• 제목/요약/키워드: carbon effect

검색결과 5,661건 처리시간 0.031초

Oxidation Resistance and Graphitization of Boron Oxide Implanted Carbon/Carbon Composites

  • Joo, Hyeok-Jong;Oh, In-Hwan;Ahn, Il-Hwan
    • Carbon letters
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    • 제5권3호
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    • pp.127-132
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    • 2004
  • Chop molding composites and 2D carbon/carbon composites were manufactured by hot press molding method. Phenol resin of novolac type was used for matrix precursor and PAN-based carbon, PAN-based graphite and pitch-based carbon fiber were used for reinforcement and boron oxide was used for oxidation retardant. All of the composites were treated by $2000^{\circ}C$ and $2400^{\circ}C$ graphitization process, respectively. After graphitization process, amount of a boron residue in carbon/carbon composites is much according to irregularity of used raw materials. Under the presence of boron in carbon/carbon composites, catalytic effect of boron was a little at $2000^{\circ}C$ graphitization temperature. However, it was quite at $2400^{\circ}C$ graphitization.

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Additional Effect of Zeolite Based on Bactericidal Activated Carbon Spheres with Enhanced Adsorption Effect and Higher Ignition Temperature

  • Zhu, Lei;Ye, Shu;Asghar, Ali;Bang, Seong-Ho;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제53권1호
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    • pp.68-74
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    • 2016
  • In this study, the fabrication of zeolite combined activated carbon spherical samples was carried out as follows. Briefly, ZSM-5 zeolite and activated carbon were composed as main absorbent materials; by controlling the weight percentage of zeolite and binder materials, a series of spherical samples (AZP 4, 6, 8) were prepared. These spherical samples were characterized by BET, XRD, SEM, EDX, and pressure drop; benzene and iodine adsorption tests, bactericidal effect test, and ignition temperature test were also performed. The adsorption capability was found to depend on the BET surface area; the spherical samples AZP6 with high BET surface area of $1011m^2/g$ not only exhibited excellent removal effects for benzene (24.9%) and iodine (920mg/g) but also a good bactericidal effect. The enhanced ignition temperature may be attributed to the homogeneous dispersion conditions and the proper weight percentage ratio between zeolite and activated carbon.

Preparation and Performance Analysis of Ophthalmic Polymer Using SWCNT and SWCCNT

  • Shin, Su-Mi;Sung, A-Young
    • 한국재료학회지
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    • 제29권12호
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    • pp.735-740
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    • 2019
  • The purpose of this study is to fabricate an ophthalmic lens by copolymerizing two types of carbon nanotubes and hydrophilic hydrogel lens materials, and to investigate its application as an ophthalmic lens material by analyzing its physical properties and antimicrobial effect. For polymerization, HEMA (2-hydroxyethyl methacrylate), EGDMA (ethylene glycol dimethacrylate), a crosslinking agent, and AIBN (azobisisobutyronitrile), an initiator, are used as a basic combination, and a single-walled carbon nanotube and a single-walled, carboxylic-acid-functionalized carbon nanotube are used as additives. To analyze the physical properties, the water content, refractive index, breaking strength, and antimicrobial effect of the fabricated lenses are measured. The fabricated lenses satisfies all the basic properties of the basic hydrogel ophthalmic lens. The water content increases with increasing amount of additive and decreases with addition of 0.2 % ratio of nanoparticles. The refractive index is inversely proportional to the water content result. As a result of the antimicrobial test of the fabricated lens, the addition of carbon nanotubes shows an excellent antimicrobial effect. Therefore, it is considered that the fabricated lens can be applied as a functional material for basic ophthalmic hydrogel lenses.

우리나라의 조세중립적 탄소세 도입의 이중배당 효과 (Revenue Neutral Introduction of Carbon Tax and Double-dividend Effect on the Korean Economy)

  • 임종수;김용건
    • 자원ㆍ환경경제연구
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    • 제19권1호
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    • pp.45-80
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    • 2010
  • 본 연구는 우리나라의 기후변화 대응 정책 입안에 있어 조세중립적 세제개편을 통한 탄소세의 도입에 따른 이중배당가설이 성립하는지를 연산가능일반균형모형을 이용하여 검토해 보았다. 법인세율 감경과 법정복리비 감경을 통한 조세중립적 세제개편과 병행한 탄소세 도입을 실험하여 본 결과, 우리나라의 경우 소득의 척도로 이중배당 효과를 측정할 때, 두 경우 모두 약이중배당 효과가 발견되고 있다. 그러나 소비 척도로 측정한 이중배당 효과는 법인세 감경을 통한 조세중립적 탄소세 도입의 경우 이중배당 효과가 전혀 나타나지 않았으며, 고용으로 측정한 이중배당 효과는 법정복리비 감경을 통한 조세중립적 탄소세 도입을 할 경우 강이중배당 효과도 발견되었다.

