• Korean Journal of Mineralogy and Petrology
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• v.33 no.4
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• pp.407-417
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• 2020

The capacity of the designated landfill site for asbestos-containing waste is approaching its limit because the amount of asbestos-containing slate is increasing every year. There is a need for a method that can safely and inexpensively treat asbestos-containing slate in large capacity and at the same time recycle it. A cement kiln can be an alternative for heat treatment of asbestos-containing slate. We intend to develop a pilot scale device that can simulate the high temperature environment of a cement kiln using a high temperature plasma reactor in this study. In addition, this reactor can be used to inactivate asbestos in the slate and to synthesize one of the minerals of cement, to confirm the possibility of recycling as a cement raw material. The high-temperature plasma reactor as a pilot scale experimental apparatus was manufactured by downsizing to 1/50 the size of an actual cement kiln. The experimental conditions for the deactivation test of the asbestos-containing slate are the same as the firing time of the cement kiln, increasing the temperature to 200-2,000℃ at 100℃ intervals for 20 minutes. XRD, PLM, and TEM-EDS analyses were used to characterize mineralogical characteristics of the slate before and after treatment. It was confirmed that chrysotile [Mg3Si2O5(OH)4] and calcite (CaCO3) in the slate was transformed into forsterite (Mg2SiO4) and calcium silicate (Ca2SiO4), a cement constituent mineral, at 1,500℃ or higher. Therefore, this study may be suggested the economically and safely inactivating large capacity asbestos-containing slate using a cement kiln and the inactivated slate via heat treatment can be recycled as a cement raw material.

• Proceedings of the KSR Conference
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• 2001.05a
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• pp.408-415
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• 2001

Hardening agent has been the traditional material for surface soil stabilization of soft ground. The aim of this study if to determine optimal mixture ratio of hardening agent in accordance with the required design specifications. Hardening agent consists of fly ash, gypsum, slag and cement for the ettringite hydrates and if effective for early stabilization of unconsolidated soil. The raw ground material is the clay that is widely found here and there in Korea. In this study, preliminary tests were performed to get optimal mixture ratio of stabilizer ingredient and marine clay in Jinhae was used to get physical and chemical properties. Laboratory tests of 50 stabilized soils were performed to get optimal mixture ratio for 16-stabilizer materials of 6 types, and mixture ratio of stabilizer ingredient and marine clay was determined.

• Journal of Ocean Engineering and Technology
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• v.15 no.1
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• pp.92-97
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• 2001

Hardening agents have been the traditional material for surface soil stabilization of soft ground. This study aims at determining the optimal mixture ratio of the hardening agent in accordance with the required design specifications. Hardening agents which consists of fly ash, gypsum, slag and cement for the ettringite hydrates is effective for early stabilization of unconsolidated soil. The raw ground material is the clay that is widely found in Korea. In this study, preliminary tests were performed to get an optimal mixture ratio of the stabilizer ingredient and marine clay from Jinhae was used to get physical and chemical properties. Laboratory tests of 50 stabilized soils were performed to get an optimal mixture ratio for 16-stabilizer materials of 6 types, and a mixture ratio of the stabilizer ingredient and marine clay was determined.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.585-588
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• 2006

The environment-friendly building material, photocatalyst/scoria/loess concrete, was prepared using scoria and loess (which have merits as building materials) and photocatalyst (which has the functions to compose the environmental contaminants and of self cleaning). In order to apply this material as a building material, the compressive and flexible strengths, and water absorptivity (which have been set by Korea Industrial Standard) were measured. The optimum mixing ratio of photocatalyst/scoria/loess concrete was obtained at the condition of $393kg/m^3$ of coarse aggregate, $802kg/m^3$ of fine aggregate in case of scoria, $80kg/m^3$ of loess, $12kg/m^3$ of photocatalyst, $400kg/m^3$ of cement, and $2kg/m^3$ of AE water reducing agent. The photocatalyst/scoria/loess concrete prepared by above mixing ratio of raw materials showed 25 MPa of compressive strength, $3.8{\sim}4.6$ MPa of flexible strength and $11.4{\sim}12.0%$ of water absorptivity, indicating that the quality of this material was suitable for Korea Industrial Standard (more than 21 MPa for compressive strength, more than 2.0 MPa for flexible strength in case of lightweight aggregate, and less than 15 % for water absorptivity in case of clay brick) for using as a building material.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.16-24
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• 2023

Coal ash generated from thermal power plants using briquettes contains Si, Al, and Fe components. These components are the main components required for the manufacture of cement clinker. In particular, Al and Fe components form the interstitial phase of cement clinker and have an important effect on the sintering of cement clinker. In this study, a large amount of coal ash was applied as a raw material for cement clinker by content, and the mineral formation process of cement clinker to which coal ash was applied was confirmed by sintering temperature. It was confirmed that the intermediate phase was generated in the sintering temperature range of 1050 ~ 1150 ℃ in the cement clinker to which a large amount of coal ash was applied. As the content of coal ash increased, the production amount of the intermediate phase increased. The phase produced by the addition of coal ash is expected to be converted to calcium silicate phase and interstitial phase and disappear above 1350 ℃. The cement clinker applied with a large amount of coal ash at 1450 ℃ formed well-developed minerals equivalent to the standard cement clinker.

