• Title/Summary/Keyword: carbon nanotube

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Fundamental parameters of nanoporous filtration membranes

  • Wei Li;Xiaoxu Huang;Yongbin Zhang
    • Membrane and Water Treatment
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    • v.14 no.3
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    • pp.115-120
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    • 2023
  • The design theory for nanoporous filtration membranes needs to be established. The present study shows that the performance and technical advancement of nanoporous filtration membranes are determined by the fundamental parameter I (in the unit Watt1/2) which is formulated as a function of the shear strength of the liquid-pore wall interface, the radius of the filtration pore, the membrane thickness, and the bulk dynamic viscosity of the flowing liquid. This parameter determines the critical power loss on a single filtration pore for initiating the wall slippage, which is important for the flux of the membrane. It also relates the membrane permeability to the power cost by the filtration pore. It is shown that for biological cellular membranes its values are on the scale 1.0E-8Watt1/2, for mono-layer graphene membranes its values are on the scale 1.0E-9Watt1/2, and for nanoporous membranes made of silica, silicon nitride or silicon carbonized its values are on the scale 1.0E-5Watt1/2. The scale of the value of this parameter directly measures the level of the performance of a nanoporous filtration membrane. The carbon nanotube membrane has the similar performance with biological cellular membranes, as it also has the value of I on the scale 1.0E-8Watt1/2.

Effect of Edge-Chemistry on Graphene-Based Hybrid Electrode Materials for Energy Storage Device

  • Hyo-Young Kim;Ji-Woo Park;Seo Jeong Yoon;In-Yup Jeon;Young-Wan Ju
    • Journal of Electrochemical Science and Technology
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    • v.14 no.1
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    • pp.31-37
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    • 2023
  • Owing to the rapid climate change, a high-performance energy storage system (ESS) for efficient energy consumption has been receiving considerable attention. ESS, such as capacitors, usually has issues with the ion diffusion of electrode materials, resulting in a decrease in their capacitance. Notably, appropriate pore diameter and large specific surface area (SSA) may result in an effective ion diffusion. Therefore, graphene and multi-walled carbon nanotube (graphene@MWCNT) hybrid nanomaterials, with covalent bonds between the graphene and MWCNT, were prepared via an edge-chemistry reaction. The properties of these materials, such as high porosity, large SSA, and high electroconductivity, make them suitable to be used as electrode materials for capacitors. The optimal ratio of graphene to MWCNT can affect the electrochemical performance of the electrode material based on its physical and electrochemical properties. The supercapacitor using optimal graphene-based hybrid electrode material exhibited highest specific capacitance value as 158 F/g and excellent cycle stability.

Characteristics of Hybrid Protective Materials with CNT Sheet According to Binder Type

  • Jihyun Kwon;Euisang Yoo
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.197-204
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    • 2022
  • Recently, the demand has increased for protective clothing materials capable of shielding the wearer from bullets, fragment bullets, knives, and swords. It is therefore necessary to develop light and soft protective clothing materials with excellent wearability and mobility. To this end, research is being conducted on hybrid design methods for various highly functional materials, such as carbon nanotube (CNT) sheets, which are well known for their low weight and excellent strength. In this study, a hybrid protective material using CNT sheets was developed and its performance was evaluated. The material design incorporated a bonding method that used a binder for interlayer combination between the CNT sheets. Four types of binders were selected according to their characteristics and impregnated within CNT sheets, followed by further combination with aramid fabric to produce the hybrid protective material. After applying the binder, the tensile strength increased significantly, especially with the phenoxy binder, which has rigid characteristics. However, as the molecular weight of the phenoxy binder increased, the adhesive force and strength decreased. On the other hand, when a 25% lightweight-design and high-molecular-weight phenoxy binder were applied, the backface signature (BFS) decreased by 6.2 mm. When the CNT sheet was placed in the middle of the aramid fabric, the BFS was the lowest. In a stab resistance test, the penetration depth was the largest when the CNT sheet was in the middle layer. As the binder was applied, the stab resistance improvement against the P1 blade was most effective.

