• Title/Summary/Keyword: cell dimension

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Crystal Structure Analysis of 6-Ethoxy-3-phenyl-5a,9a-dihydro-3H-chromen[4,3-c][1,2]oxazole-3a(4H)-carbonitrile

  • Malathy, P.;Sharmila, P.;Srinivasan, J.;Manickam, Bakthadoss;Aravindhan, S.
    • Journal of Integrative Natural Science
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    • v.9 no.2
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    • pp.94-102
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    • 2016
  • The crystal structure of the potential active 6-ethoxy-3-phenyl-5a,9a-dihydro-3H-chromen[4,3-c][1,2]oxazole-3a(4H)-carbonitrile ($C_{19}H_{15}N_2O_3$) has been determined from single crystal X-ray diffraction technique. The title compound crystallizes in the monoclinic space group C2/c with unit cell dimension a= 29.3026(9) ${\AA}$, b= 6.7695(2) ${\AA}$ and c= 19.7597(6) ${\AA}$ [${\alpha}= 90^{\circ}$, ${\beta}= 125.709(10)^{\circ}$ and ${\gamma}= 90^{\circ}$]. Single crystals suitable for X-ray diffraction were obtained by slow evaporation method, the isoxazole and six membered pyran rings adopts envelope conformation. The crystal packing of the molecules is stabilized by the weak $C-H{\ldots}N$ hydrogen bond interaction.

Crystal Structure Analysis of Methyl 8-bromo-3-phenyl-5a,9a-dihydro-3H-chromen [4,3-c][1,2] isoxazole-3a(4H)-carboxylate

  • Malathy, P.;Sharmila, P.;Srinivasan, J.;Manickam, Bakthadoss;Aravindhan, S.
    • Journal of Integrative Natural Science
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    • v.9 no.2
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    • pp.103-112
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    • 2016
  • The crystal structure of the potential active Methyl 8-bromo-3-phenyl-5a,9a-dihydro-3H-chromen [4,3-c][1,2] isoxazole-3a(4H)-carboxylate ($C_{18}H_{15}BrNO_4$) has been determined from single crystal X-ray diffraction technique. The title compound crystallizes in the triclinic space group Pī with unit cell dimension a=8.3129 (3) ${\AA}$, b=9.5847 (4) ${\AA}$ and c=11.1463(4) ${\AA}$ [${\alpha}=98.457(3)^{\circ}$, ${\beta}=102.806(2)^{\circ}$ and ${\gamma}=105.033(5)^{\circ}$]. Single crystals suitable for X-ray diffraction were obtained by slow evaporation method, the isoxazole and six membered pyran rings adopts envelope conformation. In the crystal, molecules are linked via pairs of inter molecular $C-H{\ldots}O$ hydrogen bonds to form dimmers.

Optimal Inter-Element Spacing of FD-MIMO Planar Array in Urban Macrocell with Elevation Channel Modelling

  • Abubakari, Alidu;Raymond, Sabogu-Sumah;Jo, Han-Shin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.10
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    • pp.4759-4780
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    • 2017
  • Full Dimension multiple input multiple output (FD-MIMO) architecture employs a planar array design at the Base Station (BS) to provide high order multi-user MIMO (MU-MIMO) via simultaneous data transmission to large number of users. With FD-MIMO, the BS can also adjust the beam direction in both elevation and azimuth direction to concentrate the energy on the user of interests while minimizing the interference leakage to co-scheduled users in the same cell or users in the neighboring cells. In a typical highly populated macrocell environment, modelling the elevation angular characteristics of three-dimensional (3D) channel is critical to understanding the performance limits of the FD-MIMO system. In this paper, we study the throughput performance of FD-MIMO system with varying elevation angular spread and inter-element spacing using a 3D spatial channel model. Our results show that for a typical urban scenario, horizontal beamforming with correlated antenna spacing achieves optimal performance but by restricting the spread of elevation angles of departure, elevation beamforming achieves high array gain with wide inter-element spacing. We also realize significant gains due to spatial array processing via modelling the elevation domain and varying the inter-element spacing for both the transmitter and receiver.

