• Title/Summary/Keyword: caustic reduction

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The Physical Property of the Structural Color Yarn and Fabric for Emotional Garment Using Biomimetic Technology (생체모방기술을 응용한 감성의류용 구조발색사와 직물의 물성)

  • Kim, Hyun-Ah;Kim, Seung-Jin
    • Science of Emotion and Sensibility
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    • v.15 no.1
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    • pp.141-148
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    • 2012
  • This study investigated the structural coloration and fabric hand of the caustic reduced fabrics for emotional garment using structural color yarns, which was spun by 37 alternating nylon and polyester layers capable of producing basic colors using biomimetic technology. The colorations of the three kinds of structural color yarns were confirmed using multi angle spectro-photometer, and their triangular cross sections composed with 37 alternating nylon and polyester layers were measured using SEM and were discussed with layer length in relation with coloration and spinning conditions were also set up. The apparent color difference and reflectance of the three kinds of fabrics with different density and weave pattern were analysed as ranging from 400nm to 700nm. The optimum fabric structural design which is made by warp and weft densities(194ends/in ${\times}$ 105picks/in) and caustic reduction condition by $100^{\circ}C$ temperature and 60minutes with NaOH, 20g/l solution were decided through analysis of the mechanical properties and fabric hands of these three kinds of fabrics treated with 3 kinds of the caustic reduction conditions. And it was shown that the rate of caustic reduction was increased from 13% to 23% with increasing temperature and time of caustic reduction. The extensibility, bending rigidity and shear modulus of caustic reduction treated fabrics were decreased by treatment of caustic reduction, on the other hand fabric compressibility was increased. And it was shown that the hand value of specimen number one which was treated with temperature $100^{\circ}C$ and time 60minute was the best and the hand of this fabric was better than that of Morpho $fabric^{(R)}$ made by Teijin co. Japan.

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Accelerating Effect of Organic Acid Treatment on Weight Reduction Characteristics of Sea-Island Type PET Supermicrofiber (1) (유기산 처리가 해도형 초극세 폴리에스터 섬유의 용출 특성에 미치는 영향 (1))

  • Kim, Hea-In;Jeong, Cheon-Hee;Min, Mun-Hong
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.45-53
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    • 2012
  • In order to make a supermicrofiber fabric with PET/co-PET sea-island type filament fiber, the optimum conditions of dissolution of co-PET composite filament fiber was examined. The data set was made at various organic acid concentration and steam temperature with treated time as a main variable. At the same time, the microstructure changes by organic acid treatment of sea-island type PET supermicrofibers were monitored by thermal analysis morphology, DSC thermgrams and SEM images. Weight reduction behavior of supermicrofibers by caustic treatment was investigated in a comparative method. The termination of dissolution was also confirmed using DSC thermgrams and SEM images.

Design of an Automatic Titration System for Caustic Soda Treatment System Using the Equivalent Point Estimation Algorithm (당량점 예측 알고리듬에 의한 가성소다 처리 섬유감량 시스템용 자동적정 장치 설계)

  • Cho, Jin-Ho;Jin, Kyoung-Chan;You, Byoung-Heui;Koo, Sung-Mo;Kim, Myoung-Nam;Lee, Jong-Hyun;Lee, Heung-Lark
    • Journal of Sensor Science and Technology
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    • v.3 no.3
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    • pp.28-35
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    • 1994
  • Caustic Soda Treatment Systems need a concentration measurement device in order to monitor the weight reduction amount of polyester fabrics. Since the reduction process requires several concentration measurements, we have to do the unit titration fast and exactly. Therefore, a proposition of estimation algorithm for finding the equivalent point in the titration process is needed. In this paper, we used the cardinal spline algorithm, to estimate the proper curve with the measured pH-values after each injection of titration sdution, to predict the equivalent point. While the processing time is elapsed, several equivalent points are estimated and drawed the line graph of fabrics weight reduction automatically. Finally, we designed the hardware and the software of an automatic titration system that can generate the reduction ending signal of Caustic Soda Treatment System.

