• Clean Technology
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• v.15 no.3
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• pp.147-153
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• 2009

Waste three-way catalysts were remanufactured by ultrasonic wave treatment followed by active component re-impregnation and the catalytic activities and surface properties of remanufactured catalysts were measured at various remanufacturing conditions. In case of the catalyst prepared by ultrasonic wave cleaning, the optimal period for elimination of surface contaminants from the waste catalyst was found to be about 5 minutes. The proper re-impregnation amounts of the active components for the best catalytic performance were investigated and the catalytic performance tests were also carried out with various temperature for the total hydrocarbon (THC), carbon monoxide (CO) and nitrogen oxides (NOx) conversions. The experimental results showed that the catalytic performances of the remanufactured catalysts were recovered almost the same level as those of the fresh catalyst except those of the NOx conversion.

• Analytical Science and Technology
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• v.18 no.5
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• pp.436-443
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• 2005

A study of physical properties and their application using K-powdered activated carbon system followed powdered carbon dispersion was carried out at laboratory. scale. Two types of K-powdered activated carbon for the dispersion have been used in this study to investigate the catalytic removal efficiency of pollutants from the wastewater. From the surface properties obtained for carbon samples treated with aqueous solutions containing potassium salts, main investigations were subjected to isotherm shape, SEM, EDX and surface functional groups. K-powdered activated carbons were dispersed to wastewater with pH variation to investigate the removal efficiency for the color, COD, T-N and T-P. From these removal results of the piggery waste using K-powdered activated carbon, satisfactory removal performance in the region of pH 6~8 was achieved. The excellent effects for the dispersion of the K-powdered activated carbon were proved by the above mentioned properties of the material for adsorption and trapping of organics, and catalytic effects.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.403.2-403.2
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• 2016

Porous materials play a significant role in energy storage and conversion applications such as catalyst support for polymer electrolyte membrane fuel cell. In particular, hierarchical porous materials with both micropores (poresize, ${\delta}$ < 2 nm) and regularly arranged mesopores (2 nm < ${\delta}$ < 50 nm) are known to greatly enhance the efficiency of catalytic reactions by providing enormous surface area as well as fast mass transport channels for both reactants and products from/to active sites. Although it is generally agreed that the microscopic structure of the porous materials directly affects the performance of these catalytic reactions, neither detailed mechanisms nor fundamental understanding are available at hand. In this study, we propose an atomistic model of hierarchical nanostructured porous carbons (HNPCs) in molecular dynamics simulations. By performing a systematic study, we found that structural features of the HNPC can be independently altered by tuning specific synthesis parameters, while remaining other structures unchanged. In addition, we show some structure-property relations including mechanical and gas transport properties.

• Bulletin of the Korean Chemical Society
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• v.23 no.5
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• pp.721-726
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• 2002

Two new C2-symmetric chiral $\alpha-$ and w-Diimines incorporating bulky ferrocenylethylamine and their copper(I)complexes have been synthesized and characterized by analytical and various spectroscopic techniques. The catalytic activities of these complexes have been tested in the asymmetric cyclopropanation of a series of olefins with some diazoacetates to achieve varying degree of dia- and enantio-selectivities depending on the nature of the ligand, the substrates, and the reagents. Some mechanistic implication has been made with regard to the interactions among all these chemical species.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.3
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• pp.445-451
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• 2002

The refractory-lined pipe is used to protect the system from high-temperature of the internal flow. The property of the refractory has an effect upon the stress analysis for fluid catalytic cracking(FCC) unit piping design. The equivalent elastic modulus and density considering steel and refractory must be applied in the stress analysis of the system. In the research, the theoretical method to obtain the value of the equivalent property is introduced and then the parametric analysis is carried out to understand the characteristic of the material properties, and the stress analysis is performed with reactor, the part of FCC unit.

