• 제목/요약/키워드: carbon-reduction

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Solution Plasma Synthesis of BNC Nanocarbon for Oxygen Reduction Reaction

  • Lee, Seung-Hyo
    • Journal of the Korean institute of surface engineering
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    • v.51 no.5
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    • pp.332-336
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    • 2018
  • Alkaline oxygen electrocatalysis, targeting anion exchange membrane alkaline-based metal-air batteries has become a subject of intensive investigation because of its advantages compared to its acidic counterparts in reaction kinetics and materials stability. However, significant breakthroughs in the design and synthesis of efficient oxygen reduction catalysts from earth-abundant elements instead of precious metals in alkaline media still remain in high demand. One of the most inexpensive alternatives is carbonaceous materials, which have attracted extensive attention either as catalyst supports or as metal-free cathode catalysts for oxygen reduction. Also, carbon composite materials have been recognized as the most promising because of their reasonable balance between catalytic activity, durability, and cost. In particular, heteroatom (e.g., N, B, S or P) doping on carbon materials can tune the electronic and geometric properties of carbon, providing more active sites and enhancing the interaction between carbon structure and active sites. Here, we focused on boron and nitrogen doped nanocarbon composit (BNC nanocarbon) catalysts synthesized by a solution plasma process using the simple precursor of pyridine and boric acid without further annealing process. Additionally, guidance for rational design and synthesis of alkaline ORR catalysts with improved activity is also presented.

Effect of Electrode Materials and Applied Potential in Electrocatalytic Reduction of Carbon Dioxide by Carbon Monoxide Dehydrogenase (일산화탄소탈수소화효소를 이용한 이산화탄소의 전기화학적 환원에 미치는 전극재료와 전위의 영향)

  • Shin, Jun Won;Kim, You-Sung;Song, Ji-Eun;Lee, Sang-Hee;Lee, Sang-Phil;Lee, Ho-Jun;Lim, Mi-Ran;Shin, Woon-Sup
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.165-169
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    • 2008
  • The effect of reduction of carbon dioxide by CODH(Carbon Monoxide Dehydrogenase) was compared on glassy carbon and gold working electrodes. In case of gold electrode, the choice of the optimum applied potential is very important since $H_2$ evolution can be mixed with $CO_2$ reduction. On the other hand, efficient $CO_2$ reduction was observed up to -650 mV vs. NHE on glassy carbon in neutral solution due to the larger overpotential for $H_2$ evolution on glassy carbon surface than that on gold surface. The optimum potential for $CO_2$ reduction was found to be $-570{\sim}600\;mV$ vs. NHE. The current efficiency of $CO_2$ to CO decreased dramatically at more negative potential according to the activity of enzyme decrease and the hydrogen evolution.

System Dynamics Application for the Evaluation of Greenhouse Gases Reduction Policy (시스템다이내믹스 기법을 이용한 온실가스 감축정책 평가)

  • Jang, Namjung;Kim, Min-Kyong;Yang, Go-Su
    • Korean System Dynamics Review
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    • v.14 no.1
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    • pp.55-68
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    • 2013
  • It is necessary to evaluate the greenhouse gases (GHGs) reduction policy by central and regional governments to set up the suitable GHG emissions measures. Quantitative, qualitative and synthetic methods have been adopted by previous researches to estimate GHG reduction policy. However, these methods mostly focused on the results of the reduction policy, rather than understanding and fixing the integrated structures of GHG emissions. In this research, System Dynamics(SD) was applied to 1 million green homes program, self-carfree-day system and carbon point program. The results showed that SD analyses could be appliable for the estimation of GHG reduction policy by developing the feedback loops and dynamic simulation model. SD can be consider as a supplementary tool to estimate the GHG reduction policies through the recognition of the structure in complex real system.

