• 한국가구학회지
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• 제25권3호
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• pp.207-212
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• 2014

With increased interests in environmental issues, people are looking for new materials that serve special and bio-activated functions. One of interesting materials is charcoal which has excellent adsorption ability for harmful volatile organic compounds, fireproof performance, far-infrared ray emission, and electromagnetic shielding. Since non-crack carbonized board was developed from wood-based composite materials, carbonization method might be applied to woodcraft products such as wood cup and bamboo. In this study, manufacture of wood charcoal bowl was conducted with carbonization method developed in 2009 in order to activate wood products market. Ash tree(Fraxinus rhynchophylla) cup was carbonized at $600^{\circ}C$ with two pretreatments which were phenol resin and wood tar solution treatment. After carbonization of ash tree cup, non-crack charcoal cup were successfully manufactured. Phenol resin treatment affected on charcoal cup manufacturing both positively and negatively. For a positive way, it prevented shrinkage. For a negative way, it decreased water repellency. On the contrary, wood tar treatment accelerated shrinkage a bit and increased water repellency. Based on the results, wood tar can be used as pre-treatment solution for reducing post-treatment costs. We confirmed woodcraft products can be carbonized without deformation, so carbonization may provide a high value-added products from wood.

• Journal of the Korean Wood Science and Technology
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• 제35권4호
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• pp.21-28
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• 2007

탄화온도에 따른 목탄의 pH, 원소함량비와 목탄 표면의 FT-IR 변화를 분석하기 위하여 잣나무 목탄이 사용되었다. 300, $400^{\circ}C$의 탄화온도에서 제조된 잣나무 목탄의 pH는 각각 5.27, 6.80로 측정된 반면, $500{\sim}900^{\circ}C$에서 제조된 시료의 pH는 크게 높아져 9.25~10.35로 나타났다. 탄화 온도의 차이에 따른 목탄의 원소 조성비 변화에 있어서는, 고온 탄화 목탄일수록 C 함유율이 높아지고 상대적으로 O, H의 함유율은 낮아졌다. 가장 큰 원소 조성비 변화 폭은 400와 $500^{\circ}C$의 탄화 온도에서 측정되었다. 300, $400^{\circ}C$에서 제조된 목탄의 C, O, H 원소함량비는 각긱 67.7, 28.9, 3.0%와 72.2, 24.9, 2.5%로 측정된 반면, $500{\sim}900^{\circ}C$ 사이에서 제조된 목탄의 C, O, H 함량비는 각각 83.3~90.5%, 13.6~9.0%, 2.7~0.3% 사이로 나타났다. FT-IR에 의한 목탄 표면 관능기 분석은 탄화 전 목분과 각각 $300{\sim}900^{\circ}C$ 사이의 온도에서 제조된 목탄의 IR-스펙트럼 비교로 이루어졌다. 300와 $400^{\circ}C$에서 탄화된 목탄의 표면에는 Lactone, Lactol, Carboxylic acid, Carboxylic anhydride 등의 산성 관능기들을 많이 포함하는 것으로 유추되는 반면, $500^{\circ}C$ 이상의 온도에서 탄화된 목탄의 경우에는 Pyrone 계토의 관능기를 많이 포함하는 것으로 판단된다.

• Journal of the Korean Wood Science and Technology
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• 제26권2호
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• pp.6-15
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• 1998

A total of forty five-ply, 30- by 30-cm lauan and larch plywood sheets were manufactured in the laboratory using commercial urea and phenol resin adhesives; half of these sheets were treated with fresh concrete. Each sheet was carbonized for 2, 4, and 6hours at $400^{\circ}C$, $600^{\circ}C$, and $750^{\circ}C$, respectively, and their physical properties were measured. The yie1d of charcoal decreased as carbonization temperature and time increased. Charcoal yield was greater in plywood than in veneer, and slightly greater in plywood treated with concrete compared to untreated plywood. Plywood manufactured with phenol resin adhesive had higher pH, higher equilibrium moisture content (EMC), and greater adsorption of methylene-blue dye compared to plywood manufactured with urea resin. For concrete-treated plywood, pH was greater than 10 even when the sheets were carbonized for 2hours at $400^{\circ}C$. Although the EMC of the phenol resin plywood was higher than that of the urea resin plywood, EMC of the phenol resin was lower than that of the urea resin. The larch phenol resin plywood that was carbonized for 6 hours at $750^{\circ}C$ adsorbed more methylene-blue than did the commercia1 wood-based activated charcoal as a result of total pore volume and surface area.