Nonlinear bending analysis of functionally graded CNT-reinforced composite plates

  • Cho, Jin-Rae
    • Steel and Composite Structures
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    • v.42 no.1
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    • pp.23-32
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    • 2022
  • In this paper, a nonlinear numerical method to solve the large deflection problem is introduced. And the non-dimensional load-deflection behavior of functionally graded carbon nanotube-reinforced composite (FG-CNTRC) plates is parametrically investigated. The large deflection problem is formulated according to the von Kármán nonlinear theory and the (1,1,0)* hierarchical model, and it is approximated by 2-D natural element method (NEM). The shear locking phenomenon is suppressed by the selectively reduced integration method. The nonlinear matrix equations are solved by combining the incremental loading scheme and the Newton-Raphson iteration method. The proposed method is validated from the benchmark experiments, where the propose method shows an excellent agreement with the reference methods. The nonlinear behavior of FG-CNTRC plates is evaluated in terms of the non-dimensional load-deflection curve, and it is parametrically investigated with respect to the existence/non-existence and gradient pattern of CNTs, the width-to-thickness and aspect ratios of plates and the type of boundary conditions. The non-dimensional central deflection is significantly reduced when CNTs and added, and it decreases with the volume fraction of CNTs. But, it shows a uniform increase in proportion to the width-to-thickness and aspect ratios. Both the gradient pattern of CNTs and the type of boundary conditions do also show the remarkable effects.

Table Flow Evaluation of CNT-Mixed Fiber Reinforced Cement Composite by Dispersion Method (분산방법에 따른 CNT를 혼입한 섬유보강 시멘트복합체의 유동성 평가)

  • Kim, Moon-Kyu;Kim, Gyu-Yong;Pyeon, Su-Jeong;Choi, Byung-Cheol;Park, Jun-Young;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.95-96
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    • 2023
  • In this study, the table flow of fiber reinforced cement composites mixed with CNTs dispersed differently according to the dispersion method was evaluated. The mixture was composed of plain mixture according to the presence or absence of ultrasonic dispersion and PCE-based dispersants A and B of 0.5% and 1.0%, respectively, CNT was mixed with 0.03% of cement weight and fiber was mixed with 1.5% of total volume. As a result of the experiment, NC-A0.5 showed a fluidity similar to that of P without CNT. The fluidity of NC-A0.5 and P-N showed a similar tendency, which is considered to be due to the distribution of evenly dispersed CNT particles without agglomeration between cement particles due to the dispersant. NC-B0.5 showed a similar level of firmness to P-U, but after hitting 250 mm, B Agent seems to have a significant effect on liquidity improvement.Both NC-A1.0 and NC-B1.0 seem to have increased flow due to excessive dispersion.

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Anti-icing Method of Heated Walkway in Ice Class Ships: Efficiency Verification of CNT-based Surface Heating Element Method Through Numerical Analysis

  • Woo-Jin Park;Dong-Su Park;Mun-Beom Shin;Young-Kyo Seo
    • Journal of Ocean Engineering and Technology
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    • v.37 no.5
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    • pp.215-224
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    • 2023
  • While melting glaciers due to global warming have facilitated the development of polar routes, Arctic vessels require reliable anti-icing methods to prevent hull icing. Currently, the existing anti-icing method, i.e., the heating coil method, has disadvantages, such as disconnection and power inefficiency. Therefore, a carbon nanotube-based surface heating element method was developed to address these limitations. In this study, the numerical analysis of the surface heating element method was performed using ANSYS. The numerical analysis included conjugate heat transfer and computational fluid dynamics to consider the conduction solids and the effects of wind speed and temperature in cold environments. The numerical analysis method of the surface heating element method was validated by comparing the experimental results of the heating coil method with the numerical analysis results (under the -30 ℃ conditions). The surface heating element method demonstrated significantly higher efficiency, ranging from 56.65-80.17%, depending on the conditions compared to the heating coil method. Moreover, even under extreme environmental conditions (-45 ℃), the surface heating element method satisfied anti-icing requirements. The surface heating element method is more efficient and economical than the heating coil method. However, proper heat flux calculation for environmental conditions is required to prevent excessive design.

Mechanical and Electrical Characteristics of Concrete Members Enlarged with Self-Sensing Cementitious Materials for Repair (자기감지형 보수재로 단면증타된 콘크리트 부재의 역학 및 전기적 특성 )

  • Gun-Cheol Lee;Geon-Woo Im;Chang-Min Lee;Sung-Won Hong;Young-Min Kim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.5
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    • pp.139-146
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    • 2023
  • In this study, compressive strength and adhesion strength were measured as repair materials to evaluate the mechanical and electrical properties of compression and shear specimens with self-sensing repair materials. As a result of the experiment, the strength improvement rate of the compression test specimen was higher than the section enlargement area ratio, but the shear test specimen did not show an improvement in strength as much as the section enlargement area ratio. Compression experiments under load showed high correlation between FCR-Strain and FCR-Stress, confirming self-sensing performance. However, the shear test did not show as much correlation as the compression test. Accordingly, it is judged that the self-sensing repair material is suitable for the compression member on which the compression load acts in the building.