• Korean Journal of Materials Research
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• v.34 no.6
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• pp.291-302
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• 2024

In this paper, iron ore tailings (IOT) were separated from the tailings field and used to prepare cement stabilized macadam (CSM) with porous basalt aggregate. First, the basic properties of the raw materials were studied. Porous basalt was replaced by IOT at ratios of 0, 20 %, 40 %, 60 %, 80 %, and 100 % as fine aggregate to prepare CSM, and the effects of different cement dosage (4 %, 5 %, 6 %) on CSM performance were also investigated. CSM's durability and mechanical performance with ages of 7 d, 28 d, and 90 d were studied with the unconfined compression strength test, splitting tensile strength test, compressive modulus test and freeze-thaw test, respectively. The changes in Ca²⁺ content in CSM of different ages and different IOT ratios were analyzed by the ethylene diamine tetraacetic acid (EDTA) titration method, and the micro-morphology of CSM with different ages and different IOT replaced ratio were observed by scanning electron microscopy (SEM). It was found that with the same cement dosage, the strengths of the IOT-replaced CSM were weaker than that of the porous basalt aggregate at early stage, and the strength was highest at the replaced ratio of 60 %. With a cement dosage of 4 %, the unconfined compressive strength of CSM without IOT was increased by 6.78 % at ages from 28 d to 90 d, while the splitting tensile strength increased by 7.89 %. However, once the IOT replaced ratio reached 100 %, the values increased by about 76.24 % and 17.78 %, which was better than 0 % IOT. The CSM-IOT performed better than the porous basalt CSM at 90 d age. This means IOT can replace porous basalt fine aggregate as a pavement base.

• Journal of the Korea Institute of Building Construction
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• v.22 no.3
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• pp.251-258
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• 2022

In the cement industry, in order to reduce CO₂ emissions, technology for raw materials substitution and conversion, technology for improving process efficiency of utilizing low-carbon new heat sources, and technology for collecting and recycling process-generated CO₂ are being developed. In this study, we conducted a basic experiment to contribute to the development of CSC that can store CO₂ as carbonate minerals among process-generated CO₂ capture and recycling technologies. Three types of CSC clinker with different SiO₂/(CaO+SiO₂) molar ratios were prepared with the clinker raw material formulation, and the characteristics of the clinker were analyzed. As a result of analysis and observation of CSC clinker, wollastonite and rankinite were formed. In addition, as a result of the carbonation test of the CSC paste, it was confirmed that calcite was produced as a carbonation product. The lower the SiO₂/(CaO+SiO₂) molar ratio in the CSC clinker chemical composition, the lower the wollastonite production amount, and the higher the rankinite production amount. And the amount of calcite production increased with the progress of carbonation of the CSC paste specimen. It is judged that rankinite is more reactive in mineralizing CO₂ than wollastonite.

• Resources Recycling
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• v.16 no.1 s.75
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• pp.44-53
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• 2007

The Jeonju-Il mine tailings contain large quantities of $SiO_2\;and\;Al_2O_3$ and lesser quantities of metallic components. In this study, we studied about the possibility of using mine tailings as a raw material in various industries. it was found that the sintered mine tailings had a good quality in every respect such as chromaticity, firing shrinkage and water absorption etc. Therefore if can substitute clay mineral in the ceramic industry. Also it can substitute about 2.94% of the raw materials of ordinary portland cement. We can use the coarse tailing as the fine aggregate for the ready-mixed mortar; and the fine tailing, as the filler for the bituminous paving mixture; because both products were not only suitable for Korea industrial standard in quality, but also environmentally harmless.

• Resources Recycling
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• v.20 no.6
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• pp.71-77
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• 2011

Raw mix of molten clinker was fabricated using blast furnace slag as starting material. Raw mix was melted at 1620 for molten clinker fabrication. Color and mineral composition of molten clinker was investigated by XRD and colorimeter. It was found that the molten clinker contains alite and belite equivalent to OPC clinker mineral and shows higher whiteness value than that of OPC. Whiteness of the molten clinker decreased with LSF and SM. Also the whiteness value of the slag cement using molten clinker was higher than that of common slag cement.

• Resources Recycling
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• v.27 no.1
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• pp.3-13
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• 2018

3D printing, also known as Additive Manufacturing (AM), is being positioned as a new business model of revolutionizing paradigms of existing industries. Launched in early 2000, 3D printing technology for architecture has also advanced rapidly in association with machinery and electronics technologies mostly in the United States and Europe. However, 3D printing systems for architecture require different mechanical characteristics from those of cement/concrete raw materials used in existing construction methods. Accordingly, in order to increase utilization of raw materials produced in the cement and resource recycling industry, it is necessary to develop materials processing and utilization technology, to secure new property evaluation and testing methods, and to secure database related to environmental stability for a long period which aims to reflect characteristics of an architectural 3D printing technology.