• Restorative Dentistry and Endodontics
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• 제18권2호
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• pp.431-445
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• 1993

The purpose of this study was to observe corrosion characteristics of six dental amalgams and was to analyse corrosion products electrochemically. After each amalgam alloy and Hg was triturated as the direction of the manufacturer by using mechanical amalgamator, the triturated mass was inserted into the cylinderical metal mold ($12{\times}10mm$) and was condensed with 160kg/$cm^2$ by using the hydrolic press. The specimen was removed from the mold and was stored at room temperature for 1 week, and was polished with amalgam polishing kit. The anodic and cathodic polarization curve was obtained by using cyclic voltammetric method with 3-electrode potentiostat in saline for each amalgam and Ag, Sn, Cu plate specimen at $37{\pm}0.5^{\circ}C$. The potential sweep range was -1.7V~0. 4V(vs SCE) in working electrode and scan rate was 50mV/s and the exposed surface area of each specimen to the electrolytic solution was $0.79cm^2$. The results were as follows. 1. In anodic-cathodic polarization curve of amalgam specimens, two anodic current rising areas and two cathodic current peaks were obtained at the low Cu amalgam(CF, CS) specimen and three anodic current rising areas and three cathodic current peaks were obtained at the high Cu amalgam (TY, DS, HV) specimen. 2. As this compared with the anodic and cathodic current peak potentials of Sn, Cu and Ag specimen, the first cathodic current peak I c was caused by the reduction of divalent tin salt, second cathodic current peak IIIc results from the reduction of quadravalent tin salt, and third cathodic current peak me results from the reduction of copper salt. 3. As reverse potential sweeping was done repeatedly, anodic current was decreased slightly in all amalgam specimens.

• 한국가스학회지
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• 제14권6호
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• pp.38-43
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• 2010

자원 부족과 환경규제의 강화에 따라 자동차 강판재의 고강도화와 박강판화가 주요 이슈로 대두되고 있다. 그러나 고강도 강판재 사용에 있어 수소취성은 기계적 성질 저하의 문제가 되고 있다. 본 연구에서는 개발중인 590MPa급 DP강을 대상으로 조성 및 조직특성에 따른 표면층에서의 수소의 거동에 대해 연구하였다. 수소주입은 음극전기분해법을 이용하여 강제 주입시켰고, 수소주입조건에 따른 수소주입량과 표면층 조직관찰 및 미소경도시험 결과의 관계로 부터 표면층의 수소거동을 평가하였다.

• 대한기계학회논문집A
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• 제26권6호
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• pp.1107-1113
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• 2002

This study presents the hydrogen emblittlement in the metal, which decreases the ductility and then induces the brittle fracture. The contribution deals with the effect of strain rate and notch geometry on hydrogen emblittlement of 1.25Cr-0.5Mo and 2.25Cr-1Mo steels, which are in use at high pressure vessel. Smooth and notched specimens were examined to obtain the elongation and tensile strength. For charging the hydrogen in the metal, the cathodic electrolytic method was used. In this process, current density is maintained constant. The amount of hydrogen penetrated in the specimen was detected by the hydrogen determenator(LECO RH404) with the various charging time. The distribution of hydrogen concentration penetrated in the specimen was obtained by finite element analysis. The amount of hydrogen is high in smooth specimen and tends to concentrate in the vicinity of surface. The elongation and tensile strength decreased with the passage of charging time in 1.25Cr-0.5Mo and 2.25Cr-1Mo steels. The elongation increased and tensile strength decreased as strain rate increased. As a result of this study, it is supposed that 1.25Cr-0.5Mo steel is more sensitive than 2.25Cr-lMo steel in hydrogen embrittlement. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• 한국가스학회지
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• 제10권3호
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• pp.41-47
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• 2006

가스배관, 상수관, 송유관 등의 지중 매설배관이 직류 전기철도와 인접해 있는 경우, 전기철도 시스템의 귀선 회로로 사용되는 레일에서 누설되는 표유전류에 의해 이들 금속배관에는 전기적 부식, 즉 전식이 발생할 수 있다. 전식에 의한 집중 부식은 전기방식으로 보호되는 배관에 있어서도 지속적인 재료의 열화와 이에 따른 파손을 일으킬 수 있어 대형사고로 발전할 소지를 가지고 있다. 국내에서는 이러한 표유전류에 대한 대책으로 배관과 레일을 전기적으로 접속하는 배류법이 적용되고 있는데 특히 가스배관을 중심으로 한 강제배류법의 급속한 증가에 의해 간섭문제가 매우 복잡해지고 있다. 본 논문에서는 직류전기철도시스템과 매설배관 사이의 전기적 간섭 문제를 서울과 부산 지역에서 수행한 현장 실태조사의 결과를 통해 살펴본다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1990년도 추계학술대회 논문집 학회본부
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• pp.161-165
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• 1990

