• Title/Summary/Keyword: carbon structures

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Fabrication of Photo Sensitive Graphene Transistor Using Quantum Dot Coated Nano-Porous Graphene

  • ;Lee, Jae-Hyeon;Choe, Sun-Hyeong;Im, Se-Yun;Lee, Jong-Un;Bae, Yun-Gyeong;Hwang, Jong-Seung;Hwang, Seong-U;Hwang, Dong-Mok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.658-658
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    • 2013
  • Graphene is an attractive material for various device applications due to great electrical properties and chemical properties. However, lack of band gap is significant hurdle of graphene for future electrical device applications. In the past few years, several methods have been attempted to open and tune a band gap of graphene. For example, researchers try to fabricate graphene nanoribbon (GNR) using various templates or unzip the carbon nanotubes itself. However, these methods generate small driving currents or transconductances because of the large amount of scattering source at edge of GNRs. At 2009, Bai et al. introduced graphene nanomesh (GNM) structures which can open the band gap of large area graphene at room temperature with high current. However, this method is complex and only small area is possible. For practical applications, it needs more simple and large scale process. Herein, we introduce a photosensitive graphene device fabrication using CdSe QD coated nano-porous graphene (NPG). In our experiment, NPG was fabricated by thin film anodic aluminum oxide (AAO) film as an etching mask. First of all, we transfer the AAO on the graphene. And then, we etch the graphene using O2 reactive ion etching (RIE). Finally, we fabricate graphene device thorough photolithography process. We can control the length of NPG neckwidth from AAO pore widening time and RIE etching time. And we can increase size of NPG as large as 2 $cm^2$. Thin CdSe QD layer was deposited by spin coatingprocess. We carried out NPG structure by using field emission scanning electron microscopy (FE-SEM). And device measurements were done by Keithley 4200 SCS with 532 nm laser beam (5 mW) irradiation.

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The Effect of Micro-Pore Configuration on the Flow and Thermal Fields of Supercritical CO2

  • Choi, Hang-Seok;Park, Hoon-Chae;Choi, Yeon-Seok
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.83-88
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    • 2012
  • Currently, the technology of $CO_2$ capture and storage (CCS) has become the main issue for climate change and global warming. Among CCS technologies, the prediction of $CO_2$ behavior underground is very critical for $CO_2$ storage design, especially for its safety. Hence, the purpose of this paper is to model and simulate $CO_2$ flow and its heat transfer characteristics in a storage site, for more accurate evaluation of the safety for $CO_2$ storage process. In the present study, as part of the storage design, a micro pore-scale model was developed to mimic real porous structure, and computational fluid dynamics was applied to calculate the $CO_2$ flow and thermal fields in the micro pore-scale porous structure. Three different configurations of 3-dimensional (3D) micro-pore structures were developed, and compared. In particular, the technique of assigning random pore size in 3D porous media was considered. For the computation, physical conditions such as temperature and pressure were set up, equivalent to the underground condition at which the $CO_2$ fluid was injected. From the results, the characteristics of the flow and thermal fields of $CO_2$ were scrutinized, and the influence of the configuration of the micro-pore structure on the flow and scalar transport was investigated.

Static and Fatigue Behavior Characteristics of Reinforced Concrete Beams Strengthened with CFRP Plate (CFRP Plate로 보강된 철근콘크리트 보의 정적 및 피로 거동 특성)

  • Kim, Kwang-Soo;Kim, Jin-Yul;Kim, Sung-Hu;Park, Sun-Kyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.4
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    • pp.141-148
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    • 2008
  • In the recent construction industry, Carbon Fiber Reinforced Polymers(CFRPs) have been highly considered as innovative strengthening materials for civil structures due to their superior material properties. This paper is to offer design data and strengthening efficiency of reinforced concrete beams strengthened with CFRP Plate. Static tests were carried out to evaluate failure modes and strengthening capacity. Displacements and strains of steel and CFRP plates were obtained and analyzed through a series of fatigue tests. Also, Those evaluated the energy dissipation. Results of the tests showed increase in strengthening ratios caused debonding failure at the end of beams. For the beams wrapped with CFRP sheets around the end of the plates, debonding failure mode that was induced from flexural cracks was indicated. Through the fatigue tests, it was observed that displacements, strains of steel and CFRP plates converged into certain values. It is also proved that the beams strengthened with CFRP plates are able to resist fatigue loading under serviceability.

