• 한국표면공학회지
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• 제51권5호
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• pp.332-336
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• 2018

Alkaline oxygen electrocatalysis, targeting anion exchange membrane alkaline-based metal-air batteries has become a subject of intensive investigation because of its advantages compared to its acidic counterparts in reaction kinetics and materials stability. However, significant breakthroughs in the design and synthesis of efficient oxygen reduction catalysts from earth-abundant elements instead of precious metals in alkaline media still remain in high demand. One of the most inexpensive alternatives is carbonaceous materials, which have attracted extensive attention either as catalyst supports or as metal-free cathode catalysts for oxygen reduction. Also, carbon composite materials have been recognized as the most promising because of their reasonable balance between catalytic activity, durability, and cost. In particular, heteroatom (e.g., N, B, S or P) doping on carbon materials can tune the electronic and geometric properties of carbon, providing more active sites and enhancing the interaction between carbon structure and active sites. Here, we focused on boron and nitrogen doped nanocarbon composit (BNC nanocarbon) catalysts synthesized by a solution plasma process using the simple precursor of pyridine and boric acid without further annealing process. Additionally, guidance for rational design and synthesis of alkaline ORR catalysts with improved activity is also presented.

• 전기화학회지
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• 제11권3호
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• pp.165-169
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• 2008

CODH(Carbon Monoxide Dehydrogenase)에 의한 이산화탄소 환원에 있어서 작업전극을 유리탄소전극을 사용한 경우와 금전극을 사용한 경우를 비교하여 그 영향을 관찰하였다. 금전극을 사용한 경우에는 수소발생과 섞이기 때문에 전기분해의 전위를 잘 선택해야 효율적인 이산화탄소의 환원 반응을 관찰할 수 있는데 반하여, 유리탄소전극은 금전극보다 수소 환원에 대한 과전압이 크기 때문에 -650 mV vs. NHE 까지도 중성수용액에서 수소발생 없이, 효율적인 이산화탄소의 환원을 관찰할 수 있었다. CODH를 이용한 이산화탄소의 환원에는 가해주는 전기분해 전위가 큰 영향을 미침을 알 수 있었는데, $-570{\sim}600\;mV$ vs. NHE 근처가 가장 효율적임을 알 수 있었고 이보다 더 음의 전위를 걸어주었을 때는 효소활성의 감소 및 수소발생이 복합적으로 영향을 미쳐 일산화탄소 생성의 전류효율이 급격히 감소함을 알 수 있었다.

• 한국시스템다이내믹스연구
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• 제14권1호
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• pp.55-68
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• 2013

It is necessary to evaluate the greenhouse gases (GHGs) reduction policy by central and regional governments to set up the suitable GHG emissions measures. Quantitative, qualitative and synthetic methods have been adopted by previous researches to estimate GHG reduction policy. However, these methods mostly focused on the results of the reduction policy, rather than understanding and fixing the integrated structures of GHG emissions. In this research, System Dynamics(SD) was applied to 1 million green homes program, self-carfree-day system and carbon point program. The results showed that SD analyses could be appliable for the estimation of GHG reduction policy by developing the feedback loops and dynamic simulation model. SD can be consider as a supplementary tool to estimate the GHG reduction policies through the recognition of the structure in complex real system.

• 환경정책연구
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• 제14권4호
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• pp.63-101
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• 2015

배출권 이월 및 차입은 감축기술개발투자에 영향을 미칠 수 있다. 배출권거래제하에서 이월 및 차입이 허용되면 감축비용과 배출권 가격에 따라 배출권거래제 참여기업들은 현재의 감축을 미래로 또는 미래의 감축을 현재로 선택할 수 있기 때문에 배출권 이월 및 차입은 감축기술개발에 대한 대체재적인 역할을 한다. 따라서 배출권 이월 및 차입과 같은 간접감축이행수단을 허용하는 경우에는 직접감축이행수단인 감축기술개발투자에 영향을 미친다. 불완전경쟁시장에서 이러한 간접감축조치가 감축기술개발투자에 미치는 영향은 완전경쟁시장하에서와 달라질 수 있다. 왜냐하면 과점시장의 쿠르노 경쟁하에서 감축기술개발투자가 최종소비재시장의 균형에 영향을 미칠 수 있기 때문이다. 분석 결과, 배출권 이월 및 차입으로 인한 감축기술개발투자 유인 수준은 감축비용, 할인계수, 초기무상할당, 감축기술개발투자효과 등에 의존한다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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• pp.406-409
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• 2012

Recently, enormous research efforts have been focused on the development of non-precious catalysts to replace Pt for electrocatalytic oxygen reduction reaction (ORR), and to reduce the cost of proton exchange membrane fuel cells (PEMFCs). In recent years, heteroatom (N, B, and P) doped carbon nanostructures have been received enormous importance as a non-precious electrode materials for oxygen reduction. Doping of foreign atom into carbon is able to modify electronic properties of carbon materials. In this study, nitrogen and boron doped carbon nanostructures were synthesized by using a facile and cost-effective thermal annealing route and prepared nanostructures were used as a non-precious electrocatalysts for the ORR in alkaline electrolyte. The nitrogen doped carbon nanocapsules (NCNCs) exhibited higher activity than that of a commercial Pt/C catalyst, excellent stability and resistance to methanol oxidation. The boron-doped carbon nanostructure (BC) prepared at $900^{\circ}C$ showed higher ORR activity than BCs prepared lower temperature (800, $700^{\circ}C$). The heteroatom doped carbon nanomaterials could be promising candidates as a metal-free catalysts for ORR in the PEMFCs.

