• 한국수소및신에너지학회논문집
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• 제25권4호
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• pp.344-354
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• 2014

Activated charcoal supported nickel molybdenum carbide (carburized Ni-Mo/AC) catalysts were prepared by wet-impregnation followed by temperature-programmed carburization using 20% $CH_4/H_2$ gas. The effects of pH and initial Ni/Mo mole ratio during wet-impregnation step on the characteristics of the carburized Ni-Mo/AC catalysts were investigated using ICP, XRD, XPS, BET and $CO_2$-TPD techniques, and correlated with the catalytic activity of the carburized Ni-Mo/AC in methane dry reforming reaction. Comparison of the results of methane dry reforming reaction kinetics with the results of characterization of the carburized Ni-Mo/AC catalyst showed that the catalytic activity in methane dry reforming reaction was higher at higher initial Ni/Mo mole ratio or at lower pH(3~natural value). This phenomenon was related to the crystal size of metallic Ni in the carburized Ni-Mo/AC catalyst.

• 열처리공학회지
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• 제34권6호
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• pp.272-280
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• 2021

The influence of acetylene flow rates on the carburizing behavior of an AISI 4115 steel in 1 ton-class mass production-type vacuum carburizing furnace has been studied through microstructure, carbon concentration, hardness analyses. The AISI 4115 steels were carburized with various flow rates (20, 32.7, 60 l/min) and locations in the furnace (top, center, bottom) at 950℃. The acetylene flow rate played an important role in controlling the carburizing properties of carburized samples, such as effective case depth and uniformity carburizing according to location in the furnace. At an acetylene flow rate of 20 l/min, the carburized samples had a shallow average hardened layer (0.645 mm) compared to the target hardening depth (1 mm) due to low carbon flux and spatial uniformity of carburization (17.8%) in the furnace. At a flow rate of 60 l/min, the carburized samples showed an average hardened layer (1.449 mm) deeper than the target hardening depth and had the spatial uniformity of carburization (98.8%). In particular, at a flow rate of 32.7 l/min, the carburized samples had an average hardened layer (1.13 mm) close to the target hardening depth and had the highest carburizing uniformity (99.1%). As a result, an appropriate flow rate of 32.7 l/min was derived to satisfy the target hardening depth and to have spatial uniform hardened layer in the furnace.

• The Korean Journal of Ceramics
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• 제2권4호
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• pp.197-202
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• 1996

The highly oriented diamond particles were deposited on the mirror-polished (100) silicon substrates in the bell-jar type microwave plasma deposition system using a three-step process consisting if carburization, bias-enhanced nucleation and growth. By adjusting the geometry of the substrate and substrate holder, very dense disc-shaped plasma was formed over the substrate when the bias voltage was below -200V. Almsot perfectly oriented diamond films were obtained only in this dense disc-shaped plasma. From the results of the optical emission spectra of the dense disc-shaped plasma, it was found that the concentrations of atomic hydrogen and hydrocarbon radical were increased with negative bias voltage. It was also found that the highly oriented diamonds were deposited in the region, where the intensity ratios of carbonaceous species to atomic hydrogen are saturated.

• 한국안전학회지
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• 제14권4호
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• pp.13-19
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• 1999

This study deals with effects of heat-treatment on the bending fatigue of SCM420 spur gears. The test gears are heat-treated by two different treatments. After carburization, one group of the test gears is quenched directly, while another group is furnace cooled, reheated then quenched. The fatigue test at a constant stress amplitude is performed by using an electrohydraulic serve-controlled pulsating tester. The S-N curves are obtained and illustrated. By comparing the estimated strength with the experimental results, the validity of the previous experimental formula, presented by the authors for estimating the fatigue strength of carburized gears, was discussed for these tested gears.

