• Title/Summary/Keyword: carbon effect

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Long-term clinical and experimental/surface analytical studies of carbon/carbon maxillofacial implants

  • Szabo, Gyorgy;Barabas, Jozsef;Bogdan, Sandor;Nemeth, Zsolt;Sebok, Bela;Kiss, Gabor
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.37
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    • pp.34.1-34.14
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    • 2015
  • Background: Over the past 30-40 years, various carbon implant materials have become more interesting, because they are well accepted by the biological environment. The traditional carbon-based polymers give rise to many complications. The polymer complication may be eliminated through carbon fibres bound by pyrocarbon (carbon/carbon). The aim of this study is to present the long-term clinical results of carbon/carbon implants, and the results of the scanning electron microscope and energy dispersive spectrometer investigation of an implant retrieved from the human body after 8 years. Methods: Mandibular reconstruction (8-10 years ago) was performed with pure (99.99 %) carbon implants in 16 patients (10 malignant tumours, 4 large cystic lesions and 2 augmentative processes). The long-term effect of the human body on the carbon/carbon implant was investigated by comparing the structure, the surface morphology and the composition of an implant retrieved after 8 years to a sterilized, but not implanted one. Results: Of the 16 patients, the implants had to be removed earlier in 5 patients because of the defect that arose on the oral mucosa above the carbon plates. During the long-term follow-up, plate fracture, loosening of the screws, infection or inflammations around the carbon/carbon implants were not observed. The thickness of the carbon fibres constituting the implants did not change during the 8-year period, the surface of the implant retrieved was covered with a thin surface layer not present on the unimplanted implant. The composition of this layer is identical to the composition of the underlying carbon fibres. Residual soft tissue penetrating the bulk material between the carbon fibre bunches was found on the retrieved implant indicating the importance of the surface morphology in tissue growth and adhering implants. Conclusions: The surface morphology and the structure were not changed after 8 years. The two main components of the implant retrieved from the human body are still carbon and oxygen, but the amount of oxygen is 3-4 times higher than on the surface of the reference implant, which can be attributed to the oxidative effect of the human body, consequently in the integration and biocompatibility of the implant. The clinical conclusion is that if the soft part cover is appropriate, the carbon implants are cosmetically and functionally more suitable than titanium plates.

Effect of Activated Carbon on Reducing Herbicide Injury to Vegetables (활성탄(活性炭)의 토양처리(土壤處理)가 채소(菜蔬)에 대(對)한 제초제(除草劑)의 약해경감(藥害輕減)에 미치는 영향(影響))

  • Pyon, Jong Yeong
    • Korean Journal of Agricultural Science
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    • v.7 no.1
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    • pp.27-32
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    • 1980
  • In order to determine the effect of activated carbon on toxicity of linuron and napropamide to Chinese cabbage, red pepper, and tomatoes, 5 and 10kg/10a of activated carbon were applied to the soil surface prior to treatment of linuron at 50 and 75g/10a and napropamide at 150 and 225g/10a. 1. Chinese cabbage was protected from linuron injury by spraying activated carbon on the soil to adsorb and detoxify the herbicides even though it was completely killed by linuron at 50 and 75g/10a without activated carbon application. However, Chinese cabbage was not injured by napropamide at 150 and 225g/10a and thus antidotal effect by activated carbon was negligible. 2. Red pepper was greatly injured by linuron at 50 and 75g/10a, but activated carbon significantly reduced linuron injury. Napropamide at 225g/10a was slightly injurious to red pepper. Nevertheless, this injury effect was reduced by activated carbon at 5kg/10a. 3. Tomatoes were also severely injured by linuron at 75g/10a, but activated carbon prevented linuron injury to tomatoes. However, napropamide at 150 and 225g/10a were slightly injurious to tomatoes and activated carbon did not completely prevent napropamide injury to tomatoes.

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An investigation of tribology properties carbon nanotubes reinforced epoxy composites (표면 개질된 탄소나노튜브를 사용한 에폭시 복합재료의 마모특성에 관한 연구)

  • Sulong A.B.;Goak J.C.;Park Joo-Hyuk
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.663-667
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    • 2005
  • Surface modified carbon nanotubes were applied into the epoxy composites to investigate its tribological property. Carbon nanotubes reinforced epoxy composites were fabricated by casting. Effects to the tribological property of loading concentrations and types of surface modification of carbon nanotubes were investigated under sliding condition using linear reciprocal sliding wear tester. The results show that the small amount of carbon nanotubes into the epoxy exhibited lower weight loss than the pure epoxy. It is concluded that the effect of an enormous aspect ratio of carbon nanotubes surface area which wider than conventional fillers that react as interface for stress transfer. As increased the contents of carbon nanotubes, the weight loss from the wear test was reduced. And the surface modified carbon nanotubes show better tribological property than as produced carbon nanotubes. It is due that a surface modification of carbon nanotubes increases the interfacial bonding between carbon nanotubes and epoxy matrix through chemical bonding. Changes in worn surface morphology are also observed by optical microscope and SEM for investigating wear behaviors. Carbon nanotubes in the epoxy matrix near the surface are exposed, because it becomes the lubricating working film on the worn surface. It reduces the friction and results in the lower surface roughness morphology in the epoxy matrix as increasing the contents of the carbon nanotubes.

