• Title/Summary/Keyword: caustic soda

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Studies on the Characteristics of Humic Acid and its Utilizations (I) (土炭 흄酸의 性狀 및 應用에 關한 硏究 (I) 흄酸의 溶出 및 그 條件에 따른 흄酸性狀의 變異)

  • Kim, Won-Taik
    • Journal of the Korean Chemical Society
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    • v.12 no.4
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    • pp.155-159
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    • 1968
  • On the extraction of humic acid from peat, the optimum conditions were studied and the effects of them on the characteristics of humic acid were also examined by means of infrared spectroscopy. 1. Pretreatment of peat with diluted 6-8% HCl solution for 5 hrs. prior to extraction with alcohol-benzol azeotropic mixture have resulted the better yield of humic acid. The water soluble Na-humates were obtained by the subsequent extraction with one hundred times quantity of caustic soda solutieon for 1hr. at 90 $^{\circ}C$. Thus the pure humic acids have been yielded approximately 40% (by wt.) from the raw peat. 2. In characteristics of humic acid, the chemical structure, mainly the contents of such functional groups as -COOH, -OH (phenol type), $-CH_2CO-$, $-CH_2{\cdot}O{\cdot}CH_2-$ and aromatic rings were varied according to the concentration of alkaline solution, temperature and time when the humic acids were extracted with alkali.

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STUDY ON GY NEW MINERAL PROCESSING TECHNOLOGY FOR SHIZHUYUAN POLYMETALLIC ORE

  • Zhang, Zhonghan;Li, Xiaodong;Ye, Zhiping;Guo, Jianguan
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.325-330
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    • 2001
  • Shizhuyuan W-Mo-Bi-Ca $F_2$polymetallic ore is classified to the refractory one due to its complex property, fine dissemination and close association of minerals. Through several years of researches, in line with GY new mineral processing technology developed by Guangzhou Research Institute of Nonferrous Metals, in sulfide flotation circuit, an iso-flotability flowsheet is used to replace original overall bulk flotation flowsheet, and in tungsten flotation circuit, a new chelating type-GY reagent and a special pulp-conditioning system and a new technology of wolframite slime flotation are used to replace the traditional "Caustic Soda Method"$_{[1]}$, the metallurgical performance is greatly improved. Besides, GY New Method has created a favorable condition for comprehensive recovery of fluoride from tungsten flotation tailings. Notable economic benefit has been achieved.d.

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Study on the Mass Transfer Behavior of AQ and Its Effectiveness during AQ-Kraft Pulping Process

  • Huang, Xiannan;Song, Hainong;Qin, Chengrong;Yoon, Sung-Hoon;Chai, Xin-Sheng
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.291-294
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    • 2006
  • Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.

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Influence of Cotton Pre-Treatment on Dyeing with Rubia cordifolia extracts for Cotton (면의 전처리 방법이 Rubia cordifolia 추출물의 염색성에 미치는 영향)

  • Bum Hoon Lee
    • Textile Coloration and Finishing
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    • v.35 no.1
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    • pp.1-7
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    • 2023
  • In this study, the influence of pre-treatment(bleaching, mercerization by liquid ammonia and caustic soda) on cotton fabrics were investigated on dyeing Rubia cordifolia extracts. Aluminium Sulfate, Iron(Ⅱ) Sulfate Heptahydrate, Copper(Ⅱ) Sulfate Pentahydrate, Tin(Ⅱ) Sulfate, Manganese(Ⅱ) Chloride Tetrahydrate were used as mordanting agents. K/S value and washing fastnesses of the dyed cotton fabrics pretreated under different conditions were investigated. The K/S values were increased in the order of bleaching, liquid ammonia and mercerization pre-treatment. It was found that the pre-treatment conditions did not significantly affect the color change. The colorfastness to washing of most of all dyed fabrics were over grade 4 regardless of pre-treatment condition.

