveled area(ST & PT groups: with plating, SNT & PNT groups: without plating). So, each group was consisted of 5 teeth and the gingival margin of each specimen was mesiodistally sectioned by 3 times and the marginal and internal gap were evaluated by the Stereo Microscope (${\times}180$) and the Scanning Electron Micrascope(${\times}5,000$) was used for examining the adhesive relationship of the resin cement to the cavity wall and to the cast gold surface. The results were as follows : 1. Marginal gap was less than internal gap in all groups. 2. ZPC and SNT(bevel without tin-plating) groups showed the least gap and gap in PNT(bevel without tin-plating) group, ST(bevel with tin-plating) group, PT(bevel with tin-plating) group showed the greater value in order in evaluation of the both internal gap and marginal gap. 3. With the exception of the relationships between ZPC and SNT groups, ST and PNT groups, relationships between any other groups showed the statistical significance in the internal gap(p<0.05). 4. In the marginal gap, all relationships between groups showed the statistical significance (p<0.05) except the relationships between ZPC and SNT groups, ST and PNT groups, ZPC and PNT groups. 5. ZPC group showed more soluble phenamena than the resin groups(ST, SNT, PT, PNT). 6. Resin cement showed the void spaces in spite of good penetration into the micro-irregularities on both the tooth surface and the cast surface. The void was shown more in PT and PNT groups than in the ST and SNT groups. 7. After the treatment of heat and desiccation for SEM specimen, resin cements were detached more easily from the tooth surface than from the cast surface.

• Restorative Dentistry and Endodontics
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• 제15권2호
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• pp.77-92
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• 1990

The purpose of this study was to evaluate the cytotoxic effects of 6 cavity liners in vitro. Human fibroblasts were cultured in ${\alpha}$-MEM and each liner was manually mixed and filled in glass ring cylinder ($8{\times}8mm$ in diameter, in height). The cylinders filled with the liners were placed in the center of the dish (35mm in diameter) containing 3ml of ${\alpha}$-MEM. Millipore filters (pore size $0.22{\mu}m$) to simulate dentin barrier were also placed between the bottom of cylinder and the dish. Then the culture dishes were stored in 5% $CO_2$ containing incubator for 5 and 10 days at the temperature of $36.6^{\circ}C$. The results of the experiments were analyzed by counting the cells in the period of 5 and 10 days respectively, and were assessed by calculating the cell multiplication rate and the relative growth rate. The experiemntal groups and the control group were compared statistically. The results of the study were summarized as follows: 1. The cell number of Zinc oxide-eugenol was $(4.13{\pm}1.31){\times}10^4$ cells/ml at 5 days and $(4.32{\pm}1.61){\times}10^4$ cells/ml at 10 days. 2. The cell number of Cavitec was ($8.35{\pm}2.87{\times}10^4$ cells/ml and $(10.08{\pm}5.10){\times}10^4$ cells/ml at 5 and 10 days respectively. 3. The cell number of Dycal was $(13.56{\pm}3.89){\times}10^4$ cells/ml at 5 days and $(34.75{\pm}8.85){\times}10^4$ cells/ml at 10 days. 4. The cell number of life was $(11.46{\pm}3.32){\times}10^4$ cells/ml and $(21.92{\pm}6.18){\times}10^4$ cells/ml at 5 and 10 days. 5. The cell number of Base cement was $(13.73{\pm}3.73){\times}10^4$ cells/ml and $(36.68{\pm}5.20){\times}10^4$ cells/ml at 5 and 10 days. 6. The cell number of Dentin cement was $(13.58{\pm}3.90){\times}10$ cells/ml and $(66.95{\pm}24.09){\times}10$ cells/ml at 5 and 10 days. 7. The cell multiplication rate of zinc oxide-eugenol cements was significantly less than that of the calcium hydroxide and glass ionomer cement. (P < 0.05)