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Characteristics of Carbon Dioxide Destruction with a Plasma Torch and Effect of Additives (플라즈마 토치를 이용한 이산화탄소 분해특성과 첨가제의 영향)

  • Kim, Seong Cheon;Jeon, Jeong Hyeon;Chun, Young Nam
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.3
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    • pp.287-296
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    • 2013
  • To decompose carbon dioxide, which is a representative greenhouse gas, a plasma torch was designed and manufactured. To examine the characteristics of carbon dioxide decomposition via plasma discharge, a case wherein pure carbon dioxide was supplied and a case wherein methane and/or $TiCl_4$ were injected as additives were investigated and compared. The carbon dioxide and methane conversion rate, energy decomposition efficiency, produced gas concentration, carbon monoxide and hydrogen selectivity, carbon-black and $TiO_2$ were also investigated. The maximum carbon dioxide conversion rate was 28.9% when pure carbon dioxide was supplied; 44.6% when $TiCl_4$ was injected as am additive; and 100% percent when methane was injected as an additive. Therefore, this could be explained that the methane injection showed the highest carbon dioxide decomposition. Furthermore, the carbon-black and $TiO_2$ were compared with each commercial materials through XRD and SEM. It was found that the carbon-black that was produced in this study is similar for commercial materials. It was found that the $TiO_2$ that was produced in this study is suitable for photocatalyst and pigment because it has mixed anataze and rutile.

Effect of Carbon Amino Silica Black Contained Superplasticizer on the Engineering Properties and Chromaticity of Black Color Concrete (카본 아미노 실리카 블랙 기반 고성능 감수제가 블랙 컬러 콘크리트의 공학적 특성 및 발색도에 미치는 영향)

  • Han, Min-Cheol;Hong, Seok-Min
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.181-188
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    • 2013
  • This paper is to investigate experimentally an effect of carbon amino silica black-superplasticizer(CASB-SP)on the engineering properties and chromaticity of black color concrete with 0.45 of W/C(water to cement). CASB-SP and carbon black were applied for pigment of the concrete. To prevent efflorescence of concrete, four different water repellent agents were also applied. As results, it was found that use of CASB-SP increased the slump and air contents. Furthermore, the use of CASB-SP increased the compressive strength. As CASB-SP dosages increased, chromaticity was well developed. For the effect of water repellent agent, the use of epoxy type was effective for protection from efflorescence. Based on test results, it was evaluated that 0.5% of CASB-SP effectively improve the concrete quality as well as enhance the chromaticity with proper dosage.

Initial Stage of Atmospheric Corrosion of Carbon and Weathering Steels in Thailand Climate

  • Nii, K.;Bhamornsut, C.;Chotimongkol, L.;Vutivat, E.;Nakkhuntod, R.;Jeenkhajohn, P.;Suphonlai, S.
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.183-188
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    • 2003
  • Corrosion of carbon and weathering steels were evaluated under 3 environmental exposures in Thailand (urban, rural and marine) for a year. The seasonal study was designed to determine different corrosion mechanisms by 6 months of dry season and 6 months of rainy season in a year. The sheltered exposure racks were used to determine the washing effect of min. At each site, climatic and pollutants analyses were carried out. The present study showed that the difference in corrosion rates of carbon and weathering steels was not so distinguished in both rural (AIT) and urban (TISTR) environments. The corrosion rate of weathering steel was somewhat lower than that of carbon steel and the decreasing tendency of corrosion rate with time was slightly higher for weathering steel than for carbon steel. In marine (Rayong) environment, the corrosion rate was higher and the effect of wet and dry seasons was observed. The corrosion rate in 6 dry months was higher for direct exposure than for sheltered exposure. However, in 6 rainy months. the corrosion rate of sheltered exposure was higher than that of direct exposure. In direct exposure for I year, that is, the first 6 dry months and the next 6 rainy months, the corrosion rate decreased with time. but in sheltered exposure, the corrosion rate did not decrease with time. instead, increased in the next 6 rainy months. This indicated that the protect ive layer formed in the first 6 dry months could be destroyed by high deposition of chloride to r sheltered exposure in the next 6 rainy months; whereas the rust layer for direct exposure could be kept sound due to washing effect in rainy season, even though the deposition rate of chloride was almost the same for direct and sheltered exposures. In marine environment, the weathering steel showed higher corrosion resistance than carbon steel but its corrosion rate was higher than those in other environments.