The Kinetics of Delignification in Oxygen·Alkali pulping (효소(酵素)·알칼리 증해(蒸解)의 탈(脱)리그닌에 관(関)한 동역학적(動力學的) 분석(分析))

  • Jo, Byoung Muk;Shin, Dong So
    • Journal of Korean Society of Forest Science
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    • v.56 no.1
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    • pp.26-50
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    • 1982
  • In order to obtain more detailed information concerning the degradation of lignin in the oxygen alkali pulping single stage isothermal delignification of pine wood meal (Pinus koraiensis S. et Z.) was studied in the oxygen alkali system at five temperature level ($110^{\circ}C$, $120^{\circ}C$, $130^{\circ}C$, $140^{\circ}C$, $150^{\circ}C$) for 60 min.. The rate constant, activation energy, oxygen and alkali consumption during the oxygen alkali delignification were determined by the kinetic method. The 2/5 of total lignin was eliminated at the start of the reaction. The delignification rate constant was about 3 times that of caustic soda pulping. The activation energy was about 1/3 lower than in caustic soda pulping. Like oxygen consumption, alkali consumption was also rapid early at the reaction and almost ceased after about 10 min.. The degradation reaction of lignin was strongly dependent upon the pH decrease of the cooking liquor by organic acid generated in pulping. The lignin in the oxygen alkali pulping degraded into lover molecular weight and had more hydrophillic properties. The methoxyl group decreased considerably at the first of oxygen alkali delignification, while the carbonyl, carboxyl and phenolic hydroxyl group increased rapidly.

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Potential of Coal Gasification Slag as an Alkali-activated Cement (석탄가스화 복합발전 슬래그의 알칼리 활성 시멘트로서의 가능성)

  • Kim, Byoungkwan;Lee, Sujeong;Chon, Chul-Min;Choi, Hong-Shik
    • Resources Recycling
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    • v.27 no.2
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    • pp.38-47
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    • 2018
  • Integrated gasification combined cycle (IGCC) is a next generation energy production technology that converts coal into syngas with enhanced power generation efficiency and environmental performance. IGCC produces almost coal gasification slag as the solid by-product. IGCC slag is generated about 140,000 tons for a year although recycling of it is still in the early stages. We evaluated the potential of IGCC slag which is generated from a pilot plant in South Korea as an alkali-activated cement. Samples which were activated with the combined activator of sodium silicate solution and caustic soda had an average compressive strength of 4.5 MPa, showing expansion. Expansion of the alkali-activated slag was presumed to be caused by free CaO in the slag, although it was not detected by the ethylene glycol method. Samples that were activated with the combined activator of sodium aluminate and caustic soda had an average compressive strength of 10 MPa. Hydroxy sodalite and $C_3AH_6$ were found to be the new crystalline phases. IGCC slag can be used as an alkali-activated material, but the strength performance should be improved with proper mix design approach to calculate optimum proportions which can alleviate the expansion issue at the same time.

Application of Enzymatic Hydrolysis for the Yield Optimization in Froth-Flotation of ONP

  • Ryu, Jeong-Yong;Song, Bong-Keun;Song, Jae-Kwang
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.129-136
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    • 2006
  • Although cleaner and cheaper deinking of ONP could be performed at the neutral or low alkaline condition excessive loss from froth-flotation is unavoidable and so reduction of alkali or caustic soda dosage sacrifices recycling yield. Now the new trade-off regarding alkali dosage versus flotation yield is urgently required in order to set the optimized neutral or low alkaline deinking process of ONP. Lipase from Thermomyces Lanuginosus has an effect on desizing and deacetylation reaction and it could be applied to the stock of pre flotation secondary stage in order to reduce the flotation reject without the sacrifice of optical properties of flotation accepts. Instead of inorganic base, lipase could be applied as a biochemical catalyst for the selective modification of valuable hydrophobic particles in deinking stock, for example cellulose fines and inorganic fillers covered by hydrophobic additives or contaminants. When the enzymatic hydrolysis of ester bond could be made on the surface of hydrophobic particulates, unwanted float of fine particles could be prevented. Now the enhancement of flotation selectivity or the modification of the hydrophobicity of deinking stock is expected to be promoted by the enzymatic pre treatment. And the reduction of recycling cost with the saves of raw material, recovered paper would be possible as a result.

