• KCI Concrete Journal
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• 제12권1호
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• pp.79-89
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• 2000

This research developed an accelerated curing processe for cellulose fiber reinforced cement composites using vigorous reaction between carbon dioxide and cement paste. A wet-processed cellulose fiber reinforced cement system was considered. Carbonation curing was used to complement conventional accelerated curing. The parametric study followed by optimization investigation indicated that the carbonation curing can enhance the productivity and energy efficiency of manufacturing cellulose fiber reinforced cement composites. This also adds environmental benefits to the technical and economical advantages of the technology.

• Computers and Concrete
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• 제23권5호
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• pp.351-359
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• 2019

In this study, the calcium hydroxide, an inherent product of cement hydration, was treated using biomimetic carbonation method of incorporating stearic acid to generate the hydrophobic calcium carbonate on concrete surface. Carbonation reaction was carried out at various $CO_2$ pressure and temperatures and utilizing the Scanning Electron Microscope (SEM), chloride-ion penetration test apparatus, and compression test machine to investigate the hydrophobicity, durability, and mechanical properties of the synthesized products. Experimental results indicate that the calcium stearate may change the surface property of concrete from hydrophilicity to hydrophobicity. Increasing reaction temperature can change the particles from irregular shapes to needle-rod structures with increased shear stress and thus favorable to hydrophobicity and microhardness. The contact angle against water for the concrete surface was found to increase with increasing $CO_2$ pressure and temperature, and reached to an optimum value at around $90^{\circ}C$. The maximum static water contact angle of 128.7 degree was obtained at the $CO_2$ pressure of 2 atm and temperature of $90^{\circ}C$. It was also found that biomimetic carbonation increased the permeability, acid resistance and chloride-ion permeability of the concrete material. These unique results demonstrate that the needle-rod structures of $CaCO_3$ synthetized on concrete surface could enhance hydrophobicity, durability, and mechanical properties of concrete.

• 자원리싸이클링
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• 제32권6호
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• pp.18-24
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• 2023

본 연구에서는 염소 바이패스 분진을 광물 탄산화하여 시멘트의 원료 및 콘크리트 혼화재로 적용하기 위한 초기 연구를 수행하였다. 염소 바이패스 분진의 물리적·화학적 특성을 확인하기 위해 수세 처리 유무 및 수세 횟수에 따른 XRD, XRF, 입도분포 분석을 수행하였으며 그에 따른 특성 변화를 확인하였다. 분진의 종류, 교반 온도, 시간 경과에 따른 염소 바이패스 분진의 광물 탄산화 결과 수세 미처리 샘플은 최대 24%이었으며 수세 처리 샘플은 27%이었으나 실험 조건에 따라 광물 탄산화의 속도 및 정도는 상이하였다. 수세 처리된 분진이 수세 미처리 분진에 비해 더 많은 광물 탄산화가 일어난 이유는 칼슘 함량이 더 높았기 때문이라고 판단되었다. 또한, 더 높은 교반 온도는 초기 광물 탄산화를 더 촉진시키지만 분진의 종류 및 시간 경과에 따라 상이한 결과가 도출되었다.

• Korean Chemical Engineering Research
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• 제49권2호
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• pp.137-150
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• 2011

$CO_{2}$를 탄산염의 형태로 고정화하는 광물 탄산화 기술은 $CO_{2}$ 지중 저장의 대안 기술의 하나로 중소규모로 $CO_{2}$ 저장을 실현할 수 있는 기술로 여겨지고 있다. 이 연구에서는 광물 탄산화 기술의 전세계적인 연구 개발 동향을 파악하고, 특히 우리 나라의 지질 및 산업 여건을 고려할 때 $CO_{2}$ 광물 탄산화가 $CO_{2}$ 저감 대책이 될 수 있는지에 대한 기술적 및 경제적 타당성을 검토하였다. 그 결과 국내에서는 연간 1,200만톤 이상의 $CO_{2}$를 고정화할 수 있는 산업 부산물이 발생하고 있으며, 이를 광물탄산화에 이용한다면 $CO_{2}$ 광물탄산화는 유망한 $CO_{2}$ 저감 방안이 될 수 있을 것으로 기대된다. 이 기술의 경제성 증대를 위해서는 산업 부산물의 전처리, 금속 용출액 및 용출 방법, 고속 탄산화 기술 개발, 공정열의 이용 극대화, 생성된 탄산화물의 부가가치 향상 등의 분야에서 향후 추가적인 연구 개발이 필요할 것으로 판단된다.

