• Title/Summary/Keyword: cationic agent

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Interaction between Polyelectrolytes Layer-by-Layer Assembled Fibers and Fluorescent Whitening Agent (고분자전해질 LbL multilayering 처리된 섬유와 형광증백제와의 반응성)

  • Sim, Kyu-Jeong;Lee, Sung-Rin;Chin, Seong-Min;Ryu, Jae-Ho;Youn, Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.4
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    • pp.71-77
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    • 2010
  • To utilize modified pulp fibers in papermaking system, it is necessary to evaluate the interaction between modified fibers and papermaking additives. Fluorescent whitening agent (FWA) is an important additive which has been widely used for production of writing and printing paper. We modified pulp fiber surface by Layer-by-Layer multilayering of polyelectrolytes, and investigated the interaction between these fibers and FWA used in internal addition or surface treatment. Pulp fiber with cationic surface charge showed a good affinity to internal FWA. For FWA in surface sizing agent, whiteness and brightness of paper was dependent on pickup weight and polyelectrolyte type. Pulp fibers with C-starch/PSS multilayer showed better optical properties than poly-DADMAC/PSS treatment. It indicated that polyelectrolyte type in Layer-by-Layer multilayering as well as a good affinity to FWA is important to get better whiteness and brightness.

Dye-resist Properties of Hetero-multifunctional Dye-resist Agents in Acid Dyeing of Wool

  • Oh Myung-Joon;Koh Joon-Seok;Kim Jae-Pil
    • Fibers and Polymers
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    • v.7 no.2
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    • pp.117-122
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    • 2006
  • The dye-resist effect and leveling properties of hetero-mulifunctional dye-resist agents in acid dyeing of wool were investigated. The dye-resist agent with dichlorotriazinyl group achieved better resist effectiveness than those with monochlo-rotriazinyl group. The resist effectiveness was improved by increasing the number of sulfonate group in dye-resist agents. Also, the resist agents with more sulfonate groups showed better dye-assist effectivness, attributable to the increased electrostatic attraction between dye-resist agents and the cationic dye. However, the leveling properties of dye-resist agents decreased with the number of sulfonate groups in the molecule.

HYDROLYZED GINSENG-SAPONIN QUATERNARY; A NOVEL CONDITIONING AGENT FOR HAIR CARE PRODUCTS

  • Kim, Young-Dae;Kim, Chang-Kew;Lee, Chung-Nam;Ha, Byung-Jo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.14 no.1
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    • pp.16-37
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    • 1988
  • A new quaternary ammonium compound, hydrolyzed ginseng-sapoin quaternary (HGSQ), from hydrolyzed Korean ginseng-saponin and 2, 3-epoxypropyltrimethyl ammonium chloride has been developed as a conditioning agent for hair care products. This structure has the hydrophilic group from the introduced cationic and the hydrophobic group from the aglycone of ginseng saponin. Its properties: surface tension, conductivity, critical micelle concentration, eye irritation, sorption onto hair, force reduction (%) for 20% extension and moisture retention effect comparing with the commercial standards. Also half-head tests of HGSQ-containing shampoo were carried out to compare the conditioning effects in shampoos.

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Novel Hydroxy-terminated Copolyether-based Polyurethane system for Propellant Binder (새로운 폴리에테르 공중합체 디올(HTPE)을 사용한 추진제용 폴리우레탄 바인더)

  • Yoo Ho-Joon;Song Jong-Kwon;Lee Bum-Jae;Hwang Gab-Sung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.229-232
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    • 2006
  • Two novel synthetic route proposed for Hydro-Terminated Poly(EO-ran-THF) and tri-block(PEC-PTHF-PEG) copolymer by cationic ring-opening polymerization of tetrahydrofuran(THF) and ethylene oxide(EO) and just by polymerization of EO on poly-THF, respectively. Polyurethane was synthesized from random and tri-block HTPE using N-100/IPDI mixture as curing agent, and TPB(Triphenylbismuth) as catalyst. The mechanical properties of resultant polyurethane after mixing with various ratio of isocyanate was also investigated. Finally, the post treatment process of HTPE based on amount of catalyst used in the synthesis was studied, to evaluate the optimum curing condition for the polyurethane propellant binder.

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Synthesis of Novel Hydroxy-terminated Polyether for Solid Propellent Polyurethane Binder (고체 추진제용 폴리우레탄 바인더를 위한 새로운 폴리에테르 공중합체 디올(HTPE)의 합성)

  • Shin, Bum-Sik;Lee, Bum-Jae;You, Ho-Joon;Park, Young-Chul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.05a
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    • pp.221-226
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    • 2008
  • Novel synthetic routes were proposed for hydroxy-terminated Poly(EO-co-THF) by Cationic ring-opening copolymerization of Tetrahydrofuran(THF) and Ethylene oxide(EO). It was carried out using Boron trfluoride tetrahydrofuranate($BF_3$ THF complex) as catalyst in the presence of 1,4-butandiol. The resultant products are well-defined linear polyetherpolyol. Polyurethane(TPU) were prepared using resultant polyetherpolyol with IPDI/N-100 as curing agent and TPB(Triphenylbismuth) /MA(Maleic anhydride) mixture as cure catalyst. Mechanical properties of TPU prepared from poly(EO-co-THF) polyol were investigated and compared with polyurethane using ATK HTPE.

