• Composites Research
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• 제23권3호
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• pp.7-12
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• 2010

탄소섬유 복합재료의 전기전도도와 기계적 강도를 높이기 위하여 음극 및 양극 전기영동법을 이용하여 탄소나노튜브(MWCNT)와 탄소나노섬유(CNF)를 탄소섬유직물에 부착하였다. 양극 전기영동에서는 MWCNT와 CNF의 탄소나노 입자들만이 탄소 섬유에 부착되었으나, 음극 전기영동에서는 MWCNT와 CNF 및 나노 크기의 구리 입자가 동시에 탄소섬유직물에 부착되었고 이에 따라 부착 밀도 및 복합재료 물성의 증대라는 시너지 효과를 거둘 수 있었다. 특히 나노 크기의 탄소나노입자 및 마이크로 크기의 탄소 섬유가 혼합된 멀티스케일 복합재료의 제조를 통해 두께 방향 전기전도도의 높은 향상을 얻었다. 또한 MWCNT와 CNF를 동시에 멀티스케일 복합재료에 적용하였을 경우, 각각을 적용한 경우보다 두께 방향 전기전도도가 높게 나타났다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 추계학술대회 논문집
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• pp.348-351
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• 2007

Simulations of the buckling behavior of a single wall carbon nanotube(SWCNT) was carried out using molecular dynamics simulation. Molecular dynamics simulations were done with 1fs of time step. Tersoff's potential function was used as the interatomic potential function since it has been proved to be reliable to describe the C-C bonds in carbon nanotubes. Compressive force was applied by moving the top end of the nanotube at a constant velocity. Buckling behavior under compressive load was observed for (15,15) armchair SWCNTs with 2nm of diameter and 24.9nm of length. Buckling load and critical strain is obtained from the MD simulation. Deformation occurred on the top region of the CNT because of fast downward velocity.

• 한국전기전자재료학회논문지
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• 제26권9호
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• pp.707-711
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• 2013

Carbon nanotubes(CNT) has strength and chemical stability, greatly conductivity characteristics. In particular, MWCNT (multi-walled carbon nanotubes) show rapidly resistance sensitive for changes in the ambient gas, and therefore they are ideal materials to gas sensor. So, we fabricated NOx gas sensors structured MOS-FET using MWCNT (multi-walled carbon nanotubes) material. We investigate the change resistance of NOx gas sensors based on MOS-FET with ultra lean NOx gas concentrations absorption. And NOx gas sensors show sensitivity on the change of gate-source voltage ($V_{gs}=0[V]$ or $V_{gs}=3.5[V]$). The gas sensors show the increase of sensitivity with increasing the temperature (largest value at $40^{\circ}C$). On the other hand, the sensitivity of sensors decreased with increasing of NOx gas concentration. In addition, We obtained the adsorption energy($U_a$), $U_a$ = 0.06714[eV] at the NOx gas concentration of 8[ppm], $U_a$ = 0.06769[eV] at 16[ppm], $U_a$ = 0.06847[eV] at 24[ppm] and $U_a$ = 0.06842[eV] at 32[ppm], of NOx gas molecules concentration on the MWCNT gas sensors surface with using the Arrhenius plots. As a result, the saturation phenomena is occurred by NOx gas injection of concentration for 32[ppm].

• 마이크로전자및패키징학회지
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• 제9권4호
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• pp.55-60
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• 2002

본 연구는 $580^{\circ}C$의 저온에서 ICPHFCVD(inductively coupled plasma hot filament chemical vapor deposition)를 이용하여 탄소나노튜브를 수직성장 시키는 것을 나타낸 것이다. 또한, 탄소나노튜브의 끝단에 존재하는 Ni-tip을 비성질 탄소같은 탄소질 물질등의 서로 다른 에칭특성에 기초하여 RF plasma를 이용하여 일회 공정으로 불순물을 정제하고, 고찰하였다. 정제된 이후의 탄소나노튜브는 속이 비어있는 다중벽 탄소나노튜브로 나타났으며, 성장된 탄소나노튜브는 외경과 내경은 50 nm와 25 nm였다. 또한, 탄소나노튜브의 graphite 층의 총수는 약 82개 층으로 구성되었으며, 층과 층간의 거리는 0.34nm였다. 그리고 TEM 관찰 결과, 탄소나노튜브 tip의 Ni촉매는 계속적인 에칭 공정에 의해 효과적으로 제거 되었다.

• Steel and Composite Structures
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• 제28권3호
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• pp.381-388
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• 2018

In this paper, forced vibration of micro cylindrical shell reinforced by functionally graded carbon nanotubes (FG-CNTs) is presented. The structure is subjected to transverse harmonic load and modeled by beam model. The size effects are considered based on strain gradient theory containing three small scale parameters. The mixture rule is used for obtaining the effective material properties of the structure. Based on sinusoidal shear deformation theory of beam, energy method and Hamilton's principle, the motion equations are derived. Applying differential quadrature method (DQM) and Newmark method, the frequency curves of the structure are plotted. The effect of different parameters including, CNTs volume percent and distribution type, boundary conditions, size effect and length to thickness ratio on the frequency curves of the structure is studied. Numerical results indicate that the dynamic deflection of the FGX-CNT-reinforced cylindrical is lower with respect to other type of CNT distribution.