• Corrosion Science and Technology
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• 제4권2호
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• pp.69-74
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• 2005

The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady state within about five hours after exposure. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2015년도 추계 학술논문 발표대회
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• pp.3-4
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• 2015

Environmental load reduction and sustainable development one of the study's research into the available material is discharged, remove the coarse aggregate and fine aggregate from waste concrete and utilizing the remaining cement fine powder as an alternative raw material for limestone is the main raw material of cement developing playback cement that was the purpose. Physical over existing research and chemical quality was confirmed was evaluated for durability by promoting carbonation test, research studies on the durability evaluation insignificant. As honipyul within the aggregate differential lung fine powder increases carbonation resistance performance've found that increased sharply and, S0 showed fairly similar to the OPC. Therefore, the development within the technology research to separate fine aggregate discharge fully differential and waste fine powder is determined to be the development and use of the playback durability of the cement with the carbonation levels corresponding to the OPC if made.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2005년도 춘계 학술발표회 논문집
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• pp.417-422
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• 2005

The appropriate ventilation system in vehicular tunnel should be the most economical solution with regard to both construction and maintenance. The damages on tunnel lining was affected by formula of ventilation system in long vehicular tunnel. In this study, carbonation, one of main experimental items in precision safety diagnosis, was analyzed by contouring damage area with ventilation system. Considerations of carbonation were also given to the design and maintenance which manage the long-term safety in tunnel.

• Earthquakes and Structures
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• 제20권2호
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• pp.215-224
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• 2021

The carbon dioxide present in the atmosphere is one of the main reasons for the corrosion of bridges, buildings, tunnels, and other reinforced concrete (RC) structures in most industrialized countries. With the growing use of fossil fuels in the world since the Industrial Revolution, the amount of carbon dioxide in urban and industrial areas of the world has grown significantly, which increases the chance of corrosion caused by carbonation. The process of corrosion leads to a change in mechanical properties of rebars and concrete, and consequently, detrimentally impacting load-bearing capacity and seismic behavior of RC structures. Neglecting this phenomenon can trigger misleading results in the form of underestimating the seismic performance metrics. Therefore, studying the carbonation corrosion influence on the seismic behavior of RC structures in urban and industrial areas is of great significance. In this study, a 2D modern RC moment frame is developed to study and assess the effect of carbonation corrosion, in 5-year intervals, for a 50 years lifetime under two different environmental conditions. This is achieved using the nonlinear static and incremental dynamic analysis (IDA) to evaluate the reinforcement corrosion effects. The reduction in the seismic capacity and performance of the reinforced concrete frame, as well as the collapse probability over the lifetime for different corrosion scenarios, is examined through the capacity curves obtained from nonlinear static analysis and the fragility curves obtained from IDA.

• 한국세라믹학회지
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• 제51권2호
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• pp.64-71
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• 2014

Accelerated carbonation is a technique that can be used as a CCS technology for $CO_2$ sequestration of approximately 5~20% in a stable solid through the precipitation of carbonate. An alkaline inorganic waste material such as ash, slag, and cement paste are generated from incinerators, accelerated carbonation offers the advantage of lower transport and processing costs at the same generation location of waste and $CO_2$. In this study, we evaluated an amount of $CO_2$ sequestration in various types of inorganic alkaline waste processed by means of accelerated carbonation. A quantitative evaluation of $CO_2$ real sequestration based on a TG/DTA analysis, the maximum 118.88 $g/kg_{-waste}$ of $CO_2$ in paper sludge fly ash, the maximum 134.46 $g/kg_{-waste}$ of $CO_2$ in municipal solid waste incinerator bottom ash, the maximum 9.72 $g/kg_{-waste}$ of $CO_2$ in industrial solid waste incinerator fly ash, and the maximum $18.19g/kg_{-waste}$ of $CO_2$ in waste cement paste.

• 한국세라믹학회지
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• 제53권4호
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• pp.429-434
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• 2016

Here, we introduce a means of utilizing waste oyster shells which were obtained from temporary storage near coastal workplaces as $CO_2$ adsorbents. The calcined CaO can be easily dissociated to $Ca^{2+}$ cation and $CO_3{^{2-}}$ anion by hydrolysis and gas-liquid carbonation reaction and converted to precipitated calcium carbonate (PCC) in algae-containing water. The calcium hydroxide and carbonation combination in algae-containing water significantly contributed to improving water quality which is very dependent on the addition amount of calcined powders.