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Environment R&D Incentives with Emission Banking and Borrowing in a Cournot Model (쿠르노 경쟁하의 배출권 이월 및 차입과 감축기술개발투자)

  • Jeong, Kyonghwa;Shim, Sunghee
    • Journal of Environmental Policy
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    • v.14 no.4
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    • pp.63-101
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    • 2015
  • Banking and borrowing under the ETS may affect the low carbon technology investment level. If the indirect implementation measures are allowed, firms can gradually adjust their carbon reduction costs between implementation periods based on their carbon reduction costs and emission price forecasts. This implies that banking and borrowing may reduce or increase the level of low carbon technology R&D investment. In an oligopoly market, the effects of the measures are quite different from the ones in a perfectly competitive market. This is because the indirect implementation measures can shift market competition in Cournot competition model. The effects of banking and borrowing on the carbon reduction R&D investments depend on emission reduction costs, marginal production costs, discount rate, initial free allocation, and the cost reduction effects of R&D investment.

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Heteroatom-doped carbon nanostructures as non-precious cathode catalysts for PEMFC (이종 원자 도핑 탄소 나노재료를 이용한 PEMFC Cathode용 촉매 합성 및 평가)

  • Jo, G.Y.;Shanmugam, S.
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.406-409
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    • 2012
  • Recently, enormous research efforts have been focused on the development of non-precious catalysts to replace Pt for electrocatalytic oxygen reduction reaction (ORR), and to reduce the cost of proton exchange membrane fuel cells (PEMFCs). In recent years, heteroatom (N, B, and P) doped carbon nanostructures have been received enormous importance as a non-precious electrode materials for oxygen reduction. Doping of foreign atom into carbon is able to modify electronic properties of carbon materials. In this study, nitrogen and boron doped carbon nanostructures were synthesized by using a facile and cost-effective thermal annealing route and prepared nanostructures were used as a non-precious electrocatalysts for the ORR in alkaline electrolyte. The nitrogen doped carbon nanocapsules (NCNCs) exhibited higher activity than that of a commercial Pt/C catalyst, excellent stability and resistance to methanol oxidation. The boron-doped carbon nanostructure (BC) prepared at $900^{\circ}C$ showed higher ORR activity than BCs prepared lower temperature (800, $700^{\circ}C$). The heteroatom doped carbon nanomaterials could be promising candidates as a metal-free catalysts for ORR in the PEMFCs.

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Environmental Impact Assessment for Development Projects Considering Carbon Sink and Sequestration(I) - Focused on a Solar Power Plant Development Project - (탄소흡수원을 고려한 개발사업 환경영향평가 방안(I) - 태양광발전소 건설사업 사례를 중심으로 -)

  • Hwang, Sang-Il;Park, Sun-Hwan
    • Journal of Environmental Impact Assessment
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    • v.19 no.6
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    • pp.625-631
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    • 2010
  • The objective of this work was to investigate how carbon sink and sequestration of vegetation and soil in the development project area can impact the land use plan, in addition to carbon emission capacity of the development project when we conduct environmental impact assessment. Especially, we did this work for a development project of solar power plant which would be constructed in forest area. Through this work, we found that 1) the amount of carbon sink and sequestration largely decreased due to reduction of the green area, 2) in terms of carbon sink and sequestration, conservation of natural green area is better than construction of newly vegetated area, 3) biochar application into soil can become an alternative for increase of carbon sink, and 4) even though a solar power production does hugely reduce carbon emissions and offset the carbon sink and sequestration capacity from the forest, it is necessary to consider the public value of the forest(reduction of heat island, habitat etc.) in siting for development area.

