• 한국세라믹학회지
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• 제31권3호
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• pp.330-336
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• 1994

High strength cement composites (W/C=0.1) were prepared by using various blending materials such as SiC whisker and white carbon (hydrated silica: SiO2·nH2O). The effect of various blending materials on the microstructure and strength of the hardened cement paste were investigated in the view of fracture mechanics. The plain specimen showed 101 MPa of flexural strength, 81 GPa of Young's modulus and 1.32 MPam1/2 of fracture toughness. When the blending materials were added to the composites, their values were enhanced to about 110∼138 MPa, 95∼146 GPa and 1.32∼1.87MPam1/2 respectively. The improvement of the mechanical strength for the hardened cement paste may be due to the removal of macropores, the reduction of total porosity, pozzolanic reaction and the increase of various fracture toughening effect.

• 시멘트 심포지엄
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• 27호
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• pp.6-13
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• 2000

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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• pp.142-147
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• 1995

In this study, styrene-maleic anhydride copolymer (SMA) was synthesized from styrene and maleic anhydride and further reacted with sulfuric acid to obtain water-soluble SMA and the flow and strength tests of cement mortar mixed with copolymers were carried out to evaluate the capability of copolymers as high range water reducer for the concrete. It was found from flow experiment that the fluidity of cement mortar mixed with sulfonated SMA (SSMA) was larger than that miced with aminophenol-substituted SSMA (SmSMA). The decreasing rate of the flow of cement mortar mixed with SSMA and SmSMA was decreasing rate of the flow of cement mortar mixed with SSMA and SmSMA was significantly lower than that mixed with naphthalene condensate (NSC). The compressive strength of the hardened cement mortars containing 0.5% copolymers after 28 days curing was examined. The compressive strength of hardened cement mortar containing SSMA and SmSMA was increased up to 32% and 13%, respectively, when compared to the plain. As the results, the copolymers (SSMA and SmSMA) used in this study are greatly expected as a good high range water reducers for the concrete.

• 한국농공학회지
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• 제45권3호
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• pp.41-49
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• 2003

In this study, durability performance of blended cement mortars is evaluated when various mineral admixtures are used with the cement. A comprehensive evaluation of the effects of mineral admixtures on the mortar performance was made. The properties of fresh and hardened blended mortars investigated include slump flow and compressive strength. The durability characteristics of cement materials incorporating the mineral admixtures under various physical and chemical causes of deterioration was investigated. The laboratory test results indicate that mechanical and durability properties of blended cement mortars have superior performance rather than ordinary cement mortars.

• 한국구조물진단유지관리공학회 논문집
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• 제19권2호
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• pp.125-132
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• 2015

본 연구에서는 석회석 미분말을 이용하여 제조한 콘크리트의 굳지 않은 및 굳은 특성을 실험적으로 평가하였다. 석회석 시멘트 제조시 석회석 혼입률은 10%, 15%, 25% 및 35% 범위이며, 보통 포틀랜드 시멘트를 이용하여 제조한 기준 콘크리트 (OPC)와 비교하였다. 혼입률 35%까지 슬럼프, 공기량의 굳지 않은 특성은 기준 시험체와 유사한 특성을 나타내었지만 혼입률이 증가할수록 응결시간은 지연되었다. 석회석 혼입률 15%까지는 압축 및 휨강도, 급속 동결융해 저항성능의 경우 기준 OPC 콘크리트와 동등수준을 확보할 수 있는 것으로 나타났지만, 탄산화 저항성능 향상을 위한 보완은 필요한 것으로 나타났다. 혼입률 25%, 35% 배합은 기준 콘크리트 성능에 비해 압축강도 및 휨강도의 저하가 발생되었다. 치환률이 증가할수록 제한된 수산화칼슘량으로 인해 탄산화 저항성능은 모든 배합에서 감소하였다. 강도감소 및 탄산화저항성능을 고려할 경우, 15% 수준의 석회석 미분말 치환은 가능할 것으로 판단된다.

