• Nuclear Engineering and Technology
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• v.54 no.9
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• pp.3235-3241
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• 2022

The Korea Atomic Energy Research Institute (KAERI) is planning the construction of the KIJANG Research Reactor (KJRR) for stable supply of ⁹⁹Mo. The Fission ⁹⁹Mo Production Process (FMPP) of KJRR produces solid waste such as spent uranium cake and alumina cake, and liquid waste in the form of intermediate level liquid waste (ILLW) and low level liquid waste (LLLW). This study thus established the operating range and optimum operating conditions for the cementation of ILLW from FMPP. It also evaluated whether cement waste form samples produced under optimum operational conditions satisfy the waste acceptance criteria (WAC) of a disposal facility in Korea (Korea radioactive waste agency, KORAD). Considering economic feasibility and safety, optimum operational conditions were achieved at a w/c ratio of 0.55, and the corresponding salt content was 5.71 wt%. The cement waste form samples prepared under optimum operational conditions were found to satisfy KORAD's WAC when tested for structural stability and leachability. The results indicate that the proposed cementation conditions for the disposal of ILLW from FMMP can be effectively applied to KJRR's disposal facility.

• Journal of Life Science
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• v.25 no.6
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• pp.615-623
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• 2015

This study investigated the effects of dissolved cement powder on Zacco koreanus by analyzing morphophysiological changes. The gills exposed to dissolved cement powder developed abnormal shapes in their secondary lamellae and increased numbers of mucous cells after long-term exposure. Additionally, clubbing, edema, and exfoliation of the epithelial cells were observed in the secondary lamellae. In the kidney tissue, the space in Bowman’s capsule was widened, and in the integument tissue the arrangement of the dermis was irregular due to the thinned epidermis. These results suggest that long-term exposure to cement powder can significantly affect morphological change, resulting death. The activities of antioxidant enzymes and LDH tended to increase commensurately with the duration of cement exposure. It was concluded that up-regulated proteins were the stress proteins involved in myofibrillar-protein production and down-regulated proteins were involved in glycolysis and energy metabolism after the integument’s exposure to cement. According to these results dissolved cement powder is a serious threat to the survival of fish because it causes morphological changes and weakens physiological activity in Z. koreanus tissues.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.364-372
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• 2023

By applying coarse-grained limestone and unprocessed coal ash as sintering raw materials for cement clinker, the microstructure and distribution of chemical components of cement clinker were compared and examined. Samples using coarse limestone as a raw material for cement clinker showed a decrease in sinterability compared to samples using reagent-grade raw materials. Samples using coal ash showed a tendency for some increase in sinterability. In samples using coarse limestone and coal ash, the formation of Belite was high at 1350 ℃. The conversion rate from Belite to Alite was high in the range of 1350~1450 ℃. Samples using coal ash showed stable formation of interstitial phase in the range of 1350 to 1450 ℃. The microstructure and chemical composition distribution of cement clinker sintered at 1350~1450 ℃ showed that all samples showed a form and composition distribution in which the calcium silicate phase and interstitial phase were clearly distinguished.

• Journal of Microbiology and Biotechnology
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• v.11 no.4
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• pp.558-563
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• 2001

A new alkalophilic strain of Bacillus pumilus JB¬05 producing bleach-stable and halo-tolerant alkaline protease was isolated from cement industry effluents in Karnataka, India. The effects of carbon and nitrogen sources on protease production by this alkalophilic strain were observed after a 30-h incubation. A high level of alkaline protease activity was obtained in the presence of starch as the carbon and peptone as the nitrogen sources. The partially purified enzyme showed an optimum temperature and pH activity at $58^{\circ}C$ and 10.5, respectively. The enzyme was completely inhibited by PMSF (95.0%) indicating it as a serine protease. It is bleach-stable as it retained 35% original activity in the presence of 10% (v/v) hydrogen peroxide at $30^{\circ}$C after 2 h and is halo-tolerant as it retained 70% original activity in the presence of 2.5 M sodium chloride at $30^{\circ}C$ after 2 h incubation.

