• Title/Summary/Keyword: cell dimension

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A Study on Fuel Cells Employing Anion-Exchange Membranes (음이온교환막을 채용하는 연료전지에 관한 연구)

  • Park, Jin-Soo;Park, Seok-Hee;Yang, Tae-Hyun;Lee, Won-Yong;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.77-80
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    • 2006
  • Chloromethylated polysulfone(CMPSf) and a number of mono- and diamine compounds were used to prepare anion-exchange membranes(AEMs) and an ionomer binder solution. The properties of the AEMs were investigated such as $OH^-$ conductivity, water content and dimension stability. Chloromethylation and amination of PSf were optimized in terms of the properties. Membrane-electrode assemblies were fabricated using anion-exchange membranes and the ionomer binder for solid alkaline fuel cells and direct borohydride fuel cells.

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Three-dimensional Detonation Cell Structures in a Circular Tube

  • Cho, D.R.;Won, S.H.;Shin, Edward J.R.;Choi, J.Y.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.597-601
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    • 2008
  • Three-dimensional structures of detonation wave propagating in circular tube were investigated. Inviscid fluid dynamics equations coupled with a conservation equation of reaction progress variable were analyzed by a MUSCL-type TVD scheme and four stage Runge-Kutta time integration. Variable-$\gamma$ formulation was used to account for the variable properties between unburned and burned states and the chemical reaction was modeled by using a simplified one-step irreversible kinetics model. The computational code was parallelized based on domain decomposition technique using MPI-II message passing library. The computations were carried out using a home made Windows based PC cluster having 160 AMD AthloxXP and Athlon64 processor. The computational domain consisted of through a roundshaped tube with wall conditions. As an initial condition, analytical ZND solution was distributed over the computational domain with disturbances. The disturbances has circumferential large gradient. The unsteady computational results in three-dimension show the detailed mechanisms of multi-cell mode of detonation wave instabilities resulting diamond shape in smoked-foil record.

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Influence of Ultrasonic Treatment and Nano-Clay content on the Properties of Nano-Clay/Polyurethane Foam (초음파 처리와 나노클레이 농도가 나노클레이/폴리우레탄 폼의 물성에 미치는 영향)

  • Her, Kiyoung;Lim, Soonho;Kim, Daeheum
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.208-212
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    • 2009
  • The nano-clay is widely used in polymer-nanocomposites due to the high aspect ratio, heat resistance and nano-scale dimension. In recent researches, the thermal and mechanical properties of polyurethane foam were improved with introducing the nano-clay. In this study, we describe the influence of ultrasonic treatment and content of nano-clay on properties of polyurethane foam. The nano-clay/polyurethane foam were characterized using their recovery time, compressive deflection, cell morphology and tensile test. The ultrasonic treatment was very effective for dispersion of nano-clay. Moreover, we found that introducing over 3 wt% of nano-clay bring the decrease of properties due to the poor dispersion. Expecially, ultrasonically treated 20A/polyurethane foam(1 wt%) showed greatly improved properties, such as homogeneous cell size and good dimension stability. We expect that our results could be applied to insulating materials for construction.

Simulation for Possible Coke-Free Operation of a Packed Catalyst Bed Reactor in the Steam-CO2 Reforming of Natural Gas (천연가스의 수증기-이산화탄소 복합개질용 촉매 충진 반응기의 코킹 회피 운전을 위한 모사)

  • LEE, DEUK KI;LEE, SANG SOO;SEO, DONG JOO;YOON, WANG LAI
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.5
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    • pp.445-452
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    • 2015
  • A tubular packed bed reactor for the steam-$CO_2$ combined reforming of natural gas to produce the synthesis gas of a target $H_2/CO$ ratio 2.0 was simulated. The effects of the reactor dimension, the feed gas composition, and the gas feeding temperature upon the possibility of coke formation across the catalyst bed were investigated. For this purpose, 2-dimensional heterogeneous reactor model was used to determine the local gas concentrations and temperatures over the catalyst bed. The thermodynamic potential distribution of coke formation was determined by comparing the extent of reaction with the equilibrium constant given by the reaction, $CH_4+2CO{\Leftrightarrow}3C+2H_2O$. The simulation showed that catalysts packed in the central region nearer the entrance of the reactor were more prone to coking because of the regional characteristics of lower temperature, lower concentration of $H_2O$, and higher concentration of CO. With the higher feeding temperature, the feed gas composition of the increased $H_2O$ and correspondingly decreased $CO_2$, or the decrease in the reactor diameter, the volume fraction of the catalyst bed subsequent to coking could be diminished. Throughout the simulation, reactor dimension and reaction condition for coking-free operation were suggested.