Synthesis and Properties of Ni-CNT Nanocomposites Using Electrical Explosion of Wire in Different Conditions

  • Maithili Biswas; Jin-Chun Kim
    • Korean Journal of Materials Research
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    • v.34 no.3
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    • pp.138-143
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    • 2024
  • Ni-CNT nanocomposites were synthesized via the electrical explosion of wire (EEW) in acetone and deionized (DI) water liquid conditions with different CNT compositions. The change in the shape and properties of the Ni-CNT nanopowders were determined based on the type of fluids and CNT compositions. In every case, the Ni nanopowder had a spherical shape and the CNT powder had a tube shape. However, the Ni-CNT nanopowders obtained in DI water exhibited irregular shapes due to the oxidation of Ni. Phase analysis also revealed the existence of nickel oxide when using DI water, as well as some unknown peaks with acetone, which may form due to the metastable phase of Ni. Magnetic properties were investigated using a Vibrating Sample Magnetometer (VSM) for all cases. Nanopowders prepared in DI water conditions had better magnetic properties than those in acetone, as evidenced by the simultaneous formation of super paramagnetic NiO peaks and ferromagnetic Ni peaks. The DI water (Ni:CNT = 1:0.3) sample revealed better magnetic results than the DI water (Ni-CNT = 1:0.5) because it had less CNT contents.

Novel Design of 8T Ternary SRAM for Low Power Sensor System

  • Jihyeong Yun;Sunmean Kim
    • Journal of Sensor Science and Technology
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    • v.33 no.3
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    • pp.152-157
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    • 2024
  • In this study, we propose a novel 8T ternary SRAM that can process three logic values (0, 1, and 2) with only two additional transistors, compared with the conventional 6T binary SRAM. The circuit structure consists of positive and negative ternary inverters (PTI and NTI, respectively) with carbon-nanotube field-effect transistors, replacing conventional cross-coupled inverters. In logic '0' or '2,' the proposed SRAM cell operates the same way as conventional binary SRAM. For logic '1,' it works differently as storage nodes on each side retain voltages of VDD/2 and VDD, respectively, using the subthreshold current of two additional transistors. By applying the ternary system, the data capacity increases exponentially as the number of cells increases compared with the 6T binary SRAM, and the proposed design has an 18.87% data density improvement. In addition, the Synopsys HSPICE simulation validates the reduction in static power consumption by 71.4% in the array system. In addition, the static noise margins are above 222 mV, ensuring the stability of the cell operation when VDD is set to 0.9 V.

Laser micro-drilling of CNT reinforced polymer nanocomposite: A parametric study using RSM and APSO

  • Lipsamayee Mishra;Trupti Ranjan Mahapatra;Debadutta Mishra;Akshaya Kumar Rout
    • Advances in materials Research
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    • v.13 no.1
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    • pp.1-18
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    • 2024
  • The present experimental investigation focuses on finding optimal parametric data-set of laser micro-drilling operation with minimum taper and Heat-affected zone during laser micro-drilling of Carbon Nanotube/Epoxy-based composite materials. Experiments have been conducted as per Box-Behnken design (BBD) techniques considering cutting speed, lamp current, pulse frequency and air pressure as input process parameters. Then, the relationship between control parameters and output responses is developed using second-order nonlinear regression models. The analysis of variance test has also been performed to check the adequacy of the developed mathematical model. Using the Response Surface Methodology (RSM) and an Accelerated particle swarm optimization (APSO) technique, optimum process parameters are evaluated and compared. Moreover, confirmation tests are conducted with the optimal parameter settings obtained from RSM and APSO and improvement in performance parameter is noticed in each case. The optimal process parameter setting obtained from predictive RSM based APSO techniques are speed=150 (m/s), current=22 (amp), pulse frequency (3 kHz), Air pressure (1 kg/cm2) for Taper and speed=150 (m/s), current=22 (amp), pulse frequency (3 kHz), air pressure (3 kg/cm2) for HAZ. From the confirmatory experimental result, it is observed that the APSO metaheuristic algorithm performs efficiently for optimizing the responses during laser micro-drilling process of nanocomposites both in individual and multi-objective optimization.