• 제목/요약/키워드: carbon nanotubes(CNT)

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탄소나노튜브(CNT)를 혼입한 초고성능 콘크리트(UHPC)의 고고도 전자기파(HEMP) 방호성능 평가 (Evaluation on High Altitude Electromagnetic Pulse(HEMP) Protection Performance of Carbon Nanotube(CNT) Embedded Ultra-High Performance Concrete(UHPC))

  • 정명준;홍성걸
    • 한국군사과학기술학회지
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    • 제22권2호
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    • pp.151-161
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    • 2019
  • In this study, to evaluate the High Altitude Electromagnetic Pulse(HEMP) protection performance of UHPC/CNT composites by the content of Carbon nanotubes(CNTs), Electromagnetic Shielding Effectiveness(SE) test was performed based on MIL-STD-188-125-1. And the results were verified by applying the Antenna theory. In the case of UHPC with a thickness of 200 mm mixed with 1 % CNT of cement weight, the SE was 28.98 dB at 10 kHz and 45.94 dB at 1 GHz. Then the Scabbing limit thickness for bullet proof was computed based on the result of compressive strength test which was 170 MPa, and it was examined whether it satisfied the HEMP protection criteria. As a result, the required HEMP shielding criteria were satisfied in all frequency ranges as well as the scabbing limit thickness was reduced by up to 43 % compared with that of ordinary concrete.

첨가제 종류에 따른 탄소나노튜브 금속복합재료 소결코팅 영향 (Influences to Additive Type on Carbon Nanotube metal composite)

  • 김대해;정희여;김민수;박찬우
    • Composites Research
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    • 제25권5호
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    • pp.159-163
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    • 2012
  • 냉매의 비등이나 응축같은 열전달 향상을 위하여 금속 표면위에 탄소나노튜브(CNT)를 코팅하는 것을 연구하였다. 분산제와 PVA(polyvinyl alcohol) 용액으로 분산 처리된 다중벽 탄소나노튜브/CuO의 복합 분말 코팅액을 구리기판위에 도포한 후 소결을 하였다. 본 논문에서는 CNT/CuO 소결 코팅시 다양한 분산제를 사용하여 소결 전후의 조직 형상 변화 및 특징을 실험적으로 평가하였다. 분산제로는 THF(Tetrahydrofuran), SDBS(Dodecylbenzenesulfonic acid sodium salt), SDS(Sodium dodecy sulfate)가 사용되었다. 각각의 시편들은 주사전자현미경, 열중량분석, 시차주사열량측정법, 라만분광법을 사용하여 분석하였다.

Photo Catalytic Activity of CNT-TiO2 Nano Composite in Degrading Anionic and Cationic Dyes

  • Kim, Sang-Jin;Im, Ji-Sun;Kang, Phil-Hyun;Kim, Tae-Jin;Lee, Young-Seak
    • Carbon letters
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    • 제9권4호
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    • pp.294-297
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    • 2008
  • A CNT-$TiO_2$ nano composite was prepared from titanium chloride ($TiCl_4$) via sol-gel process using multi walled carbon nano tube (MWCNT) followed by calcination at $450^{\circ}C$. Spectral analysis revealed that the formed $TiO_2$ resided on the carbon in anatase form. The effect of adsorption was investigated using aqueous solution of methylene blue and procion blue dye. The photochemical reaction of CNT-$TiO_2$ composite in aqueous suspensions was studied under UV illumination in batch process. The reaction was investigated by monitoring the discoloration of the dyes employing UV-Visible spectro-photometeric technique as a function of irradiation time. The catalyst composites were found to be efficient for the photodegradation of the dye.

Electrical Properties of CNT and Carbon Fiber Filled Hybrid Composites Based on PA66

  • Lee, Minji;Park, Se-Ho;Jhee, Kwang-Hwan;Kye, Hyoungsan;Bang, Daesuk
    • Elastomers and Composites
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    • 제56권2호
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    • pp.65-71
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    • 2021
  • In recent times, the demand for electronic devices has increased because of advancements in the electronics industry. Consequently, research on shielding against electromagnetic interference (EMI) from electronic devices has also progressed significantly. In particular, research on imparting electrical conductivity to plastic has seen substantial progress. In this study, the effect of hybrid fillers comprising carbon fiber (CF) and carbon nanotubes (CNTs) on the electrical properties of polyamide 66 (PA66) composites was investigated. PA66 composites were prepared using a BUSS Co-Kneader single-screw extruder. EMI shielding effectiveness (SE) increased with the increasing addition of unsized CF (UCF), sized CF (SCF), and CNTs. For the PA66/SCF/CNT hybrid filler composites, EMI SE significantly increased with the increase in SCF content. Finally, the hybrid filler comprising SCF and CNTs may have a synergistic effect on the EMI SE and surface resistivity of PA66/SCF/CNT composites.

