• 공업화학
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• 제27권6호
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• pp.590-598
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• 2016

본 연구는 흡착제로 야자각계 수증기 활성화 입상 활성탄을 사용하여 Acid Black 1 수용액에서의 흡착 거동과 동역학적, 열역학적 파라미터에 대해 회분식 반응을 통해 조사하였다. 흡착변수로는 pH, 초기농도, 접촉시간, 온도를 사용하였다. pH에 대한 영향을 조사하기 위해 pHpzc 값을 분석한 뒤 pH 3-11 범위에서 제거율을 조사하였다. 흡착평형자료로부터 Langmuir, Freundlich, Temkin, Dubinin-Radushkevich 등온 흡착식에 대한 적합성을 평가하였다. 흡착공정에 대한 동역학적 해석을 통해 유사 1차반응식과 유사 2차반응식에 대한 흡착반응의 일치도를 평가하였다. 열역학적 해석을 통해 엔탈피 변화 값과 활성화에너지 값을 조사하여 이를 통해 흡착공정이 흡열반응인지를 확인하였으며, 엔트로피 변화 값과 자유에너지 값을 통해 흡착공정의 자발성을 확인하였다.

• Smart Structures and Systems
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• 제22권5호
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• pp.527-546
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• 2018

This article presents an analysis into the nonlinear forced vibration of a micro cylindrical shell reinforced by carbon nanotubes (CNTs) with considering agglomeration effects. The structure is subjected to magnetic field and transverse harmonic mechanical load. Mindlin theory is employed to model the structure and the strain gradient theory (SGT) is also used to capture the size effect. Mori-Tanaka approach is used to estimate the equivalent material properties of the nanocomposite cylindrical shell and consider the CNTs agglomeration effect. The motion equations are derived using Hamilton's principle and the differential quadrature method (DQM) is employed to solve them for obtaining nonlinear frequency response of the cylindrical shells. The effect of different parameters including magnetic field, CNTs volume percent and agglomeration effect, boundary conditions, size effect and length to thickness ratio on the nonlinear forced vibrational characteristic of the of the system is studied. Numerical results indicate that by enhancing the CNTs volume percent, the amplitude of system decreases while considering the CNTs agglomeration effect has an inverse effect.

• Structural Engineering and Mechanics
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• 제62권5호
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• pp.551-565
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• 2017

Based on the strain gradient theory (SGT), vibration analysis of an embedded micro cylindrical shell reinforced with agglomerated carbon nanotubes (CNTs) is investigated. The elastic medium is simulated by the orthotropic Pasternak foundation. The structure is subjected to magnetic field in the axial direction. For obtaining the equivalent material properties of structure and considering agglomeration effects, the Mori-Tanaka model is applied. The motion equations are derived on the basis of Mindlin cylindrical shell theory, energy method and Hamilton's principal. Differential quadrature method (DQM) is proposed to evaluate the frequency of system for different boundary conditions. The effects of different parameters such as CNTs volume percent, agglomeration of CNTs, elastic medium, magnetic field, boundary conditions, length to radius ratio and small scale parameter are shown on the frequency of the structure. The results indicate that the effect of CNTs agglomeration plays an important role in the frequency of system so that considering agglomeration leads to lower frequency. Furthermore, the frequency of structure increases with enhancing the small scale parameter.

• Steel and Composite Structures
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• 제52권4호
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• pp.487-499
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• 2024

The primary objective of this study is to analyze the free vibration behavior of a sandwich cylindrical shell with a defective core and wavy carbon nanotube (CNT)-enhanced face sheets, utilizing the three-dimensional theory of elasticity. The intricate equations of motion for the structure are solved semi-analytically using the generalized differential quadrature method. The shell structure consists of a damaged isotropic core and two external face sheets. The distributions of CNTs are either functionally graded (FG) or uniform across the thickness, with their mechanical properties determined through an extended rule of mixture. In this research, the conventional theory regarding the mechanical effectiveness of a matrix embedding finite-length fibers has been enhanced by introducing tube-to-tube random contact. This enhancement explicitly addresses the progressive reduction in the tubes' effective aspect ratio as the filler content increases. The study investigates the influence of a damaged matrix, CNT distribution, volume fraction, aspect ratio, and waviness on the free vibration characteristics of the sandwich cylindrical shell with wavy CNT-reinforced face sheets. Unlike two-dimensional theories such as classical and the first shear deformation plate theories, this inquiry is grounded in the three-dimensional theory of elasticity, which comprehensively accounts for transverse normal deformations.

