• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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• pp.106-110
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• 1995

Chloride ion is considered one of the most common culprits in the corrosion of steel in concrete. It breaks down the passive film and allows the steel to corrode actively at a high rate. The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions and chloride binding effect of cement pastes made with and without fly ash. Cement pastes with water-ratio of 0.5 allowed to hydrate in sealed containers for 28 days and to express poresolution. T도 expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. It was found that the replaced cement with fly ash have little effect on Chloride binding capacity ratio.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.725-728
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• 2006

This research investigates the characteristics of chloride fixation in non-sintering cement(NSC) matrix. NSC was manufactured by adding phosphogypsum and slack lime to granulated blast furnace slag as sulfate and alkali activators. As a result, the concentration of chloride ion in pore solution of NSC-solidified matrix is more low than that of OPC-solidified matrix containing the same chloride content in cement paste. Also, the concentration of chloride ion in pore solution of NSC-solidified matrix is similar with that of BSC-solidified matrix containing the same chloride content in cement paste.

• 콘크리트학회논문집
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• 제29권1호
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• pp.101-107
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• 2017

본 연구는 시멘트계 재료의 프랙탈 특성에 관한 기초적 연구로써, 고로슬래그 미분말 혼입 시멘트 페이스트의 공극 구조를 수은압입법을 이용하여 측정하였고, 측정된 결과를 프랙탈 모델에 적용하여 그 특성을 분석하였다. 분석 결과, 고로슬래그미분말 혼입 시멘트 페이스트의 공극 구조는 그 범위가 나노미터부터 밀리미터 단위까지 다양하게 분포하는 불규칙한 조직이기 때문에, 전체 영역에 대한 프랙탈 차원을 산정했을 때 각 공극 영역의 특성을 반영할 수 없다. 따라서 프랙탈 차원 산정 시 공극 영역을 나누어서 분석하였다. Zhang and Li (1995) model을 적용했을 때, 시멘트와 GGBFS의 수화반응 결과 생성된 C-S-H 내의 gel pores 및 small capillary pores에 해당하는 micro 영역과 large capillary pores에 해당하는 macro 영역에서 각각 프랙탈 특성이 나타나는 결과를 보였다. 또한 macro 영역보다 micro 영역의 공극 표면이 더 불규칙한 형상을 나타내었다. Ji et al. (1997) model을 적용할 경우, micro 영역이 C-S-H 내의 gel pores에 해당하는 micro I과 small capillary pores에 해당하는 micro II로 구분되었으며, 각각의 프랙탈 특성이 산정되었다. 또한 Zhang and Li (1995) model을 결과와 유사하게, macro, micro II, micro I의 순서대로 공극 크기가 작아질수록 VFD 결과 값이 감소하였으며, 이는 곧 공극의 복잡성이 증가함을 나타낸다.

• Geomechanics and Engineering
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• 제8권1호
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• pp.1-15
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• 2015

This paper presents a series of conventional undrained triaxial compression tests conducted to determine the effect of both tire crumbs and cement addition on Narli sand specimens. The tire crumb contents and cement contents were 3%, 7%, 15%; and 1%, 3%, 5% by dry weight of the sand specimens respectively. Specimens were prepared at about 35% relative density, cured during overnight (about 17 hours) for artificially bonding under a 100 kPa effective stress (confining pressure of 500 kPa with a back pressure of 400 kPa), and then sheared. Deviatoric stress-axial strain, pore water pressure-axial strain behavior, and Young's modulus of the specimens at various mixture ratios of tire crumb/cement/sand were measured. Test results indicated that the addition of tire crumb to sand decreases Young's modulus, deviatoric stress and brittleness, and increase pore water pressure generation. The addition of cement to sand with tire crumbs increases deviatoric stress, Young's modulus, and changes its ductile behavior to a more brittle one. The results suggest that specimen formation in the way used here could reduce the tire disposal problem in not only economically, and environmentally, but also more effectively beneficial way for some geotechnical applications.

• Computers and Concrete
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• 제7권5호
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• pp.421-435
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• 2010

This paper utilizes the modified Davis model and the mode coupling theory, as parts of the electrolyte solution theory, to investigate the diffusivity of the ion in concrete. Firstly, a computational model of the ion diffusion coefficient, which is associated with ion species, pore solution concentration, concrete mix parameters including water-cement ratio and cement volume fraction, and microstructure parameters such as the porosity and tortuosity, is proposed in the saturated concrete. Secondly, the experiments, on which the chloride diffusion coefficient is measured by the rapid chloride penetration test, have been carried out to investigate the validity of the proposed model. The results indicate that the chloride diffusion coefficient obtained by the proposed model is in agreement with the experimental result. Finally, numerical simulation has been completed to investigate the effects of the porosity, tortuosity, water-cement ratio, cement volume fraction and ion concentration in the pore solution on the ion diffusion coefficients. The results show that the ion diffusion coefficient in concrete increases with the porosity, water-cement ratio and cement volume fraction, while we see a decrease with the increasing of tortuosity. Meanwhile, the ion concentration produces more obvious effects on the diffusivity itself, but has almost no effects on the other ions.