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Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives (첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究))

  • Lim, Kie-Pyo;Shin, Dong-Sho
    • Journal of the Korean Wood Science and Technology
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    • v.7 no.2
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    • pp.3-30
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    • 1979
  • Larch ($\underline{Larix}$ $\underline{leptolepis}$ GORDON), one of the major afforestation species in Korea in view of its growing stock and rate of growth, is not favored as a raw material for pulp due to its low yield of pulp and difficulties with bleaching arising from the high content of extractives in wood, and the high heartwood ratio and the active phenolics, respectively. The purpose of this study is to investigate the characteristics of firstly pulping with various additives of cellulose protector for the yield of pulp, and secondly bleaching with oxygen for chlotination-alkali extraction of five stage-sequence to reduce chlorine compounds in bleaching effluents. The kraft cooking liquor for five age groups of larchwood was 18 percent active alkali with 25 percent sulfidity and 5 : 1 liquor-to-wood ratio, and each soda liquor for sap-and heart-wood of the 15-year-old larchwood was 18 percent alkali having one of the following cellulose protectors as the additive; magnesium sulfate ($MgSO_4$, 2.5%), zinc sulfate ($ZnSO_4$, 2.5%), aluminium sulfate ($Al_2(SO_4)_3$, 2.5%), potasium iodide (KI, 2.5%), hydroquinone (HQ, 2.5%), anthraquinone (AQ, 0.1%) and ethylene diamine (EDA, 2.5%). Then each anthraquinone-soda liquor for the determination of suitable cooking condition was the active alkali level of 15, 17 and 19 percent with 1.0, 0.5 and 0.1 percent anthraquinone, respectively. The cooking procedure for the pulps was scheduled to heat to 170$^{\circ}C$ in 90 minutes and to cook 90 minutes at the maximum temperature. The anthraquinone-soda pulps from both heartwood and sapwood of 15-year-old larchwood prepared with 0.5 percent anthraquinone and 18 percent active alkali were bleached in a four-stage sequency of OCED. (O: oxygen bleaching, D: chlorine dioxide bleaching and E: alkali extraction). In the first stage oxygen in atmospheric pressure was applied to a 30 percent consistency of pulp with 0.1 percent magnesium oxide (MgO) and 3, 6, and 9 percent sodium hydroxide on oven dry base, and the bleached results were compared pulps bleached under the conventional CEDED (C: chlorination). The results in the study were summarized as follows: 1. The screened yield of larch kraft pulp did not differ from particular ages to age group, but heartwood ratio, basic density, fiber length and water-extractives contents of wood and the tear factor of the pulp increased with increasing the tree age. The total yield of the pulp decreased. 2. The yield of soda pulp with various chemicals for cellulose protection of the 15-year-old larchwood increased slightly more than that of pure soda pulp and was slightly lower than that of kraft pulp. The influence of cellulose protectors was similar to the yield of pulps from both sapwood and heartwood. The effective protectors among seven additives were KI, $MgSO_4$ and AQ, for which the yields of screened pulp was as high as that of kraft pulp. Considering the additive level of protector, the AQ was the most effective in improving the yield and the quality of pulp. 3. When the amount of AQ increased in soda cooking, the yield and the quality of the pulp increased but rejects in total yield increased with decreasing the amount of active alkali from 19 to 15 percent. The best proportion of the AQ seemed to be 0.5 percent at 17 percent active alkali in anthraquinone-soda pulping. 4. On the bleaching of the AQ-soda pulp at 30 percent consistency with oxygen of atomospheric pressure in the first stage of the ODED sequence, the more caustic soda added, the brighter bleached pulp was obtained, but more lignin-selective bleaching reagent in proportion to the oxygen was necessary to maintain the increased yield with the addition of anthraquinone. 5. In conclusion, the suitable pulping condition for larchwood to improve the yield and quality of the chemical pulp to the level for kraft pulp from conventional process seemed to be. A) the selection of young larchwood to prevent decreasing in yield and quality due to the accumulation extractives in old wood, B) the application of 0.5 percent anthraquinone to the conventional soda cooking of 18 percent active alkali, and followed, C) the bleaching of oxygen in atmospheric pressure on high consistency (30%) with 0.1 percent magnesium oxide in the first stage of the ODED sequence to reduce the content of chlorine compounds in effluent.

