• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.4
• /
• pp.2945-2950
• /
• 2015

While perfluoroalkane (PFA), a liquid state nucleating agent for a rigid polyurethane foam (RPUF) to enhance the thermal insulation property, has the excellent nucleating characteristics, it is very expensive as well as environmentally harmful due to the fluoride compound. Many researches, therefore, have been performed to develop the alternative nucleating agents to replace PFA. In the present work, a multi-wall carbon nanotube (MWCNT) was used as a sloid state nucleating agent, and thereby the effects on the property changes of the RPUF were carried out. Average cell size decreased from 165.6 for base RPUF to $162.9{\mu}m$ and cell uniformity was also enhanced, showing the standard cell-size deviation of 45.6 and 35.2, respectively. While k-factor of base PUF was $0.01763kcal/m.hr.^{\circ}C$, that of the sample with 0.01 phr MWCNT showed 1.02% reduced value of $0.01745kcal/m.hr.^{\circ}C$. Though the compressive yield stress is nearly the same as $0.030{\times}105Pa$ for the both samples, initial modulus of the sample with 0.01 phr MWCNT was higher than that of base sample. it was considered as the results that small amount of MWCNT could play a sufficient role as the effective nucleating agent for RPUF, showing that an echo-friendly RPUF with reduced-cost could be fabricated, which has an enhanced thermal and mechanical properties.

• Composites Research
• /
• v.27 no.5
• /
• pp.190-195
• /
• 2014

This paper predicts the complex permittivity of MWNT added epoxy depending on agglomeration by numerical analysis. 1wt% MWNT added epoxy specimen is prepared using 3-roll-mill method and its complex permittivity is measured in X-band (8.2~12.4 GHz) using freespace measurement system. The analytic model is comprised of cube epoxy and perfect sphere agglomeration. The complex permittivity of the agglomeration model is predicted by complex permittivity mixing rule using the measured complex permittivity of epoxy and 1 wt% MWNT added epoxy. Commercial electromagnetic analysis software, CST, is used to obtain S-parameter of the analytic model and MATLAB code is used to calculate complex permittivity from the S-parameter. It is confirmed that the complex permittivity increases when the agglomeration size decreases.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.8 no.4
• /
• pp.421-428
• /
• 2020

Recently, excellent thermal and electrical performance of cementitious composites by mixing nano materials are being studied. The purpose of this study is to research the heat generation and power consumption of rapid hardening nano-cementitious composites. The experiment was carried out after setting the rapid hardening cementitious material, curing day, and supply voltage as parameters. Rapid hardening nano-cementitious materials were classified into cement paste, mortar, and concrete The heat performance of all rapid hardening nano-cementitious composites in curing 1 day has increased over 10℃. The rapid hardening nano-cementitious composites can exhibit heat performance within 1 day. The heat performance of the rapid hardening nano-cementitious composites is maintained after 28 days.

• Korean Chemical Engineering Research
• /
• v.60 no.2
• /
• pp.184-192
• /
• 2022

Porous NiO synthesized via hydrothermal synthesis was used in the electrodes of lithium-sulfur batteries to inhibit the elution of lithium polysulfide. The electrode of the lithium-sulfur battery was manufactured as a freestanding flexible electrode using an economical and simple vacuum filtration method without a current collector and a binder. The porous NiO-added S/CNT/NiO electrode exhibited a high initial discharge capacity of 877 mA h g^-1 (0.2 C), which was 125 mA h g^-1 higher than that of S/CNT, and also showed excellent retention of 84% (S/CNT: 66%). This is the result of suppressing the dissolution of lithium polysulfide into the electrolyte by the strong chemical bond between NiO and lithium polysulfide during the charging and discharging process. In addition, for the flexibility test of the S/CNT/NiO electrode, the 1.6 × 4 cm² pouch cell was prepared and exhibited stable cycle characteristics of 620 mA h g^-1 in both the unfolded and folded state.

• Science of Emotion and Sensibility
• /
• v.25 no.1
• /
• pp.67-78
• /
• 2022

Interest in bio-signal monitoring of wearable devices is increasing significantly as the next generation needs to develop new devices to dominate the global market of the information and communication technology industry. Accordingly, this research developed a resistive textile strain sensor through a wetting process in a single-wall carbon nanotube dispersion solution using an E-Band with low hysteresis. To measure the resistance signal in the E-Band to which electrical conductivity is applied, a universal material tester, an Arduino, and LCR meters that are microcontroller units were used to measure the resistance change according to the tensile change. To effectively handle various noises generated due to the characteristics of the fabric textile strain sensor, the filter performance of the sensor was evaluated using the moving average filter, Savitsky-Golay filter, and intermediate filters of signal processing. As a result, the reliability of the filtering result of the moving average filter was at least 89.82% with a maximum of 97.87%, and moving average filtering was suitable as the noise filtering method of the textile strain sensor.