• 한국농공학회논문집
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• 제47권5호
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• pp.27-39
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• 2005

In the recent design of high ductile fiber-reinforced ECC (engineered cementitious composite), optimizing both processing and mechanical properties for specific applications is critical. This study presents an innovative method to develop new class ECCs, which possess the different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or shotcrete processing) while maintaining ductile hardened properties. In the material design concept, we employ a parallel control of fresh and hardened properties by using micromechanics and cement rheology. Control of colloidal interaction between the particles is regarded as a key factor to allow the performance of the specific processing. To determine how to control the particle interactions and the viscosity of cement suspension, we first introduce two chemical admixtures including a highly charged polyelectrolyte and a non-ionic polymer. Optimized mixing steps and dosages we, then, obtained within the solid concentration predetermined based on micromechanical principle. Test results indicate that the rheological properties altered by this approach were revealed to be highly effective in obtaining the desired function of the fresh ECC, allowing us to readily achieve hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension.

• 한국화재소방학회논문지
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• 제23권3호
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• pp.103-109
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• 2009

콘크리트의 온도에 의한 재료적 특성에 대한 저감은 두 가지 메커니즘에 기인한다. 첫 번째 메커니즘은 온도범위에 따른 구성성분의 상변화이다. 초기 구성성분들은 온도 증가로 인해 다른 성분들로 상변화를 일으킨다. 두 번째 메커니즘은 온도에 의한 각 구성성분의 역학적 특성 변화이다. 따라서 고온에 노출된 콘크리트의 재료적 특성에 관한 모델 역시 이 두 가지 메커니즘을 함께 고려하여 제시되어야 한다. 본 연구는 위에서 언급한 두 가지 메커니즘을 고려한 고온에 노출된 콘크리트의 재료적 특성 모델을 제안하기 위한 기반연구로서, 온도범위에 따른 상변화를 고려한 경화된 시멘트 페이스트의 공극률에 대한 이론적 모델을 제시한다.

• Advances in concrete construction
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• 제12권6호
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• pp.507-515
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• 2021

To evaluate the influence of slag on the alkalinity of pore solution and microstructure of concrete, this paper performs a leaching experiment on hardened cement-slag pastes (HCSP) slice specimens with different slag content in purified water. The pH value of pore solution, average porosity, morphology, phase composition and Ca/Si of HCSP specimens in the leaching process are measured by solid-liquid extraction, saturated-dried weighing, scanning electron microscopy-energy dispersive spectrometry (SEM-EDS) and X-ray diffraction (XRD). Results shows that the addition of slag can mitigate an increase in porosity and a decrease in Ca/Si of HCSP in the leaching process. Besides, an appropriate slag content can improve the microstructure so as to obtain the optimum leaching resistance of HCSP, which can guarantee the suitable alkalinity of pore solution to prevent a premature corrosion of reinforced bar. The optimum slag content is 40% in HCSP with a water-binder ratio of 0.45, and an excessive slag causes a significant decrease in the alkalinity of pore solution, resulting in a loss of protection on reinforced bar in HCSP.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 추계 학술논문 발표대회
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• pp.169-170
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• 2018

In this study, TGA analysis of hardened cement paste with fire damage was performed. The mass reduction rate of 600 ℃ specimens was about 22 ~ 25%, and the sample of 800 ℃ showed the mass loss rate of 9 ~ 13%. As the target temperature and hold time increased, the mass reduction rate decreased. As the depth increased, the mass reduction rate decreased.

• Computers and Concrete
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• 제17권6호
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• pp.815-829
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• 2016

This study has been carried out to investigate the effect of the surface properties of Portland cement, diatomite and zeolite on the performance of concrete composites. In this context, to describe the materials used in this study and determine the properties of them, chemical, physical, mineralogical, molecular, thermal, and zeta potential analysis have been applied. In the study, reference (Portland cement), 10%-20% diatomite, 10%-20% zeolite, 5+5%-10+10% diatomite and zeolite were substituted for Portland cement, a total of 7 different cements were obtained. Ultrasonic pulse velocity, capillary water absorption and compressive strength tests were performed on the hardened concrete specimens. Hardened concrete tests have been done on seven different types of concrete, for 28, 56 and 90 days. As a result of experiments it has been identified that both the zeolite and diatomite substitution has a positive effect on the performance of concrete.