A Study on Improvement and Effect of Carbon Point Program for Residential Buildings in Daegu (대구광역시 주거 건축물의 이산화탄소 배출 감축을 위한 탄소포인트제의 효과 및 개선방향에 관한 연구)

  • Yeo, Myung-Kil;Jeon, Gyu-Yeob;Hong, Won-Hwa;Cho, Woong-Ho
    • Journal of the Korean housing association
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    • v.23 no.4
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    • pp.11-18
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    • 2012
  • The amount of energy consumption in the buildings is approximately 20% of domestic energy consumption. The Carbon Point Program have been published on reduction of greenhouse gas emission in buildings under the paradigm of 'Low Carbon Green Growth'. This study focuses on the effect of 'Carbon Point Program' for residential buildings in Daegu. The amount of electricity and waterwork consumption and information of households were investigated to analyse the effect of carbon point program. The samples are situated in Deagu and are apartment in Bukgu and Suseonggu. The $CO_2$ emission is analysed by factors of energy resource and household organization between before participating and after participating in Carbon Point Program. The participation type has a difference of voluntary participation in Suseonggu and passive participation in Bukgu. Based on this investigation, average amount of $CO_2$ emission was reduced from voluntary participation households but all of them did not. To promote the effect of Carbon Point Program, this study proposes that needing the plans to raise will and activity of reducing carbon and to help participation which have disadvantage against achieving reduction.

Effect of Black Charcoal and Activated Carbon for Reduction of Radon Radioactivity that Emitted from Building Materials (건축재료로부터 방출되는 라돈방사능 감소를 위한 흑탄과 활성탄 효과)

  • Cho, Yun-Min;Lee, Hwa-Hyung
    • Journal of the Korea Furniture Society
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    • v.22 no.1
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    • pp.13-17
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    • 2011
  • Recently, interest in indoor air quality is increasing. Especially, radon radioactivity among the indoor air is a well-known risk factor for lung cancer because of ionizing radiation in the form of ${\alpha}$-particles. This study was carried out to investigate effect of black charcoal and activated carbon for reduction of radon radiation that emitted from building materials. Black charcoal and activated carbon were used as a barrier which was against the infiltration of radon. The source of radon was gypsum board. Two types of charcoal barrier were powder- and board-type with 5 mm, 10 mm thickness respectively. The method for this determination is evaluated radon concentration in chamber. The measurements were performed with radon detector, SARAD3120. Results of this study are as following: Black charcoal and activated carbon confirmed the highly efficient barrier. Radon concentration was reduced from 72% to 85% as compared the control chamber. Radon reduction capability, however, was no difference as barrier's types. Results obtained in ventilation condition, radon concentration shows 5.93 pCi/L on average in the closed condition and shows 2.69 pCi/L in the opened condition.

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Revenue Neutral Introduction of Carbon Tax and Double-dividend Effect on the Korean Economy (우리나라의 조세중립적 탄소세 도입의 이중배당 효과)

  • Lim, Jong-Soo;Kim, Yong-Gun
    • Environmental and Resource Economics Review
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    • v.19 no.1
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    • pp.45-80
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    • 2010
  • A computable general equilibrium model has been used to analyze the likelihood of double-dividend effect in Korean economy. Revenue neutral introduction of carbon tax through the reduction in payroll tax and corporate income tax had been experimented in this regard. Double-dividend measured by income shows the existence of weak double-dividend in both cases, while double-dividend measured by consumption level could not be found in case of carbon tax with corporate income tax reduction. A notable result is in the employment measured double-dividend effect as the sizable strong double-dividend effect were found in the case of carbon tax with payroll tax reduction.

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Studies on the Current Carbon Black Industries (최근(最近) Carbon Black 산업(産業) 동향(動向) 고찰(考祭) (고무용(用) Carbon Black을 중심(中心)으로))

  • Hwang, Yoon-Tae;Lee, Chang-Se
    • Elastomers and Composites
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    • v.27 no.2
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    • pp.89-101
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    • 1992
  • This paper is concerned with analysis for market trend and technological tendency of rubber-use black among United state, Japan and Korea, Through this comparative analysis, the subjects with which domestic carbon black industry is confronted are : first, development of new grade carbon black such as high performance carbon black, Low rolling resistance carbon black and lower grit carbon black, Second, reduction of quality fluctuation, third, improvement of applied technology and fourth, strengthening the price competitiveness through process optimization and productivity increase.

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