• Journal of the Korean Wood Science and Technology
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• 제46권6호
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• pp.656-669
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• 2018

Tropical bamboo species, which have a very rapid growth rate, are considered as a promising non-timber forest product capable of exhibiting new functionality by carbonization technology. This study was conducted to compare the characteristics of carbonized bamboos from Andong (G. pseuudoarundinacea (Steudel) Widjaja), Hitam (G. atrovialacea), Tali (G. apus), Kuning (B. vulgaris Var. striata (Lodd. Ex Lindl)), and Ampel (B. vulgaris Scharad. ex Wendland), and Betung (D. asper). Each bamboo was carbonized at 200, 400, 600, 800, and $1,000^{\circ}C$, respectively, and their physical and anatomical characteristics were investigated. The result showed that the volume and weight of carbonized bamboo decreased with increasing carbonization temperature and showed the substantial changes of volume and weight between 200 and $400^{\circ}C$. The highest and the lowest density of carbonized samples were found in Ampel bamboo and Betung bamboo, respectively. The density of all carbonized bamboos tended to decrease after carbonization at 200 and $400^{\circ}C$ and relatively become constant afterwards. The carbonized bamboo prepared at 800 and $1,000^{\circ}C$ showed better refining degree. The results of the anatomical observation showed that the vascular diameter of carbonized bamboo decreased with increasing carbonization temperature, and the shrinkage in radial and tangential direction showed similar tendency. Statistical analysis showed that there was significant correlation between physical contraction and anatomical contraction. Based on the results of this study, comprehensive data about Indonesian bamboo charcoals could be obtained and it will be useful for future application studies.

• Journal of the Korean Wood Science and Technology
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• 제41권5호
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• pp.440-446
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• 2013

To understand transition characteristics from wood to charcoal, Quercus variabilis wood was carbonized at 200, 250, 300, 340, 540 and $740^{\circ}C$, respectively. Heating value, pH and surface property by FT-IR spectroscopy of the carbonized charcoal were investigated. Heating value and pH increased with increasing carbonization temperature from 4500 cal/g and 4.3 of the control wood to 8,000 cal/g and 9 of the charcoal carbonized at $740^{\circ}C$, respectively. From FT-IR spectroscopy, the peaks from O-H, C-H and C-O stretching disappeared during carbonization at 540 and $740^{\circ}C$. Aromatic skeletal vibration at near $1,506{\sim}1,593cm^{-1}$ was repidly increased until $540^{\circ}C$. These results suggest that the chemical and physical characteristics of wood components in cell wall can be easily changed by increasing carbonization temperature and the carbonization seem to be incomplete at temperature below $540^{\circ}C$.

• Journal of the Korean Wood Science and Technology
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• 제30권1호
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• pp.34-39
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• 2002

국내 주요 간벌재와 목질재료 탄화물중 성능면과 자원면을 고려하여 선정한 후 오수정화 실험을 실시하였다. 덩어리상태(약 3×3×3 cm)의 탄화물의 주방오수 및 정화조오수 정화실험에서 간벌재 탄화물보다 목질재료 탄화물의 정화능력이 뛰어났다. 덩어리상태에서는 미세세공보다는 파티클보드의 파티클 및 MDF의 섬유간의 간극이 정화에 더 유효하게 작용했기 때문이라고 판단된다. 처리오수의 색은 처리 후 옅어졌으며 목질재료탄이 간벌재탄보다 더 옅은 색을 보였다. 냄새는 모두 감소하는 경향을 보였다.