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전기저항 측정과 음향방출을 이용한 표면 처리된 탄소 나노튜브와 나노 섬유 강화 에폭시 복합재료의 비파괴적 손상 감지능 (Nondestructive Damage Sensitivity for Functionalized Carbon Nanotube and Nanofiber/Epoxy Composites Using Electrical Resistance Measurement and Acoustic Emission)

  • Kim, Dae-Sik;Park, Joung-Man;Kim, Tae-Wook
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
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    • pp.42-45
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    • 2003
  • Nondestructive damage sensing and mechanical properties for acid-treated carbon nanotube (CNT) and nanofiber (CNF)/epoxy composites were investigated using electro-micromechanical technique and acoustic emission (AE). Carbon black (CB) was used to compare to CNT and CNF. The results were compared to the untreated case. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity under double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. For surface treatment case, the damage sensitivity and reinforcing effect were higher than those of the untreated case. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

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Effect of oxygen distribution for hot spot and carbon deposition minimization in a methane autothermal reforming reactor

  • Lee, Shin-Ku;Bae, Joong-Myeon;Kim, Yong-Min;Park, Joong-Uen;Lim, Sung-Kwang
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.1996-2000
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    • 2008
  • In autothermal reforming reaction, oxygen to carbon ratio (OCR) and steam to carbon ratio (SCR) are significant factors, which control temperature and carbon deposition into the reactor. The OCR is more sensitive than the SCR to affect the temperature distribution and reforming efficiency. In conventional operation, hydrocarbon fuel, steam, and oxygen was homogeneously mixed and injected into the reactor in order to get hydrogen-rich gas. The temperature was abruptly raised due to fast oxidation reaction in the former part of the reactor. Deactivation of packed catalysts can be accelerated there. In the present study, therefore, the effect of the oxygen distribution is introduced and investigated to suppress the carbon deposition and to maintain the reactor in the mild operating temperature (e.g., $700{\sim}800^{\circ}C$). In order to investigate the effect numerically, the following models are adopted; heterogeneous reaction model and two-medium model for heat balance.

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Effect of Conductive Additives on the Structural and Electrochemical Properties of Li4Ti5O12 Spinel

  • Park, Jae-Hwan;Lee, Seongsu;Kim, Sung-Soo;Kim, Jong-Huy
    • Bulletin of the Korean Chemical Society
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    • 제33권12호
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    • pp.4059-4062
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    • 2012
  • The effect of a conductive agent on the structural and electrochemical properties of $Li_4Ti_5O_{12}$(LTO) spinel was investigated through neutron diffraction during Li intercalation and electrochemical measurements. The charging process of LTO is known as transformation of the white $(Li_3)_{8a}[LiTi_5]_{16d}O_{12}$ into a dark-colored $(Li_{3-X})_{8a}[Li_{X+Y}]_{16c}[LiTi_5]_{16d}O_{12}$ by incorporating the inserted Li into octahedral 16c sites, and the Li in tetrahedral 8a sites shifted to 16c sites. The occupancy of the tetrahedral 8a site varied with the existence of carbon in the electrode. Without carbon, the lattice parameter and cell volume of LTO decreased more notably than in the carbon-containing LTO electrode during Li insertion process. These phenomena might be attributed that the Li occupancy of the tetrahedral 8a of the LTO electrode without carbon was less than that of the carbon-containing LTO electrode.

A simple quasi-3D sinusoidal shear deformation theory with stretching effect for carbon nanotube-reinforced composite beams resting on elastic foundation

  • Hadji, Lazreg;Zouatnia, Nafissa;Meziane, Mohamed Ait Amar;Kassoul, Amar
    • Earthquakes and Structures
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    • 제13권5호
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    • pp.509-518
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    • 2017
  • The objective of the present paper is to investigate the bending behavior with stretching effect of carbon nanotube-reinforced composite (CNTRC) beams. The beams resting on the Pasternak elastic foundation, including a shear layer and Winkler spring, are considered. The single-walled carbon nanotubes (SWCNTs) are aligned and distributed in polymeric matrix with different patterns of reinforcement. The material properties of the CNTRC beams are estimated by using the rule of mixture. The significant feature of this model is that, in addition to including the shear deformation effect and stretching effect it deals with only 4 unknowns without including a shear correction factor. The single-walled carbon nanotubes (SWCNTs) are aligned and distributed in polymeric matrix with different patterns of reinforcement. The material properties of the CNTRC beams are assessed by employing the rule of mixture. The equilibrium equations have been obtained using the principle of virtual displacements. The mathematical models provided in this paper are numerically validated by comparison with some available results. New results of bending analyses of CNTRC beams based on the present theory with stretching effect is presented and discussed in details. the effects of different parameters of the beam on the bending responses of CNTRC beam are discussed.