• Title/Summary/Keyword: carbon utilization

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Optimal Carbon Upcycling Technology Selection Method Considering Technology and Market (기술 및 시장을 고려한 최적 탄소자원화 기술 선정방법)

  • Ji Hyun Lee;Seong Jegarl;Jieun Jo
    • New & Renewable Energy
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    • v.19 no.1
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    • pp.41-52
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    • 2023
  • Various carbon upcycling technologies have been proposed and are under development to achieve Korea's carbon neutrality target. Many chemical reactions are under development through various chemical reaction pathways, and different technological maturity levels are shown for each country and company. In this situation, it is essential to establish investment decisions such as research funds and human resources allocation through technological and economic analysis for close commercialization technologies and basic technologies with low technology readiness levels (TRL). Therefore, in this study, the technology development priority for developing carbon upcycling items was selected according to the domestic Carbon Capture & Utilization (CCU) technology roadmap using the stakeholder selection tool released by EU CarbonNext. As a result of the analysis, the TRL level of Korea's major carbon upcycling technologies was analyzed to be lower than that of other carbon resource technologies, and it was considered desirable to invest in mineral carbonization technologies among various candidate technologies.

Physical and Mechanical Properties of The Lignin-based Carbon Nanofiber-reinforced Epoxy Composite (에폭시 강화 리그닌 기반 나노탄소섬유 복합재료의 특성)

  • Youe, Won-Jae;Lee, Soo-Min;Lee, Sung-Suk;Kim, Yong Sik
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.3
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    • pp.406-414
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    • 2016
  • The lignin-based carbon nanofiber reinforced epoxy composite has been prepared by immersing carbon nanofiber mat in epoxy resin solution in order to evaluate the physical and mechanical properties. The thermal and mechanical properties of the carbon nanofiber reinforced epoxy composite were analyzed using thermogravimetric analysis (TGA), differential scanning calorimeter (DSC) and tensile tester. It was found that the thermal properties of the carbon nanofiber reinforced epoxy composite improved, with its glass-transition temperature ($T_g$) increased from $90.7^{\circ}C$ ($T_g$ of epoxy resin itself) to $106.9^{\circ}C$. The tensile strengths of carbon nanofiber mats made from both lignin-g-PAN copolymer and PAN were 7.2 MPa and 9.4 MPa, respectively. The resulting tensile strength of lignin-based carbon nanofiber reinforced epoxy composite became 43.0 MPa, the six times higher than that of lignin-based carbon nanofiber mats. The carbon nanofibers were pulled out after the tensile test of the carbon nanofiber reinforced epoxy composite due to high tensile strength (478.8 MPa) of an individual carbon nanofiber itself as well as low interfacial adhesion between fibers and matrices, confirmed by the SEM analysis.

Synthesis of Multiwall Carbon Nanotube/Graphene Composite by Aerosol Process and Its Characterization for Supercapacitors (에어로졸 공정에 의한 Multiwall carbon nanotube/Graphene 복합체 제조 및 슈퍼커패시터 특성평가)

  • Jo, Eun Hee;Kim, Sun Kyung;Chang, Hankwon;Lee, Chong Min;Park, Su-Ryeon;Choi, Ji-hyuk;Jang, Hee Dong
    • Particle and aerosol research
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    • v.12 no.4
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    • pp.127-134
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    • 2016
  • A multiwall carbon nanotube (MWCNT)/graphene (GR) composite was synthesized for an enhanced supercapacitor. Aerosol spray pyrolysis (ASP) was employed to synthesize the MWCNT/GR composites using a colloidal mixture of MWCNT and graphene oxide (GO). The effect of the weight ratio of the MWCNT/GO on the particle properties including the morphology and layered structure were investigated. The morphology of MWCNT/GR composites was generally the shape of a crumpled paper ball, and the average composite size was about $5{\mu}m$. MWCNT were uniformly dispersed in GR sheets and the MWCNT not only increase the basal spacing but also bridge the defects for electron transfer between GR sheets. Thus, it was increasing electrolyte/electrode contact area and facilitating transportation of electrolyte ion and electron in the electrode. Electrochemical data demonstrate that the MWCNT/GR (weight ratio=0.1) composite possesses a specific capacitance of 192 F/g at 0.1 A/g and good rate capability (88% capacity retention at 4 A/g) using two-electrode testing system.