Synthesis and Structural Analysis of 2-Amino-4-(4-hydroxy-3-methoxyphenyl)-7,9-dimethyl-5-oxo-4, 5, 6, 7-tetrahydropyrano [2, 3-d] pyrazolo [3, 4-b] pyridine-3-carbonitrile through X-ray Crystallography

  • Ganapathy, Jagadeesan;Jayarajan, R.;Vasuki, G.;Sanmargam, Aravindhan
    • Journal of Integrative Natural Science
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    • v.8 no.1
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    • pp.30-39
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    • 2015
  • The crystal structure of the potential active 2-amino-4-(4-hydroxy-3-methoxyphenyl)-7, 9-dimethyl-5-oxo-4, 5, 6, 7-tetrahydropyrano [2, 3-d] pyrazolo [3, 4-b] pyridine-3-carbonitrile ($C_{21}H_{22}N_5O_6S$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group P-1 with unit cell dimension a=8.1201(9)${\AA}$, b=12.2684(4)${\AA}$ and c=12.387(2)${\AA}$ [${\alpha}=69.573^{\circ}$, ${\beta}=12.168^{\circ}$ and ${\gamma}=76.060^{\circ}$]. In the structure the pyrazole, pyridine and pyran are almost coplanar each other. The crystal packing is stabilized by intermolecular C-H...O and N-H... O hydrogen bond interaction.

Crystal Structure Theory and Applications of 14-Ethoxy-4,6,-dimethyl-8.12- dioxa-4.6-diazatetracyclo [8.8.0.02,7.013,18]octadeca-13,15,17-triene-3,5-dione

  • Ganapathy, Jagadeesan;Sivakumar, G.;Manickam, Bakthadoss;Sanmargam, Aravindhan
    • Journal of Integrative Natural Science
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    • v.8 no.1
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    • pp.19-29
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    • 2015
  • In view of the growing medicinal importance of chromene and its derivatives, the single crystal X-ray diffraction study was carried out for the potential active 4,6-dimethyl-9-phenyl-8,12-dioxa-4,6-diazatetracyclo [8.8.0.02,7.013,18]octadeca-2(7),13,15,17-tetraene-3,5,11-trione-2-ethoxyphenyl (2E)-but-2-enoate ($C_{18}H_{20}N_2O_5$). In the title compound are two molecules exist in the asymmetric unit. It crystallizes in the monoclinic space group $P2_1/c$ with unit cell dimension a=14.608(3) ${\AA}$, b=12.845(3) and c= 17.781(4) [alpha & gamma=$90^{\circ}$ beta=$91.233(5)^{\circ}$]. Both pyran and pyran ring of the chromene moiety adopts sofa conformation in the molecule A & B. The crystal structure is stabilized by intramolecular C-H...O hydrogen bond interaction.

A Study on the Bearing Capacity of Shallow Foundation according to the Reinforcement Geocell Layer (지오셀 보강 층수에 따른 얕은 기초의 지지력에 관한 연구)

  • Lee, Kyong-Cheon;Baek, Young-Sik;Park, Young-Hun;Kim, Nag-Young
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.4
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    • pp.85-96
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    • 2003
  • The Geocell system is the advanced system of Geo-grids, and is one of geosynthetics used for earth reinforcement of weak soil. It is the way to increase earth strength and bearing capacity by using three dimension type of geo-composite. This paper analyzed the bearing capacity mechanism of Geocell system for earth reinforcement. Plate loading tests under the model laboratory condition were performed, and the increase of bearing capacity and the decrease of settlement with shallow foundation were evaluated.

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Wood Quality of Populus nigra × maxmowiczii. (I) - Variation of Bulk Density, Wood Fiber Dimension, Microfibril Angle, and Number of Leaf Knot within Stem - (양황철나무의 재질(材質) (I) 용적밀도수(容積密度數), 목섬유(木纖維)치수 및 잎옹이 분포수(分布數)의 간내변수(幹內變數) -)

  • Park, Sang-Jin;Kang, Sun-Gu;Lee, Ki-Yeong;Jo, Jae-Myeong
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.3
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    • pp.26-33
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    • 1990
  • To study the wood quality factors of Populus nigra $\times$ maxmowiczii known a rapidly growing species, the variations of green moisture contents, bulk density, wood fibre dimensions, microfibril angles, and number of leaf knot in stem wood were investigated. The heartwood contained a higher moisture content than the corresponding sapwood. Bulk density in radial patterns variations decrease outward from the pith, then increase toward the bark. The wood-fiber length and diameters had somewhat smaller values than on Populus alba $\times$ glandulosa or Populus euramericana. The microfibril angles decreased rapidly toward the outside, and their mean values were about 16 degree. The grain angles run nearly parallel to the cell axies. Number of leaf knot showed a fluctural change above ground level to a point near the base of the crown and then increased rapidly to the top of tree and average number of leaf knot varied exclusively from tree to tree.