Probabilistic Estimation of Service Life of Box Culvert for Power Transmission Considering Carbonation and Crack Effect (탄산화와 균열을 고려한 전력구 콘크리트 구조물의 확률론적 수명 예측)

  • Woo, Sang-Kyun;Lee, Yun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.6
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    • pp.30-40
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    • 2014
  • The demand of underground structure such as box culvert for electric power transmission is increasing more and more, and the service life extension of these structures is very important. Recent observations in field and experimental evidences show that even steel in concrete can be corroded by carbonation reaction of cover concrete. Carbonation-induced corrosion in concrete may often occur in a high carbon dioxide environment. In this study, the risk of carbonation of box culverts in our nation was evaluated by measuring the carbonation rate and concrete cover depth in field. Then, the service life due to carbonation at the cover depth was calculated by in situ information and the Monte Carlo simulation in a probabilistic way. Additionally, the accelerated carbonation test for the cracked beam specimen was executed and the crack effect owing to the carbonation process on the service life of box culvert was numerically investigated via Monte Carlo simulation based on the experimental results.

Synthesis and Antimicrobial Activity of Some New 1-Alkyl-2-alkylthio-1,2,4-triazolobenzimidazole Derivatives

  • Mohamed, Bahaa Gamal;Hussein, Mostafa Ahmed;Abdel-Alim, Abdel-Alim Mohamed;Hashem, Mohammed
    • Archives of Pharmacal Research
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    • v.29 no.1
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    • pp.26-33
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    • 2006
  • Some new derivatives of 1,2,4-triazolo[2,3-a]benzimidazoles were synthesized through the reaction of 1,2-diaminobenzimidazole with carbon disulfide. The resulting 1,2,4-triazolo-[2,3a]benzimidazole-2-thione intermediate was reacted with one equivalent of alkyl halides to give the corresponding 2-alkylthio derivatives, which were further alkylated through the reaction with another one equivalent of different alkyl halides to afford the target compounds; 1-alkyl-2alkylthio-1,2,4-traizolo[2,3-a]benzimidazoles. On the other hand, the 1,2-disubstituted derivatives with two identical alkyl substituents were prepared by the reaction of 1,2,4-triazolo[2,3-a]benzimidazole-2-thione with two equivalents of the alkyl halides. The structures of the new compounds were assigned by spectral and elemental methods of analyses. The synthesized compounds were tested for their antibacterial and antifungal activities. Most of the tested compounds proved comparable results with those of ampicillin and fluconazole reference drugs. The study indicated that, the antibacterial as well as the antifungal activities of the test compounds were improved with increase in the bulkiness of the introduced alkyl groups. Also, some active antibacterial compounds were tested for their antimycobacterial activity. All the test compounds showed equipotent antitubercular activity as that of INH as a reference drug.

Bond-Slip Model of Interface between CFRP Sheets and Concrete Beams Strengthened with CFRP (탄소섬유시트로 보강된 콘크리트보의 경계면 부착-슬립모델)

  • Kim, Sung-Bae;Kim, Jang-Ho Tay;Nam, Jin-Won;Kang, Suk-Hwa;Byun, Keun-Joo
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.477-486
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    • 2008
  • External bonding of carbon fiber reinforced plastic sheets has recently emerged as a popular method for strengthening reinforced concrete structures. The behavior of CFRP-strengthened RC structure is often controlled by the behavior of the interface between CFRP sheets and concrete. In this study, a review of models on bond strength, bond-slip, and interfacial stresses has been first carried out. Then a new bond-slip model is proposed. The proposed bond-slip model has bilinear ascending regions and exponential descending region derived from modifications mode on the conventional bilinear bond-slip model. The comparison of the results with those of existing experiment researches on bond-slip models indicate good agreements.

An Experimental Study on Time-Dependant Behavior of RC Beams Strengthened with FRP (FRP가 외부부착된 철근 콘크리트보의 시간의존거동에 관한 실험적 연구)

  • Kim, Sung-Hu;Kim, Jin-Yul;Kim, Kwang-Soo;Han, Kyoung-Bong;Park, Sun-Kyu;Song, Seul-Ki
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.41-44
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    • 2008
  • Fiber Reinforced Polymers (FRPs) have recently been highly used for repairing and strengthening civil structures due to their superior material properties. By using FRPs, external bond method is the most used method in the construction industry. Although many researches on reinforced concrete externally strengthened with FRPs have been conducted, time-dependant behaviors of the beams have not been investigated yet. This paper documents a series of beam experiments that were carried out to evaluate time-dependant behavior. Three RC beams were built and the parameters considered in this experiment were types of FRPs. Through these experiments, it was proved that the beam strengthened with CFRP was more effective than that with GFRP in terms of time-dependant behavior.