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Improvement of Ink Jet Printing Paper Quality with Oxidized Starch Ester and Additives (산화에스테르전분과 첨가제를 활용한 잉크젯용지의 품질개선)

  • Jung, Kwang Ho;Jeong, Young Bin;Lee, Hak Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.4
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    • pp.21-26
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    • 2013
  • The effect of esterified starch as surface sizing agent for inkjet printing paper has been evaluated and compared with oxidized starch. Also the influence of various additives including cationic poly-DADMAC, stearic acrylic copolymer, calcium chloride, and GCC was examined. Results showed that starch ester gave higher ink density than oxidized starch. Addition of poly-DADMAC improved water fastness. In general, low molecular weight poly-DADMAC performed better than high molecular weight one, and it was attributed to the fact that it gave more uniform film forming characteristics in surface sizing. Use of styrene acrylic acid copolymer increased hydrophobicity of the paper surface, but it did not increase the ink density. Use of GCC and calcium chloride had only marginal effect on printing quality.

Recycling of Wastepaper(X) -Improvement of Fines Fractionation through Multi-Stage Froth-Flotation and Addition of Cationic Polyelectrolyte as a Fractionating Promoter for OCC Flotation- (고지재생연구(제10보) -골판지 고지의 미세분 분급효율 개선을 위한 다단계 부산부유 처리 및 분급 촉진제 적용-)

  • 여성국;류정용;신종호;송봉근
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.4
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    • pp.27-33
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    • 2000
  • A new technique for fractionating pulp stock into a long fiber portion and fines fraction was developed by KRICT in order to enhance the drainage and strength properties of recycled OCC pulp. In order to investigate the effect of fines contents in stock and stages of flotation on fractionation efficiency, flotations were performed at varied fines contents and flotation stages. Based on the result of multi-stage flotation fractionation it could be said that fines smaller than 15${\mu}{\textrm}{m}$ stabilize flotation froth of OCC. Although the amounts and the fines contents of flotation reject could be increased by multi-stage flotation fractionation of OCC, flotation stages more than 3 times were found to be inefficient in terms of fines concentrating degree. In order to satisfy the both conditions of reducing long fiber loss and of increasing flotation reject, several kinds of fractionating promoters were searched and investigated. And high molecular weight cationic polyacrylamide was chosen as a long fiber flocculating and flotation froth-stabilizing agent.

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A SINGLE FLOCCULANT/DUAL FLOCCULATION SYSTEM FOR DEWATERING USING A BRANCHED SELF INVERSING EMULSION FLOCCULANT

  • Bae, Young-Han;Lee, Sung-Sik
    • Environmental Engineering Research
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    • v.11 no.4
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    • pp.208-216
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    • 2006
  • In order to create a single flocculant/dual flocculation system, polyacrylamide-co-trimethyl ammonium ethyl acrylate chloride (TAEAC) polymers with varying molecular weights and structures were prepared for use of flocculants. The higher the cationic density of the polymer is higher, the higher was the conversion rate and the ratio of monomer. An acrylamide as nonionic monomer was less reactive than a TAEAC as cationic monomer. The branched polymer which was polymerized with a cross-linking agent, N, N-methylene bis-acrylamide had a higher stability and higher viscosity than a linear polymer but its dewatering efficiency was poor in a single flocculation system. In the case of single flocculant/dual flocculation, the branched polymer has better flocculation efficiency and the water content of the dewatered cakes was lower than the others, as the result of a re-flocculation effect. The optimum conditions for dual flocculation are a sequence in which the $1^{st}$ and $2^{nd}$ dosage are 75% and 25%/total dosage of a single flocculation system. The dewatering efficiency of a dual flocculation system is improved considerably from 10 to 25% under the experimental conditions used herein.

Antimicrobial Activity of Antimicrobial Peptide LPcin-YK3 Derived from Bovine Lactophoricin

  • Kim, Ji-Sun;Jeong, Ji-Ho;Cho, Jang-Hee;Lee, Dong-Hee;Kim, Yongae
    • Journal of Microbiology and Biotechnology
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    • v.28 no.8
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    • pp.1299-1309
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    • 2018
  • We previously reported on lactophoricin (LPcin), a cationic ${\alpha}-helical$ antimicrobial peptide derived from bovine milk, which has antimicrobial effects on Candida albicans as well as Gram-positive and Gram-negative bacteria. In this study, we designed the LPcin-YK3 peptide, a shorter analog of LPcin, and investigated its antimicrobial activity. This peptide, consisting of 15 amino acids with + 3 net charges, was an effective antimicrobial agent against the on the Gram-positive strain, Staphylococcus aureus (MIC: $0.62{\mu}g/ml$). In addition, the hemolytic activity assay revealed that the peptide was not toxic to mouse and human erythrocytes up to $40{\mu}g/ml$. We also used circular dichroism spectroscopy to confirm that peptide in the presence of lipid has ${\alpha}-helical$ structures and later provide an overview of the relationship between each structure and antimicrobial activity. This peptide is a member of a new class of antimicrobial agents that could potentially overcome the problem of bacterial resistance caused by overuse of conventional antibiotics. Therefore, it could be used as a therapeutic or natural additive, particularly in the cosmetics industry.

Effects of PCC Loading at Thick Stock on the Paper Properties (고농도 지료에서의 PCC 충전이 종이 물성에 미치는 영향)

  • Won, Jong-Myoung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.4
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    • pp.62-68
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    • 2012
  • This study was carried out to evaluate the effect of PCC loading at thick stock on the physical properties of paper. The effect of starch addition(2, 4 and 6%) and mixing time(5, 10 and 20 min.) on the filler retention and paper properties were investigated. Optimum dosage of cationic starch as a fixing agent was 4%, and mixing time did not showed any significant effect on the filler retention. PCC loading at thick stock was more effective to improve bulk and opacity than PCC loading at thin stock, although their improvement was not so significant. It was also found that the strength properties could be improved by the loading at thick stock. PCC loading method at thick stock could be considered as one of potential approaches for further improving of paper properties, although further research works are required in order to apply the PCC loading at thick stock in the paper mill.