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Evaluation of Internal Structure and Morphology of Poly(benzyl ether) Dendrimers by Molecular Dynamics Simulations

  • Hong, Taewan;Kim, Hyung-Il
    • Macromolecular Research
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    • v.12 no.2
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    • pp.178-188
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    • 2004
  • We performed molecular dynamics (MD) simulations at 300 K on a series of poly(benzyl ether) (PBE) dendrimers having a different core functionalities. We used the rotational isomeric state Metropolis Monte Carlo (RMMC) method to construct the initial configuration in a periodic boundary cell (PBC) before the MD simulations were undertaken. To elucidate the effects that the structural features have on the chain dimension, the overall internal structure, and the morphology, we monitored the radii of gyration, R$\sub$g/ and the conformational changes during the simulations. The PBE dendrimers in a glassy state adopted less-extended structures when compared with the conformations obtained from the RMMC calculations. We found that R$\sub$g/ of the PBE dendrimer depends on the molecular weight, M, according to the relation, R$\sub$g/∼M$\^$0.22/. The radial distributions of the dendrimers were developed identically in the PBC, irrespective of the core functionality. A gradual decrease in radial density resulted from the fact that the terminal branch ends are distributed all over the molecule, except for the core region.

A Case Study on the Power Performance Characteristics of Building Integrated PV System with Amorphous Silicon Transparent Solar Cells (비정질 실리콘 투과형 태양전지를 적용한 BIPV 시스템 발전 성능에 관한 사례 연구)

  • Jung, Sun-Mi;Song, Jong-Hwa;Lee, Sung-Jin;Yoon, Jong-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.49-52
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    • 2009
  • Practical building integrated photovoltaic system built by Kolon E&C has been monitored and evaluated with respect to power generation, which was installed in Deokpyeong Eco Service Area in Deokpyeong, Gyeonggi, Korea. The amorphous silicon transparent PV module in this BIPV system has 44Wp in power output per unit module and 10% of transmittance with the unit dimension with $980mm{\times}950mm$. The BIPV system was applied as the skylight in the main entrance of the building. This study provided the database for the practical application of the transparent thin-film PV module for BIPV system through 11 month monitoring as well as various statistical analyses such as monthly power output and insolation. Average monthly power output of the system was 52.9kWh/kWp/month which is a 60% of power output of the previously reported data obtained under $30^{\circ}$of an inclined PV module facing south(azimuth=0). This lower power output can be explained by the installation condition of the building facing east, west and south, which was resulted from the influence of azimuth.

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Structural Analysis of 2-Benzyl-3-[3-(4-bromo-phenyl)-1-phenyl-1H-pyrazol-4yl]-4,6-dioxo-5-phenyl-octahydro-pyrrolo[3,4-C]pyrrole-1-carboxylic Acid Ethyl Ester through X-ray Crystallography

  • Ganapathy, Jagadeesan;Pramesh, M.;Perumal, P.T.;Sanmargam, Aravindhan
    • Journal of Integrative Natural Science
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    • v.8 no.3
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    • pp.192-203
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    • 2015
  • In view of the growing medicinal importance of pyrazole and its derivatives, the single crystal X-ray diffraction study was carried out for the potential active 2-Benzyl-3-[3-(4-bromo-phenyl)-1-phenyl-1H-pyrazol-4yl]-4,6-dioxo-5-phenyl-octahydro-pyrrolo[3,4-C]pyrrole-1-carboxylic acid ethyl ester ($C_{37}H_{31}BrN_4O_4$, H2O). In the title compound are two molecules exist in the asymmetric unit. It crystallizes in the monoclinic space group $P{\hat{i}}$ with unit cell dimension $a=13.361(18){\AA}$, $b=13.424(17){\AA}$ and $c=21.649(2){\AA}$ [${\alpha}=80.745(9)^{\circ}$, ${\beta}=79.770(10)^{\circ}$ and ${\gamma}=60.788(6)^{\circ}$]. The pyrazole ring adopts planar conformation. The sum of the bond angles at nitrogen atom of the pyrazole ring indicates the $Sp^2$ hybridized state. The crystal structure is stabilized by intramolecular C-H...O hydrogen bond interaction.