On the mechanics of nanocomposites reinforced by wavy/defected/aggregated nanotubes

  • Heidari, Farshad;Taheri, Keivan;Sheybani, Mehrdad;Janghorban, Maziar;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • 제38권5호
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    • pp.533-545
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    • 2021
  • What is desirable in engineering is to bring the engineering model as close to reality as possible while the simplicity of model is also considered. In recent years, several studies have been performed on nanocomposites but some of these studies are somewhat far from reality. For example, in many of these studies, the carbon nanotubes (CNTs) are assumed completely straight, flawless and uniformly distributed throughout the matrix but by studying nanocomposites, we find that this is not the case. In this paper, three steps have been taken to bring the presented models for nanocomposites closer to reality. One is that assuming the straightness of nanotubes is removed and the waviness is considered. Also, the nanotubes are not considered to be pristine and the influence of defect is included in accordance with reality. In addition, the approximation of uniform distribution of nanotubes is ignored and according to experimental observations, the effect of nanotube aggregation is considered. As far as we know, this is the first study on these three topics together in an article. Moreover, we also include the size effects in our models for nanocomposites. To show the accuracy of our models, our results are calibrated with experimental results and compared with theoretical model. For numerical examples, we present the buckling behaviors of nanocomposites including the size effects using nonlocal theory and compare the results of our models with the results of models with above-mentioned approximations.

Growth of Vertically Aligned CNTs with Ultra Thin Ni Catalysts

  • Ryu, Je-Hwang;Yu, Yi-Yin;Lee, Chang-Seok;Jang, Jin;Park, Kyu-Chang;Kim, Ki-Seo
    • Transactions on Electrical and Electronic Materials
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    • 제9권2호
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    • pp.62-66
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    • 2008
  • We report on the growth mechanism of vertically aligned carbon nanotubes (VACNTs) using ultra thin Ni catalysts and direct current plasma enhanced chemical vapor deposition (PECVD) system. The CNTs were grown with -600 V bias to substrate electrode and catalyst thickness variation of 0.07 nm to 3 nm. The CNT density was reduced with catalyst thickness reduction and increased growth time. Cone like CNTs were grown with ultra thin Ni thickness, and it results from an etch of carbon network by reactive etchant species and continuous carbon precipitation on CNT walls. Vertically aligned sparse CNTs can be grown with ultra thin Ni catalyst.

다공성 구조를 가진 압저항 CNT/PDMS 소자의 감지특성 연구 (A Study of Detection Properties of Piezoresistive CNT/PDMS Devices with Porous Structure)

  • 이원준;이상훈
    • 센서학회지
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    • 제33권3호
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    • pp.165-172
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    • 2024
  • In this study, we investigated the detection properties of piezoresistive carbon nanotubes/polydimethylsiloxane (CNT/PDMS) devices with porous structures under applied pressure. The device, having dimensions of 10 mm × 10 mm × 5 mm, was fabricated with a porosity of 74.5%. To fabricate piezoresistive CNT/PDMS devices, CNTs were added using two different methods. In the first method, the CNTs were mixed with PDMS before the fabrication of the porous structure, while in the second, the CNTs were coated after the fabrication of the porous structure. Various detection properties of the fabricated devices were examined at different applied pressures. The CNT-coated device exhibited stable outputs with lesser variation than the CNT-mixed device. Moreover, the CNT-coated device exhibited improved reaction properties. The response time of the CNT-coated device was 1 min, which was approximately about 20 times faster than that of the CNT-mixed device. Considering these properties, CNT-coated devices are more suitable for sensing devices. To verify the CNT-coated device as a real sensor, it was applied to the gripping sensor system. A multichannel sensor system was used to measure the pressure distribution of the gripping sensor system. Under various gripping conditions, this system successfully measured the distributed pressures and exhibited stable dynamic responses.