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Strengthening of Cutouts in Existing One-Way Spanning R. C. Flat Slabs Using CFRP Sheets

  • Shehab, Hamdy K.;Eisa, Ahmed S.;El-Awady, Kareem A.
    • International Journal of Concrete Structures and Materials
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    • v.11 no.2
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    • pp.327-341
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    • 2017
  • Openings in slabs are usually required for many different applications such as aeriation ducts and air conditioning. Opening in concrete slabs due to cutouts significantly decrease the member stiffness. There are different techniques to strengthen slabs with opening cutouts. This study presents experimental and numerical investigations on the use of Carbon Fiber Reinforced Polymers (CFRP) as strengthening material to strengthen and restore the load carrying capacity of R.C. slabs after having cutout in the hogging moment region. The experimental program consisted of testing five (oneway spanning R.C. flat slabs) with overhang. All slabs were prismatic, rectangular in cross-section and nominally 2000 mm long, 1000 mm width, and 100 mm thickness with a clear span (distance between supports) of 1200 mm and the overhang length is 700 mm. All slabs were loaded up to 30 kN (45% of ultimate load for reference slab, before yielding of the longitudinal reinforcement), then the load was kept constant during cutting concrete and steel bars (producing cut out). After that operation, slabs were loaded till failure. An analytical study using finite element analysis (FEA) is performed using the commercial software ANSYS. The FEA has been validated and calibrated using the experimental results. The FE model was found to be in a good agreement with the experimental results. The investigated key parameters were slab aspect ratio for the opening ratios of [1:1, 2:1], CFRP layers and the laminates widths, positions for cutouts and the CFRP configurations around cutouts.

Hydration and Electrical Resistance of Cement Composites Containing MWCNTs (MWCNT가 첨가된 시멘트복합체의 수화 및 전기저항 특성)

  • Lee, Gun-Cheol;Kim, Young-Min
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.1
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    • pp.11-18
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    • 2020
  • Carbon nanotubes are used in various industries with their excellent mechanical properties and electrical conductivity. In the construction industry, research is being conducted to give self-sensing capabilities to structures, but the results of experiments vary among researchers, and the analysis is insufficient. Therefore, in this study, the hydration and electrical properties of MWCNT-added cement pastes were measured. The electrical resistance values of hydration heat, porosity, Rietveld quantitative analysis, compressive strength, and distance were measured.. The heat resistance, porosity, Rietvelt quantitative analysis, compressive strength and distance were measured according to electrical resistance. Experimental results showed that the heat of hydration decreased with increasing MWCNT. XRD Rietveld quantitative analysis showed that there was no significant difference in the amount of hydration products with increasing addition rate of MWCNT. As a result of SEM analysis, the MWCNT is agglomerated by van der Waals forces, and this area is considered to be caused by voids and weak areas. The electrical resistance value decreases as the addition rate is increased, and thus may play a role for magnetic sensing in the future.

Tax Exemption Grant Proposal to Promote Green Remodeling Project Implementation (그린리모델링 사업시행유도를 위한 조세혜택 부여 방안)

  • Jung, Seoyoung;Yu, Jungho
    • Korean Journal of Construction Engineering and Management
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    • v.17 no.4
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    • pp.66-75
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    • 2016
  • Korean Government is implementing green remodeling projects on existing buildings and structures in a way of promoting low carbon green growth. However, the current regulations and systems do not clearly define the scopes and contents of the green remodeling. Also, the lack of the inducement measure is another reason of the low engagement of the private enterprises to the green remodeling business. Therefore, this study proposes a tax exemption plan to promote green remodeling business implementation, with the consideration on practical applicability. And the proposed plan was applied to the green remodeling pilot project case in2 014 and the effect was quantitatively analyzed. The result is expected to be used as a base data to improve the tax exemption benefit system to invigorate green remodeling later.