• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.4
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• pp.111-118
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• 2010

Reinforced steel corrosion due to concrete carbonation is one of main factors on the durability of RC structure. The carbonation velocity have an effect on carbon dioxide density, concrete quality and structural shape. Specially, these problems have increased in urban area. This study investigates the carbonation status of the bridges and quantifies the effect of carbonation based on various domestic field data. The failure probability of durability is evaluated on the basis of reliability concept. According to experimental results of the carbonation depth, the carbonation depth increased with structural age and carbonation velocity decreased with high strength of concrete. In most cases, the failure probability of durability by carbonation was more than 10%. Also, The results requires the minimum cover thickness of 70-80mm for target safety index(${\beta}$=1.3) proposed by Korean concrete specification.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.3
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• pp.84-92
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• 2008

This study is to investigate the flexural performance of Near Surface Mounted (NSM) strengthening method using Fiber reinforced Polymer (FRP) materials to concrete structures. For this study, the inverse-shaped trapezoid CFRP composite material which has been registered as New Excellent Technology (NET) 351 was adopted to the concrete structure. In this study, two types of the CFRP types were considered; Type A ($15{\times}13{\times}6mm$) and Type B ($4{\times}3{\times}10mm$) with different strengthening ratio. In the result of the test, it was proved that NSM strengthened specimens had more flexural performance of 20-100% than that of the unstrengthened specimen. With this test result, the structural efficiency was investigated based on the coefficient of ductility and coefficient of crack resistance.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.4
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• pp.108-113
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• 2018

Researches on strengthening and rehabilitation methods are being widely conducted due to the deterioration of existing concrete structures. Use of externally bonded Carbon Fiber Reinforced Polymers (CFRP) strips for the rehabilitation is a cost-effective and time-saving method. Generally, the CFRP layout for the shear strengthening was a uni-directional layout. Many researches have focused on the variables of the uni-directional CFRP layout such as the amount of material, angle, and spacing. Pilot tests indicated that the effective confinement of the concrete member can be provided with the bi-directional CFRP layout than the uni-directional layout. Therefore, the test was carried out after the uni- and bi-directional strengthening work using the same amount of CFRP material. CFRP anchors were installed to prevent unexpected premature CFRP delamination failure before reaching CFRP fracture strain. The effectiveness of the CFRP anchor and bi-directional CFRP layout for shear strengthening was verified based on the principal tensile strain contours.

• Korean Chemical Engineering Research
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• v.50 no.1
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• pp.41-49
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• 2012

This study was aimed at the development of catalysts for the direct methanol synthesis by partial oxidation of methane. Mo-Bi-V-Al mixed oxide catalysts were prepared and characterized and used in the direct methanol synthesis reaction. The catalysts prepared by the sol-gel method had much larger surface areas than those prepared by the co-precipitation method. The larger the surface area was, the less the methanol selectivity was. The catalysts having larger surface area facilitate the complete oxidation of methane, decreasing the selectivity of methanol. The catalysts prepared by the sol-gel method showed higher methanol selectivity of 13% at $20^{\circ}C$ lower temperature than those prepared by the co-precipitation method. Through XRD analysis, it was revealed that the structures of the catalysts prepared by the two methods were different. In the reaction, methanol selectivity increased and carbon dioxide selectivity decreased with pressure due to the suppression of complete oxidation reaction at a high pressure.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.4
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• pp.266-273
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• 2008

Natural gas hydrates are ice-like solid substances, which are composed of water and natural gas, mainly methane. They have three kinds of crystal structures of five polyhedra formed by hydrogen-bonded water molecules, and are stable at high pressures and low temperatures. They contain large amounts of organic carbon and widely occur in deep oceans and permafrost regions. Therefore, they are expected as a potential energy resource in the future. Especially, $1m^3$ natural gas hydrate contains up to $172Nm^3$ of methane gas, de pending on the pressure and temperature of production. Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming natural gas hydrate were numerically obtained in pure water and single electrolyte solution containing 3 wt% NaCl. The results show that the predictions match the previous experimental values very well, and it was found that NaCl acts as an inhibitor. Also, help gases such that ethane, propane, i-butane, and n-butane reduce the hydrate formation pressure at the same temperature.