• 한국전기전자재료학회논문지
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• 제17권2호
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• pp.212-216
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• 2004

In this paper, we have fabricated a triode field emitter using carbon nanotubes (CNTs) directly grown by thermal chemical vapor deposition(CVD) method as an electron omission source. Vertically aligned CNTs have been grown in the center of the gate hole, to the size of 1.5 ${\mu}{\textrm}{m}$ in diameter, with help of a sacrificial layer of a type generally used in metal tip process. By the method of tilling the substrate, we made CNTs emitters both with and without SiO$_2$layer, a sidewall protector, deposited on sidewall of gate. After that we researched the electrical characteristics about two types of emitters. In effect, a sidewall protector can enhance the electrical characteristics by suppressing the problem of short circuits between the gate and the CNTs. The leakage current of an emitter with a sidewall protector is approximately sevenfold lower than that of an emitter without it at a gate voltage of 100 V.

• Steel and Composite Structures
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• 제23권6호
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• pp.623-631
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• 2017

Present paper deals with the temperature-dependent buckling analysis of sandwich nanocomposite plates resting on elastic medium subjected to magnetic field. The lamina layers are reinforced with carbon nanotubes (CNTs) as uniform and functionally graded (FG). The elastic medium is considered as orthotropic Pasternak foundation with considering the effects of thermal loading on the spring and shear constants of medium. Mixture rule is utilized for obtaining the effective material properties of each layer. Adopting the Reddy shear deformation plate theory, the governing equations are derived based on energy method and Hamilton's principle. The buckling load of the structure is calculated with the Navier's method for the simply supported sandwich nanocomposite plates. Parametric study is conducted on the combined effects of the volume percent and distribution types of the CNTs, temperature change, elastic medium, magnetic field and geometrical parameters of the plates on the buckling load of the sandwich structure. The results show that FGX distribution of the CNTs leads to higher stiffness and consequently higher buckling load. In addition, considering the magnetic field increases the buckling load of the sandwich nanocomposite plate.

• 한국재료학회지
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• 제18권11호
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• pp.583-591
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• 2008

In this study, two series of CNT/$TiO_2$ electrodes were prepared. The decrease of surface area compared with that of the pristine carbon nanotubes (CNTs) indicated the blocking of micropores on the surface of the CNTs; was further supported by scanning electron microscopy (SEM) and field emission SEM (FE-SEM) observations. The X-ray diffraction (XRD) results showed that the CNT/$TiO_2$ composites contained a mix of anatase and rutile forms of $TiO_2$ particles when the precursor was $TiO_2$ powder, whereas when the precursor was Ti ($OC_4H_7$) (TNB), the composites contained only the typical single and clear anatase $TiO_2$ particles. The energy dispersive X-ray spectroscopy (EDX) spectra showed the presence of C, O and Ti peaks for all samples. It was found that catalytic decomposition of methylene blue (MB) solution could be attributed to synthetic effects between the $TiO_2$ photocatalysis and electro-assisted CNTs network, and that photoelectrocatalytic oxidation increased with an increase of CNT composition. It was also found that the photoelectrocatalytic oxidation efficiency for MB is higher than that of photocatalytic oxidation. Moreover, the CNT/$TiO_2$ composites catalyst prepared by the impregnation method demonstrates higher photoelectrocatalytic activity than the mechanical mixture with the same CNT content.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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• pp.97-98
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• 2009

Here, we describe a versatile strategy for precise control of the optoelectrical properties of the single walled carbon nanotube (SWNT)/silane binder hybrid films by noncovalent hybridization. Stable SWNT/silane binder solutions were prepared by direct mixing of high concentration CNT solutions and silane sol solutions. The critical binder content was determined by varying the amount of binder in the SWNT/binder solutions. A binder content of 50 wt% was used to prepare the other SWNT/binder solutions. This study demonstrates how the intermolecular interactions between the SWNTs and the silanes can affect the conductivity of the CNT/binder network films by characterizing the optoelectrical and Raman spectroscopic properties of the SWNT/silane films containing silane binders with various functional groups. The use of the PTMS binder with phenyl groups was found to be most effective in the fabrication of transparent and conductive films on glass substrates. Such a precise control of the optoelectrical properties of SWNT/binder films can be useful to fabricate the high performance conductive thin films, with ramifications for understanding the fundamental intermolecular interaction in carbon materials science.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1532-1534
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• 2008

Aquesous carbon nanotubes (CNTs) solutions were prepared using SDS (sodium dodecyl sulfonate) and NADDBS (sodium dodecylbenzene sulfonate). Our inks are found to have the viscosity of 1-2 cps. In addition, the surface tension of inks inversely decreased with increasing surfactant concentration and then saturated at critical micelle concentration (CMC). The low surface tension at CMC gave rise to lower contact angles on Indium layers, resulting in larger printable feature sizes. In the fabrication of cold cathode, jet-printing is feasible to modify and scale up the cathode structures. These feasibilities could contribute jet-printing method to be more adaptable for making large-area cold cathodes.