• Advances in concrete construction
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• v.2 no.2
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• pp.77-89
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• 2014

The properties of fresh and hardened concrete made using three types of artificial cold bonded aggregates are determined. The properties, namely, slump, water absorption, compressive strength and splitting tensile strength of concrete containing artificial aggregate are reported. The variables considered are aggregate type and water-to-cement ratio. Three types of cold bonded aggregates are prepared using fly ash and quarry dust. The water-to-cement ratio of 0.35, 0.45, 0.55 and 0.65 is used. The test result indicates that artificial aggregates can be recommended for making the concrete up to a strength grade of 38 MPa. The use of quarry dust in the production of artificial aggregate mitigates environmental concerns on disposal problems of the dust. Hence, the alternate material proposed in this study is a green technology in concrete production.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.248-249
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• 2017

Red mud is an industrial by-product produced during the manufacturing aluminum hydroxide (Al(OH)₃) and aluminum oxide(Al₂O₃) from Bauxite ores. In Korea, approximately 2tons of red mud in a sludge form with 40~60% moisture content is produced when 1 ton of Al₂O₃ is produced through the Bayer process. An annual production of approximately 20tons are produced by company K, which is responsible for most of the domestic production. Therefore, in order to utilize Red Mud in the construction industry, this study evaluated the pore characteristics of ordinary portland cement mortar according to the red mud replacement ratio.

• Journal of the Korean Ceramic Society
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• v.47 no.3
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• pp.216-222
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• 2010

Portland cement has been restricted in applications to ecological area because of its environmental harmfulness and the $CO_2$ emission during a production process. Geopolymer materials attract some attention as an inorganic binder due to their superior mechanical and eco-friendly properties. In this study, geopolymer-based cement was prepared by using aluminosilicate minerals (flyash, meta-kaolin) with alkaline-activators and its compressive strength with concentration of alkaline-activators was investigated. Aluminosilicate-based geopolymers were obtained by mixing aluminosilicate minerals, alkaline solution (NaOH or KOH with different concentration) and water-glass under the vigorous stirring for 20 min. Compressive strength after curing at $30^{\circ}C$ for 3 days increased with the concentration of alkaline-activator due to the enhanced polymerization of the aluminosilicate materials and dense microstructure. Aluminosilicate-based geopolymer cement using KOH as an alkaline-activator showed high compressive strength compared with NaOH activator. In addition, geopolymer cement using fly-ash as a raw material showed higher compressive strength than that of meta-kaolin.

• Journal of the Korean GEO-environmental Society
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• v.9 no.7
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• pp.37-43
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• 2008

The unconfined compressive strength of soil-cement mixed with red mud, an industrial by-product of alumina production, was investigated in the laboratory. The investigation involved laboratory tests under the various conditions such as red mud content, cement content, fly ash content and ratio of soil replacement with sands. The unconfined compressive strength tests were performed at 7, 14 and 21 days after specimen preparation. Results of the study show that the unconfined compressive strength increased as red mud and fly ash content decreased and cement content increased. Increasing the soil replacement ratio with sands had an insignificant effect on compressive strength because the soil had a similar particle size as the replacement sands.

• Advances in environmental research
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• v.3 no.4
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• pp.337-353
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• 2014

The determination of the effectiveness of the immobilization of blasting dust (waste generated in galvanic activities) in cement matrix, as well of mechanical, physical and microstructural properties of concrete paving blocks produced with partial replacement of cement was the objective of this work. The results showed that blasting dust has high percentage of silica in the composition and very fine particle size, characteristics that qualify it for replacement of cement in manufacturing concrete blocks. The replacement of Portland cement by up to 5% residues did not cause a significant loss in compressive strength nor increase in water absorption of the blocks. Chemical tests indicated that there is no problem of leaching or solubilization of contaminants to the environment during the useful life of the concrete blocks, since the solidification/stabilization process led to the immobilization of waste in the cement mass. Therefore, the use of blasting dust in the manufacture of concrete paving blocks is promising, thus being not only an alternative for proper disposal of such waste as well as a possibility of saving raw materials used in the construction industry.

• Advances in concrete construction
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• v.6 no.6
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• pp.659-677
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• 2018

The use of some superplasticizers in the production of mortar or concrete influences the hydration kinetic and the amount of total heat. This results in a modification of some properties, namely mortar workability, mechanical strength and durability. Three superplasticizers were used; a polynaphthalenesulfonate (PNS), a melamine resin (PMS) and a polycarboxylate (PC). They have been incorporated into various amount in a standardized mortar based on limestone cement. The aim of this study was to evaluate the rheological, mechanical and Calorimeters properties of this mortar. This will select the most compatible product and more able to be used depending on the climate of the country and the cement used. The PNS is incompatible with this type of cement registering a decrease of strength but the PMS and the PC modify the kinetics of hydration with significant heat generation and improved mechanical strength. The measured heat flow is significantly influenced by the type and dosage of superplasticizer especially for low dosage. Hydration heat and compressive strength of the different mixtures can be evaluated by determining their ultimate values and ages to reach these values where the correlation coefficients are very satisfactory.