• Carbon letters
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• v.5 no.4
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• pp.186-190
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• 2004

In this work, a nickel metal (Ni) electroplating on the activated carbon fiber (Ni/ACFs) surfaces was carried out to remove the toxic hydrogen chloride (HCl) gas. The surface properties of the treated ACFs were determined by using nitrogen adsorption isotherms at 77 K, SEM, and X-ray diffraction (XRD) measurements. HCl removal efficiency was confirmed by a gas-detecting tube technique. As a result, the nickel metal contents on the ACF surfaces were increased with increasing the plating time. And, it was found that the specific surface area or the micropore volume of the ACFs studied was slightly decreased as increasing the plating time. Whereas, it was revealed that the HCl removal efficiency containing nickel metal showed higher efficiency values than that of untreated ACFs. These results indicated that the presence of nickel metal on the ACF surfaces played an important role in improving the HCl removal over the Ni/ACFs, due to the catalytic reactions between nickel and chlorine.

• Journal of Electrochemical Science and Technology
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• v.4 no.3
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• pp.89-92
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• 2013

Poly (3,4-ethylenedioxythiophene) (PEDOT) polymers with different electric conductivities were synthesized directly on a FTO substrate via a chemical polymerization method and applied as a platinum (Pt)-free counter electrode for dye-sensitized solar cells (DSSCs). The catalytic properties of the PEDOT as a function of electrical conductivity were studied using cyclic voltammograms, J-V measurements and impedance spectroscopy. The PEDOT counter electrode with around 340 S/cm conductivity exhibited the best performance as a counter electrode for tri-iodide reduction. The ability to modulate catalytic activity of PEDOT with changes in conductivity shows one of promising routes for developing new counter electrode of Pt-free DSSCs.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.176.1-176.1
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• 2014

Graphene has attracted an increasing attention due to its extraordinary electronic, mechanical, and thermal properties. Especially, the two dimensional (2D) sheet of graphene with an extremely high surface to volume ratio has a great potential in the preparation of multifunctional nanomaterials, as 2D supports to host metal nanoparticles (NPs). Copper oxide is widely used in various areas as antifouling paint, p-type semiconductor, dry cell batteries, and catalysts. Although the copper oxide(II) has been well known for efficient catalyst in C-N cross-coupling reaction, copper oxide(I) has not been highlighted. In this research, CuO and Cu2O nanoparticles (NPs) dispersed on the surface of grapehene oxide (GO) have been synthesized by impregnation method and their morphological and electronic structures have been systemically investigated using TEM, XRD, and XAFS. We demonstrate that both CuO and Cu2O on graphene presents efficient catalytic performance toward C-N cross coupling reaction. The detailed structural difference between CuO and Cu2O NPs and their effect on catalytic performance are discussed.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.93-93
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• 2011

Nanostructures consisting of $TiO_2$ particles as a core and carbon as a shell ($TiO_2$@C) were prepared by heat treatment of $TiO_2$ nanoparticles at high temperature in a methane atmosphere. X-ray diffraction and transmission electron microscopy showed that a carbon shell layer was formed well. These structures were used as supports for platinum nanoparticles and the hybrid particles exhibit improved catalytic activity and stability toward ORR compared to Pt on a carbon black (Vulcan XC-72R). It is likely that enhanced catalytic properties of the Pt on $TiO_2$@C could be due to the stability of the core-shell support in comparison with carbon black support.

• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1091-1097
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• 2014

Tageteserecta flower like zinc oxide nanostructures composed of hexagonal nanorods were synthesized via sonochemical method at room temperature. The synthesized nanomaterials exhibited wurtzite hexagonal phase structure with the single crystalline nature. The diameter of the individual nanorods that constitute the flower shaped zinc oxide structures is in the range of 120-160 nm. The sonication time effectively determined the morphological properties of the prepared materials. The catalytic activity of prepared zinc oxide nanostructures towards N-formylation reactions were evaluated without any surface modification and the nanostructures exhibited good reaction yield with the prompt recyclability behavior.