• 환경영향평가
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• 제19권6호
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• pp.625-631
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• 2010

The objective of this work was to investigate how carbon sink and sequestration of vegetation and soil in the development project area can impact the land use plan, in addition to carbon emission capacity of the development project when we conduct environmental impact assessment. Especially, we did this work for a development project of solar power plant which would be constructed in forest area. Through this work, we found that 1) the amount of carbon sink and sequestration largely decreased due to reduction of the green area, 2) in terms of carbon sink and sequestration, conservation of natural green area is better than construction of newly vegetated area, 3) biochar application into soil can become an alternative for increase of carbon sink, and 4) even though a solar power production does hugely reduce carbon emissions and offset the carbon sink and sequestration capacity from the forest, it is necessary to consider the public value of the forest(reduction of heat island, habitat etc.) in siting for development area.

• 한국주거학회논문집
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• 제23권4호
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• pp.11-18
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• 2012

The amount of energy consumption in the buildings is approximately 20% of domestic energy consumption. The Carbon Point Program have been published on reduction of greenhouse gas emission in buildings under the paradigm of 'Low Carbon Green Growth'. This study focuses on the effect of 'Carbon Point Program' for residential buildings in Daegu. The amount of electricity and waterwork consumption and information of households were investigated to analyse the effect of carbon point program. The samples are situated in Deagu and are apartment in Bukgu and Suseonggu. The $CO_2$ emission is analysed by factors of energy resource and household organization between before participating and after participating in Carbon Point Program. The participation type has a difference of voluntary participation in Suseonggu and passive participation in Bukgu. Based on this investigation, average amount of $CO_2$ emission was reduced from voluntary participation households but all of them did not. To promote the effect of Carbon Point Program, this study proposes that needing the plans to raise will and activity of reducing carbon and to help participation which have disadvantage against achieving reduction.

• 한국가구학회지
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• 제22권1호
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• pp.13-17
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• 2011

Recently, interest in indoor air quality is increasing. Especially, radon radioactivity among the indoor air is a well-known risk factor for lung cancer because of ionizing radiation in the form of ${\alpha}$-particles. This study was carried out to investigate effect of black charcoal and activated carbon for reduction of radon radiation that emitted from building materials. Black charcoal and activated carbon were used as a barrier which was against the infiltration of radon. The source of radon was gypsum board. Two types of charcoal barrier were powder- and board-type with 5 mm, 10 mm thickness respectively. The method for this determination is evaluated radon concentration in chamber. The measurements were performed with radon detector, SARAD3120. Results of this study are as following: Black charcoal and activated carbon confirmed the highly efficient barrier. Radon concentration was reduced from 72% to 85% as compared the control chamber. Radon reduction capability, however, was no difference as barrier's types. Results obtained in ventilation condition, radon concentration shows 5.93 pCi/L on average in the closed condition and shows 2.69 pCi/L in the opened condition.

• 자원ㆍ환경경제연구
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• 제19권1호
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• pp.45-80
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• 2010

본 연구는 우리나라의 기후변화 대응 정책 입안에 있어 조세중립적 세제개편을 통한 탄소세의 도입에 따른 이중배당가설이 성립하는지를 연산가능일반균형모형을 이용하여 검토해 보았다. 법인세율 감경과 법정복리비 감경을 통한 조세중립적 세제개편과 병행한 탄소세 도입을 실험하여 본 결과, 우리나라의 경우 소득의 척도로 이중배당 효과를 측정할 때, 두 경우 모두 약이중배당 효과가 발견되고 있다. 그러나 소비 척도로 측정한 이중배당 효과는 법인세 감경을 통한 조세중립적 탄소세 도입의 경우 이중배당 효과가 전혀 나타나지 않았으며, 고용으로 측정한 이중배당 효과는 법정복리비 감경을 통한 조세중립적 탄소세 도입을 할 경우 강이중배당 효과도 발견되었다.

• Elastomers and Composites
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• 제27권2호
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• pp.89-101
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• 1992

This paper is concerned with analysis for market trend and technological tendency of rubber-use black among United state, Japan and Korea, Through this comparative analysis, the subjects with which domestic carbon black industry is confronted are : first, development of new grade carbon black such as high performance carbon black, Low rolling resistance carbon black and lower grit carbon black, Second, reduction of quality fluctuation, third, improvement of applied technology and fourth, strengthening the price competitiveness through process optimization and productivity increase.