Experimental study on capture of carbon dioxide and production of sodium bicarbonate from sodium hydroxide

  • Shim, Jae-Goo;Lee, Dong Woog;Lee, Ji Hyun;Kwak, No-Sang
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.297-303
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    • 2016
  • Global warming due to greenhouse gases is an issue of great concern today. Fossil fuel power plants, especially coal-fired thermal power plants, are a major source of carbon dioxide emission. In this work, carbon capture and utilization using sodium hydroxide was studied experimentally. Application for flue gas of a coal-fired power plant is considered. Carbon dioxide, reacting with an aqueous solution of sodium hydroxide, could be converted to sodium bicarbonate ($NaHCO_3$). A bench-scale unit of a reactor system was designed for this experiment. The capture scale of the reactor system was 2 kg of carbon dioxide per day. The detailed operational condition could be determined. The purity of produced sodium bicarbonate was above 97% and the absorption rate of $CO_2$ was above 95% through the experiment using this reactor system. The results obtained in this experiment contain useful information for the construction and operation of a commercial-scale plant. Through this experiment, the possibility of carbon capture for coal power plants using sodium hydroxide could be confirmed.

Production of 1,2-Propanediol from Glycerol in Saccharomyces cerevisiae

  • Jung, Joon-Young;Yun, Hyun-Shik;Lee, Jin-Won;Oh, Min-Kyu
    • Journal of Microbiology and Biotechnology
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    • v.21 no.8
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    • pp.846-853
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    • 2011
  • Glycerol has become an attractive carbon source in the biotechnology industry owing to its low price and reduced state. However, glycerol is rarely used as a carbon source in Saccharomyces cerevisiae because of its low utilization rate. In this study, we used glycerol as a main carbon source in S. cerevisiae to produce 1,2-propanediol. Metabolically engineered S. cerevisiae strains with overexpression of glycerol dissimilation pathway genes, including glycerol kinase (GUT1), glycerol 3-phosphate dehydrogenase (GUT2), glycerol dehydrogenase (gdh), and a glycerol transporter gene (GUP1), showed increased glycerol utilization and growth rate. More significant improvement of glycerol utilization and growth rate was accomplished by introducing 1,2-propanediol pathway genes, mgs (methylglyoxal synthase) and gldA (glycerol dehydrogenase) from Escherichia coli. By engineering both glycerol dissimilation and 1,2-propanediol pathways, the glycerol utilization and growth rate were improved 141% and 77%, respectively, and a 2.19 g 1,2- propanediol/l titer was achieved in 1% (v/v) glycerolcontaining YEPD medium in engineered S. cerevisiae.

Characteristics of Bacterial Communities in Biological Filters of Full-Scale Drinking Water Treatment Plants

  • Choi, Yonkyu;Cha, Yeongseop;Kim, Bogsoon
    • Journal of Microbiology and Biotechnology
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    • v.29 no.1
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    • pp.91-104
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    • 2019
  • The taxonomic and functional characteristics of bacterial communities in the pre-chlorinated rapid filters and ozonated biological activated carbon (BAC) filters were compared using Illumina MiSeq sequencing of the 16S rRNA gene and community-level physiological profiling (CLPP) based on sole-carbon-source utilization patterns. Both the rapid filters and BAC filters were dominated by Rhizobiales within ${\alpha}-proteobacteria$, but other abundant orders and genera were significantly different in both types of filter. Firmicutes were abundant only in the intermediate chlorinated rapid filter, while Acidobacteria were abundant only in the BAC filters. Bacterial communities in the rapid filter showed high utilization of carbohydrates, while those in the BAC filters showed high utilization of polymers and carboxylic acids. These different characteristics of the bacterial communities could be related to the different substrates in the influents, filling materials, and residual disinfectants. Chlorination and ozonation inactivated the existing bacteria in the influent and formed different bacterial communities, which could be resistant to the oxidants and effectively utilize different substrates produced by the oxidant, including Phreatobacter in the rapid filters and Hyphomicrobium in the BAC filters. Bradyrhizobium and Leptothrix, which could utilize compounds adsorbed on the GAC, were abundant in the BAC filters. Ozonation increased taxonomic diversity but decreased functional diversity of the bacterial communities in the BAC filters. This study provides some new insights into the effects of oxidation processes and filling materials on the bacterial community structure in the biological filters of drinking water treatment plants.