CNT 마이크로파 가열을 이용한 고분자 기판의 상온 접합 및 기계적 특성평가 (Room-temperature Bonding and Mechanical Characterization of Polymer Substrates using Microwave Heating of Carbon Nanotubes)

  • 손민정;김민수;주병권;이태익
    • 마이크로전자및패키징학회지
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    • 제28권2호
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    • pp.89-94
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    • 2021
  • 최근 플렉시블 기기의 상용화를 위하여 기계적 신뢰성 연구가 활발히 진행되고 있으며 이를 고려하여 신뢰성 높은 다양한 접합부의 구현이 중요하다. 기기의 많은 부피를 차지하는 고분자 기판 또는 필름을 접합할 때에는 재료의 약한 내열성으로 접합공정 중 열 손상이 발생할 수 있으므로 신뢰성을 확보를 위해 상온 접합공정이 필요하다는 제약이 있다. 기존의 기판 접합을 위해 사용되는 에폭시 또한 고온 경화가 요구되는 경우가 많고, 특히 경화 접합 후 에폭시는 접합부 유연성 및 피로 내구성에서 한계를 보인다. 이를 해결하기 위하여 접착제 사용이 없는 저온 접합 공정의 개발이 필요한 상황이다. 본 연구에서는 마이크로파에 의한 탄소나노튜브 가열을 이용한 고분자 기판의 저온 접합공정을 개발하였다. PET 고분자 기판에 다중벽 탄소나노튜브 (MWNT)를 박막 코팅한 뒤 이를 마이크로파로 국부 가열함으로써 접합 기판 전체는 저온을 유지하며 CNT-PET 기계적 얽힘을 유도하는 방식이다. PET/CNT/PET 접합시편에 600 Watt 출력의 마이크로파를 10초간 조사함으로써 유연기판 접합에 성공하였고 매우 얇은 CNT 접합부를 구현하였다. 접합 시편의 기계적 신뢰성을 평가하기 위해 중첩 전단 강도 시험, 삼점 굽힘 시험, 반복 굽힘 시험을 수행하였으며 각 시험으로부터 우수한 접합강도, 유연성, 굽힘 내구성이 확인되었다.

Ni 나노입자의 배열을 이용한 다중벽 탄소나노튜브의 제어된 성장 (Controlled Growth of Multi-walled Carbon Nanotubes Using Arrays of Ni Nanoparticles)

  • 지승묵;이태진;방재호;홍영규;김한철;하동한;김창수;구자용
    • 한국진공학회지
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    • 제17권5호
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    • pp.473-480
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    • 2008
  • 화학기상증착법과 Ni 나노입자 배열을 이용한 탄소나노튜브의 최적 성장 조건을 연구했다. Ni 입자의 크기를 변화시키는 방법으로 탄소나노튜브의 직경을 20 nm 이하까지 제어할 수 있었다. 개별 Ni 입자의 크기와 위치는 기존의 식각법 등을 이용하여 웨이퍼 수준의 대면적에서 연속적으로 제어가 가능하였다. 성장온도, 탄소원, 희석가스 등의 비율을 최적화 함으로써 $SiO_2/Si$ 웨이퍼의 넓은 면적에서 각 Ni 입자로부터 단 한 개씩의 탄소나노튜브가 100% 확률로 성장 가능하다는 것을 보였다. 탄소나노튜브의 위치, 직경, 벽두께 등의 특성들은 성장조건을 조정하여 제어가능하다는 것을 보였다.

CNT/EEA를 사용한 반도전 재료의 열안정성에 관한 연구 (Study on the Thermal Properties of Semiconductive Shield Materials using CNT/EEA)

  • 양훈;양종석;국정호;방정환;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.223-224
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    • 2007
  • In this paper, we investigated resistant immunity of semiconductive shield materials in power cables' ordinary operation temperature. It used EEA(Ethylene Ethyl Acrylate) in base polymer and measured TGA(Thermal Gravimetric Analysis) in controlling contents. It increased pyrolysis temperature in content increasement of CNT(Carbon Nanotubes). As a result, we knew superiority that CNT:CB is 10:0.

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