• Journal of the Korea Furniture Society
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• v.25 no.3
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• pp.207-212
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• 2014

With increased interests in environmental issues, people are looking for new materials that serve special and bio-activated functions. One of interesting materials is charcoal which has excellent adsorption ability for harmful volatile organic compounds, fireproof performance, far-infrared ray emission, and electromagnetic shielding. Since non-crack carbonized board was developed from wood-based composite materials, carbonization method might be applied to woodcraft products such as wood cup and bamboo. In this study, manufacture of wood charcoal bowl was conducted with carbonization method developed in 2009 in order to activate wood products market. Ash tree(Fraxinus rhynchophylla) cup was carbonized at $600^{\circ}C$ with two pretreatments which were phenol resin and wood tar solution treatment. After carbonization of ash tree cup, non-crack charcoal cup were successfully manufactured. Phenol resin treatment affected on charcoal cup manufacturing both positively and negatively. For a positive way, it prevented shrinkage. For a negative way, it decreased water repellency. On the contrary, wood tar treatment accelerated shrinkage a bit and increased water repellency. Based on the results, wood tar can be used as pre-treatment solution for reducing post-treatment costs. We confirmed woodcraft products can be carbonized without deformation, so carbonization may provide a high value-added products from wood.

• Journal of the Korean Wood Science and Technology
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• v.35 no.4
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• pp.21-28
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• 2007

To analyze the changes in pH and elemental content ratio of wood charcoal and in FT-IR spectra of their surfaces, wood charcoals carbonized from Pinus koraiensis were used. pHs of wood charcoals carbonized from Pinus koraiensis at 300 and $400^{\circ}C$ were 5-27 and 6.80, respectively, whereas they were between 9.25~10.35 for the wood charcoals manufactured between $500{\sim}900^{\circ}C$ From the changes in the elemental ratios of Pinus koraiensis wood charcoal by increasing carbonization temperature, carbon (C) contents increased by elevating the carbonization temperature with the decreasing in content ratios of O and H. The largest changes in the ratio was found between the carbonization temperature 400 and $500^{\circ}C$. Ratios of C, O, H of the wood charcoal manufactured at 300 and $400^{\circ}C$ were 67.7, 28.9, 3.0% and 72.2, 24.9, 2.5%, respectively, while those at $500{\sim}900^{\circ}C$ were between 83.3~90.5, 13.6~9.0, 2.7~0.3%. The surface functional groups of Pinus koraiensis wood charcoals were determined by comparison of FT-IR spectra of the wood powder and the wood charcoal carbonized with the wood powder. The functional groups on the surface of wood charcoals carbonized at 300 and $400^{\circ}C$ were considered to be acidic groups like Lactone, Lactol, Carboxylic acid, Carboxylic anhydride, whereas Pyrone types could be the major functional groups for the wood charcoals carbonized between 500 and $900^{\circ}C$.

• Journal of the Korean Wood Science and Technology
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• v.26 no.2
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• pp.6-15
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• 1998

A total of forty five-ply, 30- by 30-cm lauan and larch plywood sheets were manufactured in the laboratory using commercial urea and phenol resin adhesives; half of these sheets were treated with fresh concrete. Each sheet was carbonized for 2, 4, and 6hours at $400^{\circ}C$, $600^{\circ}C$, and $750^{\circ}C$, respectively, and their physical properties were measured. The yie1d of charcoal decreased as carbonization temperature and time increased. Charcoal yield was greater in plywood than in veneer, and slightly greater in plywood treated with concrete compared to untreated plywood. Plywood manufactured with phenol resin adhesive had higher pH, higher equilibrium moisture content (EMC), and greater adsorption of methylene-blue dye compared to plywood manufactured with urea resin. For concrete-treated plywood, pH was greater than 10 even when the sheets were carbonized for 2hours at $400^{\circ}C$. Although the EMC of the phenol resin plywood was higher than that of the urea resin plywood, EMC of the phenol resin was lower than that of the urea resin. The larch phenol resin plywood that was carbonized for 6 hours at $750^{\circ}C$ adsorbed more methylene-blue than did the commercia1 wood-based activated charcoal as a result of total pore volume and surface area.