• 펄프종이기술
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• 제36권4호
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• pp.60-66
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• 2004

In this paper, oyster shell, diatomaceous earth, and active carbon were used as filter media for treating wastewater produced in paper mills. After filtering, the changes of COD and turbidity were investigated. As the results of estimating the efficiency of wasterwater treatment, porous oyster shell having higher specific surface area in powder was more effective than the others in removal of contaminants in waterwater, especially turbidity.

• 한국제4기학회지
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• 제18권2호통권23호
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• pp.75-86
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• 2004

The sea level curve and environmental change were reconstructed at Sejuk-ri during the early Neolitic Age, based on the sedimentary facies, the distribution of remains and carbon datings. Before 6,500 years BP, the sea-level experienced one oscillation. The Neolitic men utilized geomorphic environment which formed according to the sea-level change. They might be occupied in gathering, fishing and hunting including whales hunting. The Neolitic men made acom hollows in order to remove tannin. Besides, they remained shell mounds which were formed from 6,500 years BP to around 6,000 years BP. They left the living place about 6,000 years BP because of transgression.

• 환경위생공학
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• 제14권2호
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• pp.18-24
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• 1999

The purpose of this study was carried out to estimate removal possibility of IBMP and IPMP causing odor in raw water. As a result of Freundlich isotherm. IBMP was superior to IPMP in adsorptive capacity. Adsorptive capacities of activated carbon were found to be in order of Lignite, Coconut shell, and Charcoal. These were well fitted with Freundlich isotherm. According to adsorption breakthrough tests for Lignite GAC, breakthrough time of IPMP and IBMP were 5.7hr and 5.5hr, respectively. Because adsorptive capacities of target material were very different with pore size distribution, it seemed that Lignite and Coconut shell based activated carbons were recommended in order to remove door compounds.

• 소성∙가공
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• 제13권4호
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• pp.319-325
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• 2004

Continuous casting machine has been experienced a rapid development to increase productivity with high casting speed and to meet consumer's strict demands for high quality. However, because most of defects and cracks are initially formed in mold and grown into surface cracks during the post process, more specific and clear investigations upon heat transfer mechanism between mold and solidified shell are necessarily needed. In this study heat transfer coefficients which shows the characteristic of heat transfer mechanism are calculated with temperatures measured in bloom mold using optimal algorithm, and thermal analysis are investigated using the calculated heat transfer coefficients. Finally uniformity of solidified shell is investigated for high carbon steel, 0.187%C from thermal analysis.

• Bulletin of the Korean Chemical Society
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• 제35권12호
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• pp.3465-3474
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• 2014

Porous silica particles are the most prevailing raw material for stationary phases of liquid chromatography. During a long period of time, various methodologies for production of porous silica particles have been proposed, such as crashing and sieving of xerogel, traditional dry or wet process preparation of conventional spherical particles, preparation of hierarchical mesoporous particles by template-mediated pore formation, repeated formation of a thin layer of porous silica upon nonporous silica core (core-shell particles), and formation of specific silica monolith followed by grinding and calcination. Recent developments and applications of useful porous silica particles will be covered in this review. Discussion on sub-$3{\mu}m$ silica particles including nonporous silica particles, carbon or metal oxide clad silica particles, and molecularly imprinted silica particles, will also be included. Next, the individual preparation methods and their feasibilities will be collectively and critically compared and evaluated, being followed by conclusive remarks and future perspectives.

• Steel and Composite Structures
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• 제28권3호
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• pp.381-388
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• 2018

In this paper, forced vibration of micro cylindrical shell reinforced by functionally graded carbon nanotubes (FG-CNTs) is presented. The structure is subjected to transverse harmonic load and modeled by beam model. The size effects are considered based on strain gradient theory containing three small scale parameters. The mixture rule is used for obtaining the effective material properties of the structure. Based on sinusoidal shear deformation theory of beam, energy method and Hamilton's principle, the motion equations are derived. Applying differential quadrature method (DQM) and Newmark method, the frequency curves of the structure are plotted. The effect of different parameters including, CNTs volume percent and distribution type, boundary conditions, size effect and length to thickness ratio on the frequency curves of the structure is studied. Numerical results indicate that the dynamic deflection of the FGX-CNT-reinforced cylindrical is lower with respect to other type of CNT distribution.