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Analysis of the Physical Properties of Morphotex(R) According to Caustic Reduction Conditions (감량조건에 따른 Morphotex(R) 소재의 역학물성 분석)

  • Kim, Sang-Ryong;Kim, Seung-Jin;Gwon, O-Gyeong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.150-152
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    • 2008
  • 사회가 발달하여 감성사회로 접어들면서, 섬유산업도 새로운 감성소재를 개발하기 위한 연구를 추구하고 있다. 이러한 분야의 연구수단으로 생체모방(Biomimetics)을 활용하는 연구개발이 활발히 진행되고 있는데, 이중 미래지향적인 차세대 섬유로 Morphotex(R)를 이용한 Morpho 직물이 있다. 감성소재분야에서 '구조발색섬유'라고 불리어지는 독특한 색미를 가진 섬유소재인 Morphotex$^{(R)}$는 남미의 MORPHO 나비 날개의 구조적 발색원리를 모방하여 만든 광발색섬유로 염료와 안료를 사용하지 않는 친환경섬유이면서 고기능성과 쾌적성을 겸비한 소재로 요즘 많은 각광을 받고 있다. 본 연구에서는 구조발색 소재를 이용하여 제직한 감성의류소재 직물의 감량조건에 따른 감성특성을 비교.분석해보았다. 먼저 구조발색 소재로 제직 된 직물의 감량공정특성에 따른 구조발색 소재 직물의 인장 인열 특성을 분석하였으며 또한 KES-FB system으로 구조발색 소재 직물의 역학특성을 측정하고 측정한 역학특성으로부터 감성태를 평가해 보았다.

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Analysis on the Physical Properties of $Prism^{(R)}$ Fabrics for garment According to Caustic Reduction Conditions (의류용 구조발색 섬유의 감량조건에 따른 물성 분석)

  • Jo, Jin-Hwang;Kim, Sang-Ryong;Choe, Yeong-Hui;Kim, Seung-Jin
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.59-60
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    • 2008
  • 본 연구는 섬유의 구조적, 광학적 설계에 의해 빛의 간섭현상을 이용하여 색을 발현하는 구조발색 의류소재의 개발을 위하여 삼각단면의 구조발색섬유를 방사하고 직물을 제직한후 온도와 시간에 따른 삼각단면 섬유소재의 감량조건을 달리하여 그에 따른 $Prism^{(R)}$ 의류용 직물의 역학물성 및 태 특성을 측정하였다. 역학물성에는 인장특성, 인열특성을 측정하였으며 KES-FB system을 이용하여 역학물성을 측정 후 Hand value를 산출하였다.

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Application of Enzymatic Hydrolysis for the Yield Optimization in Froth-Flotation of ONP

  • Ryu, Jeong-Yong;Song, Bong-Keun;Song, Jae-Kwang
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.129-136
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    • 2006
  • Although cleaner and cheaper deinking of ONP could be performed at the neutral or low alkaline condition excessive loss from froth-flotation is unavoidable and so reduction of alkali or caustic soda dosage sacrifices recycling yield. Now the new trade-off regarding alkali dosage versus flotation yield is urgently required in order to set the optimized neutral or low alkaline deinking process of ONP. Lipase from Thermomyces Lanuginosus has an effect on desizing and deacetylation reaction and it could be applied to the stock of pre flotation secondary stage in order to reduce the flotation reject without the sacrifice of optical properties of flotation accepts. Instead of inorganic base, lipase could be applied as a biochemical catalyst for the selective modification of valuable hydrophobic particles in deinking stock, for example cellulose fines and inorganic fillers covered by hydrophobic additives or contaminants. When the enzymatic hydrolysis of ester bond could be made on the surface of hydrophobic particulates, unwanted float of fine particles could be prevented. Now the enhancement of flotation selectivity or the modification of the hydrophobicity of deinking stock is expected to be promoted by the enzymatic pre treatment. And the reduction of recycling cost with the saves of raw material, recovered paper would be possible as a result.

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Improvement in Early Strength of Concrete Using Blast Furnace Slag by KOH (KOH에 의한 고로슬래그 미분말을 사용한 콘크리트의 초기강도 향상)

  • Lee, Ju-Sun;Song, Ri-Fan;Park, Byoung-Kwan;Back, Dae-Hyun;Pei, Chang-Chun;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.05b
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    • pp.53-56
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    • 2009
  • This study reviewed the characteristics of concrete made of performance improving mixture materials based on KOH as a means to resolve the problems of initial quality reduction that result in concretes with blast furnace slag powder. Summarizing the results, first as the characteristics of fresh concrete, liquidity was found to reduce in general with increased BS substitution ratio. Objective range of liquidity was not satisfied in all mixes according to the use of performance improving mixture materials. Air capacity was satisfied to the objective range in all mixes. As the characteristics of hardened concrete, while compressive strength showed a decreasing trend with increasing BS substitution ratio at early age, increasing trend was shown by the plain with increasing BS substitution ratio at later age. On the other hand, K1 and K2 were only effective among mixture materials at early age, but K1F30 showed excellent strength at both early and later ages.

