• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2013년 춘계학술대회
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• pp.655-668
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• 2013

In this study, a combination of the plasma discharge in the reactor by the reaction surface discharge reactor complex catalytic reactor and air pollutants, hazardous gas SOx, change in frequency, residence time, and the thickness of the electrode, the addition of simulated composite catalyst composed of a variety of gases, including decomposition experiments were performed by varying the process parameters. 20W power consumption 10kHz frequency decomposition removal rate of 99% in the decomposition of sulfur oxides removal experiment that is attached to the titanium dioxide catalyst reactor experimental results than if you had more than 5% increase. If added to methane gas was added, the removal efficiency increased decomposition, the oxygen concentration increased with increasing degradation rate in the case of adding carbon dioxide decreased.

• 한국대기환경학회지
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• 제22권1호
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• pp.43-51
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• 2006

Nonthermal plasma-driven catalysis (PDC) was investigated for the decomposition of benzene and toluene as model compounds of volatile organic compounds (VOCs) at atmospheric pressure and low temperature. Two types of catalysts Ag/$TiO_{2}$ and Pt/$\gamma-Al_{2}O_{3}$ were tested in this study. The amount of catalysts packed in the PDC reactor did not influence on the decomposition efficiency of benzene. The type of catalysts also had no influence on the decomposition efficiency of toluene and carbon balance. The Ag/$TiO_{2}$ catalyst showed constant $CO_{2}$ selectivity of about $73\%$ regardless of the specific input energy. However, the selectivity of $CO_{2}$ was greatly enhanced with the Pt/$\gamma-Al_{2}O_{3}$ catalysts, and reached $97\%$ at 205 J/L. Two test runs with 20 fold difference in the gas flow clearly indicated that lab-scale data can be successfully applied for the scaling-up of PDC system.

• 한국안전학회지
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• 제27권5호
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• pp.77-87
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• 2012

Compared to a batch reactor, where all reactants are initially charged to the reactor, the semi-batch reactor presents serious advantages. The feed of at least one of the reactants provides an additional way of controlling the reaction course, which represents a safety factor and increases the constancy of the product quality. The aim of this study was to investigate the characteristics of thermal hazard such as a feed time, catalysis concentration and solvent concentration in methylthioisocyanate(MTI) synthesis reaction process. The experiments were carried out by the Multimax reactor system and Accelerating rate calorimeter(ARC). The MTI synthesis reaction process has many reaction factors and complicated reaction mechanism of multiphase reaction. Through this study, we can use as a tool for assessment of thermal hazard of other reaction processes by applying experiment method provided.

• 한국대기환경학회지
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• 제23권2호
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• pp.203-213
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• 2007

Numerical analysis has been performed to understand flow characteristics in the reactor with bag filters in an integrated adsorption/catalytic process which can treat dioxin and $NO_{x}$ together. Computational fluid dynamics technique was employed with Euler-Lagrangian model to consider flue gas and activated carbon particles simultaneously, so that residence time of flue gas and activated carbon particle could be obtained from the numerical analysis directly. The numerical analysis has been performed with different three particle sizes and compared each flow characteristics with particle's size. Fundamental flow patterns of flue gas and activated carbon particles, pressure distribution, residence time of flue gas and activated carbon particles, and distribution of activated carbon have been obtained from the numerical analysis. Flow patterns of flue gas and activated carbon particles in the reactor were very complicated and they moved along very various paths. Therefore, their residence time in the reactor was also various. The results obtained would be effectively used to estimate the removal efficiency in the reactor once the residence time is combined with the reaction equation.

• Korean Chemical Engineering Research
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• 제43권1호
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• pp.98-102
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• 2005

본 연구에서는 유기금속 전구체인(HFAC)Cu(DMB)을 이용하여 구리를 제조하고, 기판온도 및 요오드 화합물이 증착 구리막의 표면 형상 및 충진 특성에 미치는 영향을 살펴보았다. 증착 온도가 높을수록 표면 형상이 거칠어지고 충진 특성이 악화되었으며, 요오드를 사용하여 증착할 경우 표면 거칠기와 충진 특성이 개선됨을 알 수 있었다. 이때 요오드 화합물과 전구체를 동시에 반응기에 유입할 경우보다 구리의 씨앗층을 증착하고 요오드 화화물을 반응기에 유입한 후 다시 구리 증착을 진행하는 경우가 좀 더 효과가 컸다.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 1999년도 추계학술대회 논문집
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• pp.453-454
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• 1999