KEPCO has experienced eight oil leakage failures due to POF cable corrosion in the 154KV underground POF cable transmission line since the line was operated in 1976. Experimentally, We have verified that the cause of the failure is electrolytic corrosion of the cable owing to subway leakage current. For the countermeasure, We adopted the total Cathodic Protection System by the use of Victim Anode, Forced Drainage Method and Impressed Current Method with polarization cell.

• Bulletin of the Korean Chemical Society
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• 제15권11호
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• pp.945-949
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• 1994

Mixtures of cyano complexes of palladium(II) and platinum(II) were separated by capillary electrophoresis using a fused silica capillary as a separation column and 30 mM phosphate buffer (pH 7) containing 15 wt. % acetonitrile as a running buffer. By virtue of the high ionic mobilities of the negatively charged cyano complexes of Pd(II) and Pt(II), they were separated using a cathodic injection and anodic detection scheme. The metal complexes eluted through the capillary were detected by direct UV absorption at 214 nm. A linear relationship between peak area and concentration was obtained for both ions and the detection limit was lower than $10^{-14}$ mole. The proposed method was applied to real sample, e.g., anode slime obtained from an electrolytic copper refinary, as a method for the simultaneous determination of palladium and platinum.

• 한국압력기기공학회 논문집
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• 제11권2호
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• pp.61-67
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• 2015

3D FEM modeling based on 3D CAD data has been performed to evaluate the efficiency of CP system in a real operating nuclear power plant. The results of it successfully produced sophisticated profiles of electrolytic potential and current distributions in the soil of an interested area. This technology is expected to be a breakthrough for detection technology of damages on buried pipes when it comes into combining with a brand of area potential earth current (APEC) and ground penetrated radar (GPR) technologies. 2D current distribution and 2D current vectors on the earth surface from the APEC survey will be used as boundary conditions with exact 3D geometry data resulting in visualization of locations and extents of corrosion damages on the buried pipes in nuclear power plants.

• 한국수소및신에너지학회논문집
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• 제12권3호
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• pp.231-238
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• 2001

Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2001년도 추계학술발표회 초록집
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• pp.56-56
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• 2001

Ni-W alloy deposit is one of the best alternatives to hard chromium plating because of its good mechanical properties (high hardness, high strength, and good wear resistance). Ni-W alloy is deposited from weakly acidic or alkaline electrolytic bath with nickel sulfate, sodium tungstate or APT, and some kinds of organic hydroxy-acid complex and ammonia salts. W content of the deposit can be changed from 0 to 5Owt% and the coating with high W content is more attracted. But, meanwhile, the deposited layers are always found high internal stress, which cause them to become brittle and to bond insufficiently with the substrate. On the second hand, as the W content is incresed, the current efficiency reduced, which results in large quantities of hydrogen evolution and then produces bubbles on surface and pitting appearance In this paper, the influence of some additives on Ni-W alloy electroplating was investigated by means of compositional analysis and SEM. The initial results showed that 2-butyne-1,4-diol was the best brightener for Ni-W plating process. It could brighten and level deposit, but decreased the cathodic current efficiency. Its optimum concentration range is from O.lgjL to 0.5gjL. Besides, three kinds of additives including 2-butyne-1,4-diol were examined with Dagguchi method.

• 한국응용과학기술학회지
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• 제35권3호
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• pp.612-621
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• 2018

본 연구에서는 전기분해 방법을 이용한 질산성질소($NO_3{^-}-N$) 분해가 $TiO_2$ nanotube plate 및 구리, 니켈, 스테인리스 스틸, 알루미늄, 주석, 티타늄을 환원전극으로 사용하였을 때 가능한지를 평가하였다. 전극의 전기화학적 특성 평가는 임피던스 측정을 하여 비교하였고, $TiO_2$ nanotube plate의 표면 분석은 주사전자현미경을 통해 SEM 및 BET 분석법을 이용한 비표면적 분석을 통해 비교하였다. 질산성질소 전해실험의 경우 90분의 실험을 진행하였으며, 실험 결과 전극 표면의 부식이 수반되지 않은 $TiO_2$ nanotube plate가 기타 금속 전극에 비해 질산성질소 환원 반응속도가 가장 뛰어난 것으로 확인되었다.