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Kinetic Study on Preparation of Iron Fine Powders by Hydrogen Reduction of Ferous Chloride Vapor (염화물의 기상환원반응에 의한 미립질 철분말의 생성속도에 관한 연구)

  • Lee, Hwa-Yeong;Kim, Seong-Gyu
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.385-391
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    • 2000
  • A kinetic study on the preparation of iron powder by hydrogen reduction of ferrous chloride vapor has been carried out both experimentally and theoretically. For the preparation of iron powder, ferrous chloride was vaporized and transported to a reaction zone by Ar gas used as carrier. Ferrous chloride vapor and hydrogen were mixed and subject to a reduction reaction at high temperature to produce iron powder and HCI gas. Iron powder was collected with organic solvent at the end of reaction zone and HCI gas was also absorbed in a caustic soda solution to determine the conversion ratio of ferrous chloride. For the development of rate equations, a 1st-order reaction and equilibration of ferrous chloride vapor with Ar gas were assumed. According to the results, the rate constant, k could be expressed as $k=7,879exp(-53,840/RT)\textrm{dm}^3/mole.sec$ and the activation energy was found to be 53.84kJ/mole. From TEM observation, the particle size distribution of iron powder produced was found to be in the range of $0.1~1.0{\mu\textrm{m}}$ which was not significantly influenced by reaction temperature or gas flow rates.

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Reuses Of Wash Water Effluents Of The Ion-Exchanger Units Of Water Demineralization Plant For Economic And Environmental Benefits

  • Miah, Raisuddin
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.799-806
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    • 1995
  • In industrial field, a large volume of regenerants (acid and caustic soda) and their washing effluents are regularly disposed off from the water demineralization plant during regeneration of the ion-exchanger units. Of these waste effluents, a part of the wash water discharged from the single bed Anion and Mixed Bed units can be utilized at a certain stage of their washing cycles when its conductivity is fallen down and becomes considerably less than that of the input raw water. The main aim of this specific waste effluent utilization is to dilute the TDS concentration of the input raw water (fed into the single bed ion-exchanger units) by blending. The achievement is the increase of the longevity of the production cycles of the I.E. units along with the improvement of the production quality and decrease of the regeneration frequencies. As a result, regenerant consumption would be saved because of the reduction of ionic load in feed water which will ultimately reduce the water purification cost. At the same time, the environment pollution will also be protected to a considerable extent. This operational measure is quite effective and useful specially where high TDS water is demineralized only by single bed ion-exchangers. In such case, the water treatment plant is very often found to suffer from both production quality and quantity in addition to carrying out of random and restless regenerations. Proper reuses of the aforesaid wash water effluents of the Anion and MB units excellently minimizes the difficulties experienced in practice. This paper contains the utilities and techniques of reuses of the different kinds of waste effluents of the industrial water treatment plant in addition to the specific reuses of the post-regeneration wash waters of the Anion and MB ion-exchanger units.

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Studies on the Bituminization Process of Radioactive Liquid Waste[I]

  • Lee, Sang-Hoon;Chun, Kwan-Sik;Lim, Eung-Keuk
    • Nuclear Engineering and Technology
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    • v.7 no.3
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    • pp.213-222
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    • 1975
  • Immobilization of the second-cycle radioactive liquid wastes from a Purex process was developed with the blown asphalt (manufactured by Kukdong Shell Oil Company Ltd) to eliminate the possibility that the radioactive materials will be redispersed into the environment. Attempts to incorporate these wastes directly into the asphalt martrices without any pretreatment were not successful, as it was observed that the sulphuric acid in the waste oxidised the asphalt. Hence, the waste was treated with caustic soda and made alkaline prior to bituminization, so that it was found that this pretreatment made the waste compatible to the asphalt matrices. The pure blown asphalt samples irradiated with doses of 4.0$\times$10$^{7}$ rad showed no evidence of volume increase. The suitable temperature for incorporation of the alkaline wastes into blown asphalt was 180-20$0^{\circ}C$. The Products containing 50 wt% salts represented the following good properties viz., volume reduction (about 1.4), homogeneity, teachability etc. During the period of 131 day $s^{l37}$Cs from products containing 40wt% salts was leached at rates ranging from 2.70$\times$10-4 to 8.27$\times$10-4g/cm2_day but the rate for $^{90}$ Sr was lower by one to two orders of magnitude by distilled water. The leaching rates for $^{137}$ Cs and $^{90}$ Sr by sea water were slightly lower than by distilled water. Both of the leaching rates decreased with increasing pH.H.

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