최근 대기 환경오염이 심각한 문제로 부각됨에 따라 독성 유기물질 분해 및 제독에 반도체 광촉매를 이용한 광산화기술(Advanced Oxidation Process, AOP)을 적용한 연구가 활발히 진행되고 있다. 1972년 Fujishima와 Honda가 전압을 걸어준 TiO$_2$ 단결정 전극상에 자외선을 쪼이면 물이 수소와 산소로 광분해되는 것을 발견한 이후 분균일 광촉매반응(Heterogeneous Photocatalysis)에 관한 연구가 시작되었다.(중략)

• 대한기계학회논문집A
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• 제32권11호
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• pp.1016-1021
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• 2008

The development of the first wall whose major function is to withstand high neutron and heat fluxes is a critical path to fusion power. The materials database and the fabrication technology are being developed for design, construction and safety operation of the fusion reactor. The first wall was designed to consist of the plasma facing armor, the heat sink layer and the supporting plates. and Porous materials are of significant interest due to their wide applications in catalysis, separation, lightweight structural materials. In this study, the characteristics of the sintering process of SiC ceramic, $SiC_f$/SiC composite and porous $C_f$/SiC composite have been introduced order to study of the fusion blanket materials and heat-exchange pannel.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2012년 춘계학술대회
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• pp.421-433
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• 2012

The objective of this study is to obtain the optimal process condition and the maximum decomposition efficiency by measuring the decomposition efficiency, electricity consumption, and voltage in accordance with the change of the process variables such as the frequency, maintaining time period, concentration, electrode material, thickness of the electrode, the number of windings of the electrode, and added materials etc. of the harmful atmospheric contamination gases such as NO, $NO_2$, and $SO_2$etc. with the plasma which is generated by the discharging of the specially designed and manufactured $TiO_2$ catalysis reactor and SPCP reactor.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.245-245
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• 2012

Syntheses of oxide supported metal catalysts by wet-chemical routes have been well known for their use in heterogeneous catalysis. However, uniform deposition of metal nanoparticles with controlled size and shape on the support with high reproducibility is still a challenge for catalyst preparation. Among various synthesis methods, arc plasma deposition (APD) of metal nanoparticles or thin films on oxide supports has received great interest recently, due to its high reproducibility and large-scale production, and used for their application in catalysis. In this work, Au and Pt nanoparticles with size of 1-2 nm have been deposited on titania powder by APD. The size of metal nanoparticles was controlled by number of shots of metal deposition and APD conditions. These catalytic materials were characterized by x-ray diffraction (XRD), inductively coupled plasma (ICP-AES), CO-chemisorption and transmission electron microscopy (TEM). Catalytic activity of the materials was measured by CO oxidation using oxygen, as a model reaction, in a micro-flow reactor at atmospheric pressure. We found that Au/$TiO_2$ is reactive, showing 100% conversion at $110^{\circ}C$, while Pt/$TiO_2$ shows 100% conversion at $200^{\circ}C$. High activity of metal nanoparticles suggests that APD can be used for large scale synthesis of active nanocatalysts. We will discuss the effect of the structure and metal-oxide interactions of the catalysts on catalytic activity.

• KSBB Journal
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• 제17권4호
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• pp.396-402
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• 2002

바이오디젤(지방산 메틸 에스테르)은 생분해성, 무독성, 그리고 재생연료로서 지난 10여년간 많은 관심을 끌고 있다. 바이오디젤을 생산하기 위해 다양한 방법들이 개발되었는데, 그 중 알칼리 촉매를 이용한 에스테르화 반응이 짧은 시간동안 높은 수율을 얻을 수 있다. 따라서 본 연구에서는 알칼리 촉매하에 에스테르화 반응의 최적조건을 찾기 위하여 response surface method를 사용하였다. 결과적으로 바이오디젤 생산 공정에 영향을 주는 7개의 변수 중 반응온도, 반응시간, 그리고 교반속도가 중요했는데 이들의 최적 값은 각각 67$^{\circ}C$, 68분, 94 rpm이었다. 이와같은 최적인 조건하에서 실험한 결과 바이오디젤로의 전화율은 99.7%이었다.