Low-Carbon Information Management of Street Lamps and Street Trees Using GIS (GIS를 이용한 가로등 및 가로수의 저탄소 정보 관리)

  • Choi, Byoung Gil;Na, Young Woo;Kwon, Oh Sub
    • Journal of Korean Society for Geospatial Information Science
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    • v.22 no.1
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    • pp.55-62
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    • 2014
  • Diverse improvement projects such as replacing street lamps with LED, street trees, etc are currently in progress in Korea to reduce greenhouse gas so as to cope with change in climate. However, the effect of climate change policy is not exactly analyzed, because exhaust quantity and absorption quantity of greenhouse gas of the target street lamp and street trees are not arranged as information. Thus, this study studied the method to systematically manage low carbon related information of urban facilities by using GIS. It was found that low carbon information of the urban facilities is necessary to exactly analyze effect of climate change policy and the method to calculate carbon exhaust quantity and absorption quantity of each facilities should be established to build exact low carbon information of urban facilities. Further, it was found that the visualization of information related to low carbon of street lamp and street trees by using GIS easily and visually grasps and systematically controls the effect of policy coping with change in climate than the existing numeral data of exhaust quantity and absorption quantity of greenhouse gas.

Effect of Multi-wall Carbon Nanotube Surface Treatment on the Interface and Thermal Conductivity of Carbon Nanotube-based Composites (다중벽탄소나노튜브 복합재료의 계면 및 열전도도에 표면처리 방법이 미치는 영향)

  • Yoo, Gi-Moon;Lee, Sung-Goo;Kim, Sung-Ryong
    • Journal of Adhesion and Interface
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    • v.11 no.4
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    • pp.174-180
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    • 2010
  • The effect of carbon nanotube surface treatment on the interface and thermal conductivity of carbon nanotube-based poly(methylmethacrylate) (PMMA) composites was investigated. Coagulation and atomic-transfer radical polymerization (ATRP) was applied to modify the surface of multi-wall carbon nano-tube. The composite of ATRP method used carbon nanotube showed the higher transparency and thermal conductivities than that of the coagulation method used. In comparison to the thermal conductivity of pure PMMA, 0.21 W/mK, the ATRP carbon nanotube used PMMA/MWNT composite showed a thermal conductivity of 0.38 W/mK. The interface between carbon nanotube and PMMA was observed by scanning electron microscope and uniform dispersion of carbon nanotube was observed without any void in the PMMA matrix. It may be beneficial to transport the phonon without any scattering and it may result in a higher thermal conductivity.

A Study on the Adsorption Characteristics of Phenol in the presence of Humic Acid Using Activated Carbon Fiber (섬유상활성탄소를 이용한 Humic Acid 공존시 페놀의 흡착특성에 관한 연구)

  • Tak, Seong-Jae;Seo, Seong-Wen;Kim, Seong-Sun;Kim, Jin-Man
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.54-61
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    • 2000
  • Recently, our circumstances are threatened by an accident that leakage of under ground storage tank and illegal dumping of synthetic organic compounds at chemical plants and many treatment methods, Activated carbon adsorption, Ozonization, Membrane filtration and Photocatalystic oxidation, are developed to remove such a synthetic organic compounds. And it has reported that Activated carbon adsorption have a great removal efficiency to nondegradable matters and organic compounds which have a high molecular weight. Comparing with other adsorbents, Activated carbon adsorption have a worse efficiency when ad desorption speed is low. Thus improved type of adsorbents was invented and one of those is Activated Carbon Filter. The purpose of this study was getting information about adsorption characteristic phenol which can be applied Activated Carbon Fiber and Granular Activated Carbon. In detail, With comparing removal characteristics of phenol in the presence Humic Acid using Activated Carbon Fiber(ACF) and Granular Activated. Carbon(GAC), it is to certify an effective application of Activated Carbon Fiber. At the range of this study, Batch test, Isotherm adsorption test and Factorial analysis, following conclusion were obtained from the results of this study. Batch test was carried to know time of adsorption equilibrium. In this study about time of adsorption equilibrium by ACF was faster than GAC's, for developed micropore of ACF. From the result of phenol adsorption test, High removal rate of adsorption is shown at pH 5. The result of lsotherm adsorption test, it has represented that the Freundlich's isotherm is most suitable one in others, that a ACF's adsorption capacity is more excellent than GAC's. Adsorption of phenol exiting humic acid is decreased getting raised humic acid concentration. Since ACF's micropore is developed at this time, an effect of high molecular humic acid is lower. Factorial analysis was carried to know about Main effect which was injection dosage of adsorbent in the range of this study.

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