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Studies on the Chemical Composition of Quercus variabilis and Q. serrata Grown in Mt. Jiri (지리산산(智異山産) 굴참나무재(材)와 졸참나무재(材)의 화학적(化學的) 조성(組成))

  • Moon, Chang Kuck
    • Journal of Korean Society of Forest Science
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    • v.58 no.1
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    • pp.23-26
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    • 1982
  • The chemical components in sap and heart wood of Q. variabilis and Q.serrate grown in Mt. Jiri were analyzed Q. variabilis ash contents were 0.57%, in sap wood portion and 1.00% in heart wood. Of the extractives cold water extractives were 5.74% in sap wood and 4.77% in heart wood. Hot water extractives were 6.33% in sap, 6.30% in heart wood portion. 1% caustic soda extractives were 15.52% in sap wood and 15.63% in heart wood. Alcohol-benzol extractives were 4.89% in sap wood and 2.96% in heart wood Holocellulose contents were 73.19% in sap wood, 78.83% in heart wood. Lignin contents were 21.76% in sap wood and 18.14% in heart wood portion. In pentosan contents there were 15.92% in sap wood and 26.50% in heart wood. In Q serrata ash contents were 0.26% in sap wood and 0.27% in heart wood. Cold water extractives were 2.81% in sap wood and 2.04% in heart wood. Hot water extractives were 5.32% in sap wood and 7.08% in heart wood portion. 1%-C austic soda extractives were 15.73% in sap wood and 16.55% in heart wood. Alcohol-benzol extractives were 3.93% in sap wood and 3.51% in heart wood. Holo celluloe contents were 74.21% and 74.84% in sap and heart wood portion respectively. Lignin contents were 14.11% in sap wood and 19.19% in heart wood. Of the pentosan contents there were 20.75% and 21.44% in sap and heart wood respectively. In conclution ash, holocellulose, lignin and pentosan contents showed always consistent differences between sap and heart wood in Q.variabilis, but in Q.serrata only lignin content showed slight difference between sap and heart wood.

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The characteristics and changes of traditional hemp textile production of Gurye at Jeollanam-do in modern times (1920s~1980s) (근대 시기(1920~1980) 전라남도 구례군의 전통 삼베 수공업 생산 방식의 특징과 변화)

  • Choi, Seung Yeun
    • The Research Journal of the Costume Culture
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    • v.22 no.1
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    • pp.16-27
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    • 2014
  • This study investigated the characteristics of and changes in hemp textile production practices at Gurye in Jeollanam-do in modern times. To do this, in this study, both a literature review and fieldwork research were utilized as research methods. The literature review focused on Gurye's hemp data, and the fieldwork research involved two separate trials. Male and Female residents of Gurye who had experience in the area of hemp production from the 1920s to the 1980s participated in this study. The results were as follows. First, regarding hemp fiber cultivation in Gurye, hemp cultivation continued to the 1970s and there were no changes in hemp cultivation practices during the Japanese colonial-era. Second, there have been very important changes in hemp kilns over time. In the 1950s, there were both single-body kilns and separate-body kilns in Gurye. Later, specifically in the 1950s, a new type of kiln using an iron pot appeared, and the most modern kilns were concrete structures. Third, in Gurye, women cooperatively removed hemp husks immediately after stemming, subsequently bleaching the hemp by soaking it in lye or caustic soda. Over time, there have been changes in ash types and in soaking periods. Fourth, loom types changed from the traditional Korean back-strap loom to the treadle loom in the 1930s- to 1940s. Fifth, since the 1970s, the hemp textile output levels of Gurye have been reduced due to the westernization of clothing styles, the inflow of Chinese hemp fiber and government regulations pertaining to hemp cultivation.