• Journal of Power System Engineering
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• v.17 no.5
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• pp.78-85
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• 2013

A high thermal conductivity material, namely graphene is treated by planetary ball milling machine to transport the heat by increasing the temperature. Experiments were performed to assess the heat transfer enhancement benefits of coating the bottom wall of copper substrate with graphene. It is well known that the graphene is unable to disperse into base fluid without any treatment, which is due to the several reasons such as attachment of hydrophobic surface, agglomeration and impurity. To further improve the dispersibility and thermal characteristics, planetary ball milling approach is used to grind the raw samples at optimized condition. The results are examined by transmission electron microscopy, x-ray diffraction, Raman spectrometer, UV-spectrometer, thermal conductivity and thermal imager. Thermal conductivity measurements of structures are taken to support the explanation of heat transfer properties of different samples. As a result, it is found that the planetary ball milling approach is effective for improvement of both the dispersion and heat carriers of carbon based material. Indeed, the heat transfer of the ground graphene coated substrate was higher than that of the copper substrate with raw graphene.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.232-238
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• 1990

To study the biological roles of Zn, we investigated simple model systems of $Zn^{++}, coordinated with OH_2 or NH_3,$ or with O=C- in peptide. The geometrical structures and net atomic charges were calculated by the ab initio HF-SCF theory using double zeta basis sets. The ligands of O-H, N-H, and O=C- are very polar due to $Zn^{++}$. Therefore, the carbon atom in peptide becomes so electrophilic that it can be easily attacked by other nucleophiles. In addition, to understand how $Zn^{++}$ is coordinated with ligands in enzyme, a molecular mechanics method is applied to the system of the enzyme of carboxypeptidase A (CPA) with the substrate of glycyltyrosine. From our results, it appears that the Zn ion is coordinated not only by four ligands in enzyme and substrate but also by one water molecule.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.658-658
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• 2013

Graphene is an attractive material for various device applications due to great electrical properties and chemical properties. However, lack of band gap is significant hurdle of graphene for future electrical device applications. In the past few years, several methods have been attempted to open and tune a band gap of graphene. For example, researchers try to fabricate graphene nanoribbon (GNR) using various templates or unzip the carbon nanotubes itself. However, these methods generate small driving currents or transconductances because of the large amount of scattering source at edge of GNRs. At 2009, Bai et al. introduced graphene nanomesh (GNM) structures which can open the band gap of large area graphene at room temperature with high current. However, this method is complex and only small area is possible. For practical applications, it needs more simple and large scale process. Herein, we introduce a photosensitive graphene device fabrication using CdSe QD coated nano-porous graphene (NPG). In our experiment, NPG was fabricated by thin film anodic aluminum oxide (AAO) film as an etching mask. First of all, we transfer the AAO on the graphene. And then, we etch the graphene using O2 reactive ion etching (RIE). Finally, we fabricate graphene device thorough photolithography process. We can control the length of NPG neckwidth from AAO pore widening time and RIE etching time. And we can increase size of NPG as large as 2 $cm^2$. Thin CdSe QD layer was deposited by spin coatingprocess. We carried out NPG structure by using field emission scanning electron microscopy (FE-SEM). And device measurements were done by Keithley 4200 SCS with 532 nm laser beam (5 mW) irradiation.

• Environmental Engineering Research
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• v.17 no.2
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• pp.83-88
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• 2012

Currently, the technology of $CO_2$ capture and storage (CCS) has become the main issue for climate change and global warming. Among CCS technologies, the prediction of $CO_2$ behavior underground is very critical for $CO_2$ storage design, especially for its safety. Hence, the purpose of this paper is to model and simulate $CO_2$ flow and its heat transfer characteristics in a storage site, for more accurate evaluation of the safety for $CO_2$ storage process. In the present study, as part of the storage design, a micro pore-scale model was developed to mimic real porous structure, and computational fluid dynamics was applied to calculate the $CO_2$ flow and thermal fields in the micro pore-scale porous structure. Three different configurations of 3-dimensional (3D) micro-pore structures were developed, and compared. In particular, the technique of assigning random pore size in 3D porous media was considered. For the computation, physical conditions such as temperature and pressure were set up, equivalent to the underground condition at which the $CO_2$ fluid was injected. From the results, the characteristics of the flow and thermal fields of $CO_2$ were scrutinized, and the influence of the configuration of the micro-pore structure on the flow and scalar transport was investigated.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.4
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• pp.141-148
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• 2008

In the recent construction industry, Carbon Fiber Reinforced Polymers(CFRPs) have been highly considered as innovative strengthening materials for civil structures due to their superior material properties. This paper is to offer design data and strengthening efficiency of reinforced concrete beams strengthened with CFRP Plate. Static tests were carried out to evaluate failure modes and strengthening capacity. Displacements and strains of steel and CFRP plates were obtained and analyzed through a series of fatigue tests. Also, Those evaluated the energy dissipation. Results of the tests showed increase in strengthening ratios caused debonding failure at the end of beams. For the beams wrapped with CFRP sheets around the end of the plates, debonding failure mode that was induced from flexural cracks was indicated. Through the fatigue tests, it was observed that displacements, strains of steel and CFRP plates converged into certain values. It is also proved that the beams strengthened with CFRP plates are able to resist fatigue loading under serviceability.