• 콘크리트학회논문집
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• 제11권4호
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• pp.31-41
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• 1999

Blended Low Heat type cement is ground granulated blast furnace slag and fly ash mixed ternary with ordinary portland cement. From the viewpoint of X-ray patterns of domestic LHC, the main components of cement such as $C_2$S, $C_3$A, $C_3$S are considerably reduced. Therefore the heat evolution of LHC paste is 42cal/g lower than of OPC paste. At early age, the compressive strength development of LHC concrete is delayed, but the slump loss ratio of fresh concrete is reduced more than 20% with elapsed time. The penetrability of LHC is lower than that of OPC by 1/7.8 with the penetrability of chloride ion into the concrete until the age of 120 days. And the PD Index value of LHC is 0.44$\times$10-6 $\textrm{cm}^2$/s, which indicates only 39.3% of OPC. From the Mercury Intrusion Porosimetry test of cement past, we know that the pore size of LHC is more dense than that of OPC by production of C-S-H.

• Geomechanics and Engineering
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• 제19권4호
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• pp.343-352
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• 2019

For quality control and the economical design of grouted sand, the prior establishment of the unconfined compressive strength (UCS) estimating formula is very important. This study aims to develop an empirical UCS estimating formula for grouted sand based on the physical properties of sands and the UCS of cured pure grout. Four sands with varying particle sizes were grouted with both microfine cement and Ordinary Portland cement. Grouted specimens were prepared at three different relative densities and at three different water-to-cement ratios, and unconfined compression tests were performed. The results demonstrate that UCS of grouted sand can be expressed as the power function of the UCS of cured pure grout: $UCS_{grouted\;sand}/1MPa=A_{soil}{\cdot}(UCS_{pure}/1MPa)^N$. Because the exponent N strongly depends on the combination of pore area and pore size, N is expressed as the function of porosity (n) and specific surface ($S_a$). Additionally, because $S_a$ determines the area of the sand particle that cement particles can adsorb and n determines the number of cementation bondings between sand particles, $A_{soil}$ is also expressed as the function of n and $S_a$. Finally, the direct relationship between $A_{soil}$ and N is also investigated.

• 한국세라믹학회지
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• 제36권3호
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• pp.260-265
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• 1999

보통 포틀랜드 시멘트와 플라이애쉬, 슬래그를 혼합한 혼합시멘트 경화체를 이용하여 이온 확산에 미치는 혼합재의 영향과 양이온 공존시 염소이온의 확산에 대하여 고찰하였다. 겉보기 이온확산계수가 보통 포틀랜드의 시멘트보다 플라이애쉬와 슬래그를 혼합한 시멘트 경화체가 약 10-3배로 매우 낮은 값을 나타내었다. 이것은 포졸란 반응에 의해 많은 CSH 수화물이 capillary pore에 형성되어 macro pore가 감소되고 micro pore가 증가되어 이온 확산에 대한 저항이 커졌기 때문이다. 또한, Mg2+이온 공존시에 염소이온의 확산은 증가되었다.

• 한국구조물진단유지관리공학회 논문집
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• 제22권3호
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• pp.90-96
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• 2018

본 연구에서는 탄소 포집 물질인 ${\gamma}-C_2S$를 함유하고 있는 Stainless Steel Slag AOD를 포함한 시멘트 페이스트의 역학적 및 미세구조 변화를 연구하였다. ${\gamma}-C_2S$는 비수경성이며 그러므로 물과 반응하지 않는다. 그러나 ${\gamma}-C_2S$는 물에 의한 탄산화 양생조건에서 반응성을 가지고 있다. 그 반응은 페이스트 안의 공극을 치밀하게 형성하기 때문에 STS-A를 사용한 시멘트 페이스트의 공극구조는 탄산화 ($CO_2$ 농도는 약 5%)후에 수은압입시험에 의해 측정될 수 있다. 또한 Fractal 특성은 시멘트 페이스트의 미세구조변화는 탄산화 영향에 대하여 연구하였다. 그 결과로부터 STS-A를 포함하는 탄산화 시멘트 페이스트는 강도가 증가하였고 공극구조는 더 치밀해졌다.

• 대한토목학회논문집
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• 제26권5A호
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• pp.909-915
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• 2006

콘크리트의 자기수축을 예측하기 위해 기존 수화도와 자기수축의 진행 속도 차이를 불포화공극 생성 속도로 가정하고 시멘트 페이스트의 자기수축 실험을 통하여 물-결합재비에 반비례하는 불포화공극 보정계수를 산정할 수 있었다. 이를 자기수축 기여 성분과 미기여 성분이 고려된 변형 Pickket 모델을 이용하여 콘크리트의 자기수축을 예측하였으며, 실험값 및 기존 Tazawa 모델과 일치하는 경향을 나타내어 불포화공극 보정계수에 의한 자기수축 예측이 타당함을 알 수 있었다. 그러나 강도의 함수로 설정된 기존 CEB-FIP 자기수축 예측 모델의 경우 최종 자기수축률과 자기수축 발현 시간함수에 대하여 다소의 수정이 필요할 것으로 판단된다.