• Journal of the Korean Wood Science and Technology
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• 제48권4호
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• pp.417-430
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• 2020

4종의 판상형 목재제품의 방염제 도포량과 침지시간에 따른 방염성능을 분석하기 위하여 소방청의 방염성능기준에 따라 목재제품의 탄화길이와 탄화면적을 측정하였다. 잣나무 합판, 낙엽송 합판, 편백 판재, 타공처리된 자작나무 합판에 자체 개발된 방염제를 각각 300, 500 g/㎡씩 도포하고 방염처리되지 않은 시험편과 비교하였다. 일반적으로 방염제의 도포량이 증가함에 따라 탄화길이와 탄화면적이 감소하여 방염성능이 증가하는 경향을 나타냈으나, 낙엽송 합판을 제외하고 탄화길이와 탄화면적의 감소량이 크지 않았다. 타공처리된 자작나무 합판의 침지시간에 따른 방염성능은 60분의 침지시간까지 양의 상관관계를 나타냈으나, 그 이후 점차 완만해지는 경향을 보였다. 방염제의 도포량과 침지시간에 따른 목재제품의 방염성능은 추후 방염성능 기준에 맞는 불연·준불연 목재의 생산을 위한 기초자료로 이용될 것으로 기대된다.

• Journal of the Korean Wood Science and Technology
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• 제35권4호
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• pp.29-37
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• 2007

탄화온도 차이에 따른 목질 탄화물의 중금속 흡착성 변화를 알아보기 위하여, 신갈나무(Quercus mongolica) 목부와 낙엽송(Larix kaempferi) 수피분말을 $400{\sim}900^{\circ}C$에서 탄화하였다. 목질 탄화물의 pH는 재료의 종류와 관계없이 탄화온도의 증가와 함께 증가하여 $900^{\circ}C$의 목탄 및 수피탄은 각각 10.8, 10.4를 나다내었다. 또한 탄화 온도 증가와 함께 탄소함량비가 증가하고 동일 탄화온도에서 목탄에 비해 수피탄의 탄소함량비가 큰 경향을 보였다. 액상흡착력을 나타내는 요오드흡착력은 목탄이 수피탄보다 다소 큰 경향을 나타내었다. 이러한 특성을 지닌 목탄과 수피탄에 의한 15ppm의 Cd, Zn 및 Cu 중금속용액에 대한 흡착제거율을 조사한 바, 높은 탄화온도에서 제조된 목탄과 수피탄일수록 높은 중금속제거율을 나타내었으며, 탄화물 종류에 있어서는 목탄이 수피탄 보다 높은 중금속 제거율을 나타내는 경향이 있었다. 특히 목탄의 경우, $500^{\circ}C$ 이상에서 제조된 탄화물 0.2 g의 사용으로 거의 100%에 가까운 제거율을 나타내었다. 한편 흡착질 종류에 있어서의 제거성능에는 다소 차이가 있으며, 본 연구에서 사용한 탄화물의 흡착성은 Cu>Cd>Zn 순으로 높았다. 이는 목탄과 같은 흡착제와 흡착의 대상이 되는 흡착질과의 물리 화학적 상호관계가 흡착에 영향을 주기 때문으로 목탄의 흡착효율을 높이기 위해서는 이에 대한 연구가 더 필요할 것으로 생각된다.

• Journal of Forest and Environmental Science
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• 제30권2호
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• pp.226-232
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• 2014

To understand transition characteristics from wood to charcoal the dimensional changes of carbonized woods at low temperature from $300^{\circ}C$ to $350^{\circ}C$ at the intervals of $10^{\circ}C$ were investigated. Three species of hardwoods and two species of softwoods were used in this study. Measurements of dimensional changes of cells were observed by stereoscopic microscope and an image analyzer. The apparent volume of each specimen decreased greatly with increasing temperature. Severe cracks and collapse were observed frequently in hardwoods and hardly in softwoods. Vessel diameter and tracheid cell wall thickness of the wood samples were decreased with increasing carbonization temperature. Contraction of vessel diameter in tangential direction was greater than that in radial direction. Cell wall thickness of tracheids decreased with increasing carbonization temperature. Consequently, even though it was small range of carbonization temperature, dimensions of wood components were changed considerably.

• Journal of the Korean Wood Science and Technology
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• 제36권3호
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• pp.39-46
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• 2008

고밀도 우드세라믹을 제조하기 위한 기초연구로서 수지함침율에 따라 제조된 1차 탄화 우드세라믹을 수지 재함침 후 2차 탄화하여 우드세라믹을 제조하고 그 물리적 성질을 조사하였다. 1, 2차 탄화 우드세라믹의 성질 비교에서 수지함침율이 증가함에 따라 2차 탄화 후 중량 및 밀도증가율은 감소하였고, 수지함침율 40%일 때 1차 탄화 시보다 중량은 23.8%, 그리고 밀도는 30.0% 증가하여 최고치를 나타냈다.