Characteristics of Culm Anatomy and Dimensional Variation in Genus Phyllostachys Grown Damyang District, Korea (담양지방(潭陽地方) 왕대속(屬) 4종(種)의 조직(組織) 및 간내(稈內) 변이성(變異性))

  • Lee, Jae-Ki;Park, Sang-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.3
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    • pp.14-23
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    • 1987
  • This study was carried out to investigate the anatomical characteristics, the radial and axial variation of the cell dimension and bulk density for four bamboo species used as the major material of bamboo products in Korea; Phyllostachys(P.bambusoides, P.edulis, P.nigra var.henonis, and Pnigra). The results obtained were summarized as follows; 1) In the outer part of culm, the mophological difference of cell diameter and distribution were not acknowledged. However, gum-like substance was occurred In the epidermis, hypodermis, cortex and metaxylem vessel of P.nigra, while it was occured only in the metaxylem vessel of P.edulis. 2) The protoxylem vessel in the central zone of culm-wall could be in the two types; the first type consisted of 4-5 small cell pieces occurred in P.edulis and P.nigra var. henonis, the second type of 1-2 large cell pieces in P.bambusoides and P.nigra. And transition of cell diameter from the vascular bundle sheath to the ground tissue was gradually enlarged in P.nigra and P.edulis but abruptly in P.bambusoides and P.nigra var. henonis. 3) Thin-wall tyloses were well developed in the outer and central zone of culm-wall in four species. 4) Compared with the central part of culm-wall, the number of parenchyma cells and the amount of the vascular bundle sheaths per unit area were a few in the inner part. The inner part nearest to the pith cavity was consisted of thick-well parenchyma cell. 5) The dimensional variations of metaxylem vessel and parenchyma cell in the radial direction were decreased from the inner part to the epidermis in all species observed. 6) The fiber length was the maximum in the central zone and its diameter was increased from the inner part to the outer part. In the axial variation. fiber length was slightly increased from the base and then decresed slowly toward the top, and its diameter was reverse. 7) The axial variation of the bulk density was continuously increased from the base toward the top and its radial variation was rapidly increased from the inner part to the epidermis.

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Analysis on a Dynamic Model with One Dimension in Water Transportation of PEM Fuel Cell (PEM연료전지의 수분전달에 있어서 1차원 해석을 수행한 동적모델에 관한 연구)

  • Bakhtiar, Agung;Hong, Boo-Pyo;You, Jin-Kwang;Kim, Young-Bok;Yoon, Jung-In;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.32 no.5
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    • pp.118-123
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    • 2012
  • Water balance has a significant impact on the overall fuel cell performance. Maintenance of proper water management should provide an adequate membrane hydration and avoidance of water flooding in the catalyst layer and gas diffusion layer. Considering the important of advanced water management in PEM fuel cell, this study proposes a simple one dimensional water transportation model of PEM fuel cell for use in a dynamic condition. The model has been created by assumption that the output is the water liquid saturation difference. The liquid saturation change is the total difference between the additional water and the removal water on the system. The water addition is obtained from fuel cell reaction and the electro osmotic drag. The water removal is obtained from capillary transport and evaporation process. The result shows that the capillary water transport of low temperature fuel cell is high because the evaporation rate is low.

Structure of Opposite Wood in Angiosperms(II) - Structure of Opposite Woods in the Horizontal-growing Stems of Immature Woods - (활엽수(闊葉樹) Opposite재(材)의 구조(構造)(II) - 수평(水平) 생장(生長)시킨 유영목수간(幼 令木樹幹)의 Opposite재(材) 구조(構造) -)

  • Park, Sang-Jin;Park, Byung-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.17 no.3
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    • pp.20-27
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    • 1989
  • This experiment was made to find the peripheral variations of annualring widths, the cell dimensions, microfibril angles and bulk densities within each annual-ring of horizontal-growing young tree of beech(Betul a platyphylla var. japonica) and Oak (Quercus variabilis) from the tension to the opposite side. Also a comparision between the features of the obnormal annual ring for horizontal-growing year and normal annual ring for the straight-growing years was made. The dimension of propotion of the element, the microfibril angles and the bulk density decreased or increased continuously toward opposite side which showed minimum or maximum value. The dimension of elements the microfibril angles and the bulk density decreased or increased continuously towards opposite side which showed minimum or maximum value. The dimension of elements. the microfibril angles and the bulk density in the normal annual rings were similar to those in the lateral woods. whereas were significantly more different in the tension wood than in the opposite wood. The features of typical opposite wood in the hardwoods were influenced by the locations within the inclined stems than effects of the decrease in the annual ring width. The oppostie woods in hardwoods did not conform to the tension wood and lateral wood. The abnormal annual ring included the opposite wood, lateral wood similar to normal wood and tension wood having specialized structure even in the same annual ring.