• 한국분말재료학회지
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• 제6권4호
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• pp.320-324
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• 1999

The formation, microstructure and properties of novel ceramic composite materials manufactured by active-filler-controlled polymer pyrolysis were investigated. In the presence of active filler particles such as transition metals, bulk components of various geometry could be fabricated from siliconorganic polymer. Molybdenum- and tungsten-filled polymer suspensions were prepared and their conversion to ceramic composites by annealing in $CH_4$ atmosphere were studied. Dimensional change. porosity and phase distribution (filler network) were analyzed and correlated to the resulting hardness values. Molybdenum and tungsten as active filler were carburized completely to $Mo_2C$, $W_2C$ and WC in $CH_4$ atmosphere. Consequently, microcrystalline composites with the filler reaction products embedded in a silicon oxycarbide glass matrix were formed. Hardness was increased with increasing carburization and reached 8.6-9.5 GPa in the specimen pyrolyzed in $CH_4$ atmosphere.

• Applied Microscopy
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• 제43권2호
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• pp.81-87
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• 2013

The influence of carbide formation on mechanical properties has been investigated in carburized steels. Through controlled diffusion and precipitation processes, the morphologies of carbides could be changed and then fine, networked, and spherical shapes at carburized layers were obtained. These morphological changes affected tensile and bending fatigue properties of the steel. The fine and the spherical carbides acted as resistance sites against crack propagation, which improved the mechanical properties. However, the networked carbides deteriorated the properties because the cracks propagated along the boundaries of them. These results indicate that the morphological control of carbides is one of important keys to improve the mechanical properties.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 하계학술대회 논문집 C
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• pp.1542-1545
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• 2002

Experimental works were performed to implement the hetero-epitaxial growth of diamond films on the (100)- and (111)-oriented Si substrates. The deposition process used to prepare diamond films consisted of a bias-enhanced nucleation(BEN) step, accompanied with a growth step using a microwave plasma CVD system. The highly oriented diamond films were deposited under the growth condition of relatively low methane concentrations and high temperatures. Material properties and surface morphologies of deposited diamond films were improved by the addition of carburization step into the deposition process.

• 한국기계가공학회지
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• 제11권6호
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• pp.139-144
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• 2012

In the automobile industry, the various efforts to lower their industrial cost and enhance fuel efficiency have been made through process improvement or weight saving of automobile parts. Gear is one of significant parts of transmission, which is made by cast iron or alloy steel. It is expensive due to complex processing, inferior materials and large machining allowance. In this study, alternative gear cars oil which is based on fluid applications materials is produced by reducing surface induction hardening and carburizing hardened in production. And then, wear characteristic and mechanical properties such as hardness of the sintered alloy which is used as a substitute for small machining allowance is investigated.

• Advances in materials Research
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• 제3권1호
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• pp.283-295
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• 2014

In this paper, the microstructure, hardness, tensile deformation and fracture behavior of high strength alloy steel X2M is presented anddiscussed. The influence of both composition and processing on microstructure of the as-provided material and resultant influence of microstructure, as a function of orientation, on hardness, tensile properties and final fracture behavior is highlighted. The macroscopic mode and intrinsic microscopic features that result from fracture of the steel specimens machined from the two orientations, longitudinal and transverse is discussed. The intrinsic microscopic mechanisms governing quasi-static deformation and final fracture behavior of this high strength steel are outlined in light of the effects oftest specimen orientation, intrinsic microstructural effects and nature of loading.

• 한국분말재료학회지
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• 제9권3호
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• pp.167-173
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• 2002

A new approach to produce nanostructured WC/Co composite powders by a mechanochemical process was made to improve the mechanical properties of advanced hardmetals. Homogeneous spherical W-Co salt powders were made by spray drying of aqueous solution from ammonium metatungstate($(NH_4)_6(H_2W_{12}O_{40})\cdo4H_2O$,AMT) and cobalt nitrate hexahydrate (Co(NO$_3$)$_2$.6$H_2O$). spray dried W-Co salt powders were calcined for 1 hr at $700^{\circ}C$ in atmosphere of air. The oxide powder was mixed with carbon black by ball milling and this mixture was heated with various temperatures and times in $H_2$. The $WO_3/CoWO_4$ composite oxide powders were obtained by calcinations at $700^{\circ}C$. The primary particle size of W/Co composite oxide powders by SEM was 100 nm. The reduction/carburization time decreased with increasing temperatures and carbon additions. The average size of WC particle carburized at $800^{\circ}C$ by TEM was smaller than 50 nm.