Current status of CCU technology development (CCU 기술개발 국내외 기술동향)

  • Sim, Jae-Gu
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.4
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    • pp.517-523
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    • 2016
  • South Korea is the 8th biggest greenhouse gas emitter in the world due to its phenomenal economic growth based on manufacturing, and it is ranked first among OECD members for the rate of increase in emissions. Thus, the Korea government has voluntarily presented a reduction target and demonstrated global leadership. For the reduction of nation's GHG emission, importance of CCU(Carbon Capture and Utilization) along with CCS(Carbon Capture and Storage) technology development is increased. CCU technology is $CO_2$ utilization technology for the usage of $CO_2$ from flue gas and it can create a new economic value while reducing $CO_2$ emission. Therefore, with continued technology development, the number of application of CCU technology is increasing globally.

Study on the check list composition at Sustainable building strategies and Design methods of Long-life housing (장수명 공동주택의 친환경 요소기술 및 계획기법 체크리스트 구성에 관한 연구)

  • Han, Nam-Soo;Lee, Young
    • Journal of the Korean housing association
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    • v.21 no.1
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    • pp.103-112
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    • 2010
  • This Study is about the check-List composition for 'Low carbon green growth' of Long-life housing. That utilization for required the check-list composition at Sustainable building strategies and Design methods. That for long life housing, sustainable building strategies part of building construction and interior, the proper foundation for legislative system, maintenance methods with in building life cycle, sustainable and green architecture capability realization prepare for connection plan with 'Low carbon-green growth'. Extracting from elements of Architectural planing answer to basic concept of Low carbon-green growth and aimed at Low carbon scheme for energy saving, green growth scheme for environmental conservation as to each application purpose reconstitute by classify Check-list category about elements of Architectural planing. Through this architectural research deduce elements of architectural planing that can be research utilization with in Check-list composition.

Characterization of the Effects of Relative Humidity and Bed-depth on $CO_2$ Capture for Maximizing the Utilization Rate of Soda Lime Sorbent

  • Cho, Il-Hoon;Park, Guen-Il;Kim, Joon-Hyung;Hwang, Taek-Sung;Lee, Mi-Kyoung
    • Carbon letters
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    • v.2 no.2
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    • pp.113-119
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    • 2001
  • The advanced method for $CO_2$capture is currently one of the most important environmental issues in worldwide and it is therefore necessary to have available technologies, which minimize the discharge of $CO_2$ including Carbon-14 from nuclear facilities into the atmosphere. A key aspect of this work is to provide the technically principal data required to improve a $CO_2$ removal system for the utilization of regenerative sorbent use, specifically include suggestions regarding its modified column design (parallel dual-bed assembly), stop-restart operation and the economic feasibility of sorbent use. The removal performance of soda lime and the effects of relative humidity (RH) and packing bed-depth (BD) on $CO_2$ removal were investigated. In a single-bed, it revealed that the utilization of soda lime for $CO_2$ removal at line velocity of 13 cm/sec and bed depth of 12 cm increased with the increased relative humidity up to 85%. However, in the parallel dual-bed assembly applied with the stop-restart operation, a maximum utilization rate of soda lime for $CO_2$ removal was obtained even at 55% of RH and 8 cm of BD, specifically the utilization rate of soda lime by using this $CO_2$ removal assembly was about two-fold superior to that in a single-bed.

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Determination of Carbon Source Utilization of Bacillus and Pythium Species by Biolog$^{(R)}$ Microplate Assay

  • Chun, Se-Chul;R.W. Schneider;Chung, Ill-Min
    • Journal of Microbiology
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    • v.41 no.3
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    • pp.252-258
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    • 2003
  • The carbon utilizations of Bacillus species and Pythium species were investigated by using a Biolog$^{(R)}$ microplate assay to determine if there are differences in the carbon utilizations of selected strains of these species. It may be possible to afford a competitive advantage to bacterial biological control agents by providing them with a substrate that they can readily use as a carbon source, for example, in a seed coating formulation. Microplates, identified as SFP, SFN and YT were used to identify spore-forming bacteria, nonspore-forming bacteria, and yeast, respectively. Bacterial and mycelial suspensions were adjusted to turbidities of 0.10 to 0.11 at 600 nm. One hundred microliters of each of the bacterial and mycelial suspension were inoculated into each well of each of the three types of microplates. L-arabinose, D-galactose, D-melezitose and D-melibiose of the 147 carbohydrates tested were found to be utilized only by bacteria, and not by Pythium species, by Biolog$^{(R)}$ microplate assay, and this was confirmed by traditional shake flask culture. Thus, it indicated that the Biolog$^{(R)}$ microplate assay could be readily used to search for specific carbon sources that could be utilized to increase the abilities of bacterial biological control agents to adapt to contrived environments.