• Composites Research
• /
• v.35 no.3
• /
• pp.139-146
• /
• 2022

In this study, we study fabrication methods suitable for CNT fibers-based composite. We try to fabricate a composite material using a small amount of CNT fiber preparation of woven fabrics or stitched unidirectional fabrics consisting of CNT fiber is not achievable currently. The composite materials on the basis of CNT fibers have been mainly manufactured filament winding method due to productivity issues and difficulties in composite processes. We develop a new method to prepare CNT fibers-based composite using resin infiltrated CNT fibers-based films. Because CNT fibers have numerous nanopores inside, unnecessary resin can remain after curing and decrease the mechanical properties of the composites. To remove the excess resin, pressure should be applied during the process, but the pressure applied through VaRTM was not enough to remove the excess resin. To obtain the composite with high ratio of CNT fibers, higher pressure using hot press machine and foams next to the resin-infiltrated CNT fibers are necessary. We can obtain the composite having a mass ratio of 58.5 wt% based on the new suggested method and diluted epoxy. The specific strength of the composite reach 0.525 N/tex. This study presents a new process method that can be applied to the manufacturing of CNT fiber composite materials in the future.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.32 no.2
• /
• pp.77-82
• /
• 2022

Recently, research on the development of low-cost/high-efficiency water electrolysis catalysts to replace noble metal catalysts is being actively conducted. Since overvoltage reduces the overall efficiency of the water splitting device, lowering the overvoltage of the oxygen evolution reaction (OER) is the most important task in order to generate hydrogen more efficiently. Currently, noble metal catalysts show excellent characteristics in OER performance, but they are experiencing great difficulties in commercialization due to their high price and efficiency limitations due to low reactivity. In this study, a water electrolysis catalyst Ni-MWCNT was prepared by successfully doping Ni into the MWCNTs structure through the pulsed laser ablation in liquid (PLAL) process. High resolution-transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS) were performed for the structure and chemical composition of the synthesized Ni-MWCNT. Catalytic oxygen evolution reaction evaluation was performed by linear sweep voltammetry (LSV) overvoltage characteristics, Tafel slope, electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and Chronoamperometry (CA) was used for measurement.

• Clean Technology
• /
• v.29 no.3
• /
• pp.178-184
• /
• 2023

Transition metal chalcogenides have garnered significant attention as anode materials for sodium-ion batteries due to their high theoretical capacity. Nevertheless, their practical application is impeded by their limited lifespan resulting from substantial volume expansion during cycling and their low electrical conductivity. To tackle these issues, this study devised a solution by synthesizing a nanostructured anode material composed of porous CNT (carbon nanotube) spheres and (Ni,Co)Se₂ nanocrystals. By employing spray pyrolysis and subsequent heat treatments, a porous-structured (Ni,Co)Se₂-CNT composite microsphere was successfully synthesized, and its electrochemical properties as an anode for sodium-ion batteries were evaluated. The synthesized (Ni,Co)Se₂-CNT microsphere possesses a porous structure due to the nanovoids that formed as a result of the decomposition of the polystyrene (PS) nanobeads during spray pyrolysis. This porous structure can effectively accommodate the volume expansion that occurs during repeated cycling, while the CNT scaffold enhances electronic conductivity. Consequently, the (Ni,Co)Se₂-CNT anode exhibited an initial discharge capacity of 698 mA h g^-1 and maintained a high discharge capacity of 400 mA h g^-1 after 100 cycles at a current density of 0.2 A g^-1.

• Composites Research
• /
• v.36 no.4
• /
• pp.270-274
• /
• 2023

The stacking configuration of fiber-reinforced polymer (FRP) composites, achieved via the filament winding process, exhibits distinct variations compared to conventional FRP composite stacking arrangements. Consequently, it becomes challenging to ascertain the influence of mechanical properties based on the typical stacking structures. Thus, it becomes imperative to enhance the mechanical behavior and optimize the interleaved structures to improve overall performance. Therefore, this study aims to investigate the impact of incorporating amorphous halloysite nanotubes (A-HNTs) within different layers of five unique layer arrangements on the low-velocity impact properties of interleaved carbon fiber-reinforced polymer (CFRP) structures. The low-velocity impact characteristics of the laminate were validated using a drop weight impact test, wherein the resulting impact damage modes and extent of damage were compared and evaluated under microscopic analysis. Each interleaved structure laminate according to whether nanoparticles are added was compared at impact energies of 10 J and 15 J. In the case of 10 J, the absorption energy showed a similar tendency in each structure. However, at 15 J, the absorption energy varies from structure to structure. Among them, a structure in which nanoparticles are not added exhibits the highest absorption energy. Additionally, various impact fracture modes were observed in each structure through optical microscopy.

• Science of Emotion and Sensibility
• /
• v.25 no.4
• /
• pp.45-52
• /
• 2022

Recently, interest in and demand for sensors that recognize physical activity and their products are increasing. In particular, the development of wearable materials that are flexible, stretchable, and able to detect the user's biological signals is drawing attention. In this study, an experiment was conducted to improve the dip-coating efficiency of a single-walled carbon nanotube dispersion solution after fine holes were made in a hydrophobic material with a micro needle. In this study, dip-coating was performed with a material that was not penetrated, and comparative analysis was performed. The electrical conductivity of the sensor was measured when the sensor was stretched using a strain universal testing machine (Dacell Co. Ltd., Seoul, Korea) and a multimeter (Keysight Technologies, Santa Rosa, CA, USA) was used to measure resistance. It was found that the electrical conductivity of a sensor that was subjected to needling was at least 16 times better than that of a sensor that was not. In addition, the gauge factor was excellent, relative to the initial resistance of the sensor, so good performance as a sensor could be confirmed. Here, the dip-coating efficiency of hydrophobic materials, which have superior physical properties to hydrophilic materials but are not suitable due to their high surface tension, can be adopted to more effectively detect body movements and manufacture sensors with excellent durability and usability.