• Journal of the Korean Wood Science and Technology
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• v.46 no.6
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• pp.656-669
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• 2018

Tropical bamboo species, which have a very rapid growth rate, are considered as a promising non-timber forest product capable of exhibiting new functionality by carbonization technology. This study was conducted to compare the characteristics of carbonized bamboos from Andong (G. pseuudoarundinacea (Steudel) Widjaja), Hitam (G. atrovialacea), Tali (G. apus), Kuning (B. vulgaris Var. striata (Lodd. Ex Lindl)), and Ampel (B. vulgaris Scharad. ex Wendland), and Betung (D. asper). Each bamboo was carbonized at 200, 400, 600, 800, and $1,000^{\circ}C$, respectively, and their physical and anatomical characteristics were investigated. The result showed that the volume and weight of carbonized bamboo decreased with increasing carbonization temperature and showed the substantial changes of volume and weight between 200 and $400^{\circ}C$. The highest and the lowest density of carbonized samples were found in Ampel bamboo and Betung bamboo, respectively. The density of all carbonized bamboos tended to decrease after carbonization at 200 and $400^{\circ}C$ and relatively become constant afterwards. The carbonized bamboo prepared at 800 and $1,000^{\circ}C$ showed better refining degree. The results of the anatomical observation showed that the vascular diameter of carbonized bamboo decreased with increasing carbonization temperature, and the shrinkage in radial and tangential direction showed similar tendency. Statistical analysis showed that there was significant correlation between physical contraction and anatomical contraction. Based on the results of this study, comprehensive data about Indonesian bamboo charcoals could be obtained and it will be useful for future application studies.

• Journal of the Korean Wood Science and Technology
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• v.41 no.5
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• pp.440-446
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• 2013

To understand transition characteristics from wood to charcoal, Quercus variabilis wood was carbonized at 200, 250, 300, 340, 540 and $740^{\circ}C$, respectively. Heating value, pH and surface property by FT-IR spectroscopy of the carbonized charcoal were investigated. Heating value and pH increased with increasing carbonization temperature from 4500 cal/g and 4.3 of the control wood to 8,000 cal/g and 9 of the charcoal carbonized at $740^{\circ}C$, respectively. From FT-IR spectroscopy, the peaks from O-H, C-H and C-O stretching disappeared during carbonization at 540 and $740^{\circ}C$. Aromatic skeletal vibration at near $1,506{\sim}1,593cm^{-1}$ was repidly increased until $540^{\circ}C$. These results suggest that the chemical and physical characteristics of wood components in cell wall can be easily changed by increasing carbonization temperature and the carbonization seem to be incomplete at temperature below $540^{\circ}C$.

• Journal of the Korean Wood Science and Technology
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• v.30 no.1
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• pp.34-39
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• 2002

This study examined the effect of carbonized wastewoods on purification of waste water. The purification ability of charcoals(lump-shaped, approximately 3×3×3 cm) maded by wood-based material for waste water from a kitchen and septic tank was superior to those of thinned wood. For lump-shaped charcoal, gaps between particles in particleboard, and gaps between fibers in MDF were much more effective than micropore in purification of waste water. After purification test, color of waste water from wood-based material charcoals were much more lighter than thinned wood charcoals. In addition, odors of waste water from both charcoals tended to be decreased.