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Capacity Design of Lithium Ion Battery Based on the Characteristics of Materials (${\cdot}$부극 재료의 특성에 따른 리튬이온전지의 용량설계)

  • Moon Seong-In;Doh Chil-Hoon;Yun Seong-Kyu;Yum Duk-Hyung
    • 한국전기화학회:학술대회논문집
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    • 1998.12a
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    • pp.7-27
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    • 1998
  • In order to design capacity of lithium ion battery, some calculations were carried out based on the characteristics of materials by the given battery shape and dimension. The principle of design was built by the interpretation of the correlation of material, electrochemical and battery factors. Parameters of materials are fundamental physical properties of constituent such as cathode. separator, anode, current collectors and electrolyte. Electrochemical factor includes potential pattern as a function of specific capacity, specific discharge capacity(or initial irreversible specific capacity or Ah efficiency) as a function of specific charge capacity and material balancing. Parameters of battery are dimension, construction hardware and performance. Battery capacity was simulated for a lithium cobalt dioxide as cathode and a hard carbon as anode to achieve 1100 mAh for the charge limit voltage of 4.2V, the weight ratio(+/-) of 2.4 and ICR18650. A fabricated test cell (ICR18650) which have weight ratio(+/-) of 2.4 discharged to 1093 mAh for the charge limit voltage of 4.2V. The sequential discharge capacity show good correspondence with designed capacity.

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Bayesian Variable Selection in the Proportional Hazard Model with Application to Microarray Data

  • Lee, Kyeong-Eun;Mallick, Bani K.
    • Proceedings of the Korean Statistical Society Conference
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    • 2005.05a
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    • pp.17-23
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    • 2005
  • In this paper we consider the well-known semiparametric proportional hazards models for survival analysis. These models are usually used with few covariates and many observations (subjects). But, for a typical setting of gene expression data from DNA microarray, we need to consider the case where the number of covariates p exceeds the number of samples n. For a given vector of response values which are times to event (death or censored times) and p gene expressions(covariates), we address the issue of how to reduce the dimension by selecting the significant genes. This approach enables us to estimate the survival curve when n ${\ll}$p. In our approach, rather than fixing the number of selected genes, we will assign a prior distribution to this number. The approach creates additional flexibility by allowing the imposition of constraints, such as bounding the dimension via a prior, which in effect works as a penalty To implement our methodology, we use a Markov Chain Monte Carlo (MCMC) method. We demonstrate the use of the methodology to diffuse large B-cell lymphoma (DLBCL) complementary DNA (cDNA) data and Breast Carcinomas data.

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Modeling and simulation of VERA core physics benchmark using OpenMC code

  • Abdullah O. Albugami;Abdullah S. Alomari;Abdullah I. Almarshad
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3388-3400
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    • 2023
  • Detailed analysis of the neutron pathway through matter inside the nuclear reactor core is exceedingly needed for safety and economic considerations. Due to the constant development of high-performance computing technologies, neutronics analysis using computer codes became more effective and efficient to perform sophisticated neutronics calculations. In this work, a commercial pressurized water reactor (PWR) presented by Virtual Environment for Reactor Applications (VERA) Core Physics Benchmark are modeled and simulated using a high-fidelity simulation of OpenMC code in terms of criticality and fuel pin power distribution. Various problems have been selected from VERA benchmark ranging from a simple two-dimension (2D) pin cell problem to a complex three dimension (3D) full core problem. The development of the code capabilities for reactor physics methods has been implemented to investigate the accuracy and performance of the OpenMC code against VERA SCALE codes. The results of OpenMC code exhibit excellent agreement with VERA results with maximum Root Mean Square Error (RMSE) values of less than 0.04% and 1.3% for the criticality eigenvalues and pin power distributions, respectively. This demonstrates the successful utilization of the OpenMC code as a simulation tool for a whole core analysis. Further works are undergoing on the accuracy of OpenMC simulations for the impact of different fuel types and burnup levels and the analysis of the transient behavior and coupled thermal hydraulic feedback.