• Journal of the Korean Wood Science and Technology
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• v.48 no.4
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• pp.417-430
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• 2020

The flame retardancy, such as carbonized length and area, of four plank type wood products by the spreading concentration and impregnation time of flame retardant were measured according to standard of the Nation Fire Agency in Republic of Korea. To measure the flame retardancy, Korean pine plywood, Japanese larch plywood, Japanese cypress planks, and perforated birch plywood boards were treated with self-development flame retardant by 300 and 500 g/㎡ spreading concentration and those were compared with control specimen. In general, the flame retardant performance of wood products improved as the spreading concentration of flame retardant increased. Except for Japanese larch plywood, there was no significant difference in the flame retardant performance by the spreading concentration. The flame retardant performance of perforated birch plywood board was positively correlated up to 60 minutes of impregnation time, but then gradually decreased. These results about the flame retardancy of wood products by spreading concentration and impregnation time were expected to be basic data for improving flame-retardant treated wood.

• Journal of the Korean Wood Science and Technology
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• v.35 no.4
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• pp.29-37
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• 2007

To evaluate the effect of carbonization temperature of charcoal on the heavy metal adsorption property, Quercus mongolica wood and Larix kaempferi bark powder (100~60 mesh) were carbonized at between 400 and $900^{\circ}C$ at intervals of $100^{\circ}C$. In the properties of carbonized materials which affect the adsorption ability, pH increased with increasing the carbonization temperature, so that the pHs of wood and bark charcoal carbonized at $900^{\circ}C$ were 10.8 and 10.4, respectively. Also, in both materials, the carbon content ratio became larger as the carbonization temperature was raised. At the same carbonization temperature, carbon content ratio of the bark charcoal tended to be greater than that of the wood charcoal. In case of iodine adsorption which indicates the adsorption property in liquid phase, the wood charcoal showed higher adsorption value than the bark charcoal. From the investigation of adsorptive elimination properties of the charcoals against 15 ppm Cd, Zn, and Cu, the higher the carbonization temperature, the greater elimination ratio was. In comparison, the wood charcoal presented higher elimination ratio than that of the bark charcoal. In the wood charcoals carbonized at higher than $500^{\circ}C$, especially, 0.2 g of the charcoal was enough to eliminated almost 100% of the heavy metal ions. Heavy metal ion elimination ratio of the charcoals depended on the kinds of adsorbates. The effectiveness of adsorbates in adsorptive elimination by the charcoals were in order of Cu > Cd > Zn. This is because the physicochemical interaction between the adsorbate and adsorbent affects their adsorption properties, it is considered that subsequent researches are needed to improve the effectiveness of heavy metal adsorption by the charcoals.

• Journal of Forest and Environmental Science
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• v.30 no.2
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• pp.226-232
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• 2014

To understand transition characteristics from wood to charcoal the dimensional changes of carbonized woods at low temperature from $300^{\circ}C$ to $350^{\circ}C$ at the intervals of $10^{\circ}C$ were investigated. Three species of hardwoods and two species of softwoods were used in this study. Measurements of dimensional changes of cells were observed by stereoscopic microscope and an image analyzer. The apparent volume of each specimen decreased greatly with increasing temperature. Severe cracks and collapse were observed frequently in hardwoods and hardly in softwoods. Vessel diameter and tracheid cell wall thickness of the wood samples were decreased with increasing carbonization temperature. Contraction of vessel diameter in tangential direction was greater than that in radial direction. Cell wall thickness of tracheids decreased with increasing carbonization temperature. Consequently, even though it was small range of carbonization temperature, dimensions of wood components were changed considerably.

• Journal of the Korean Wood Science and Technology
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• v.36 no.3
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• pp.39-46
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• 2008

Repeated impregnation and carbonization processes were performed to prepare high-density woodceramics using a sawdust board. The physical properties were investigated to confirm morphological and structural changes of one-time and two-time phenolic resin-treated and carbonized woodceramics. As comparing between one-time and two-time carbonized woodceramics, the weight and the density of the two-time carbonized woodceramics decreased with an increase of the amount of impregnated phenolic resin. In addition, when the amount of impregnated phenolic resin was about 40% in these woodceramics, the two-time carbonized woodceramics showed higher weight (23.8%) and density (30.0%) than the one-time treatment.