• 한국대기환경학회지
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• 제3권1호
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• pp.41-46
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• 1987

Adsorption and reaction studies were made for the catalytic oxidation in aqueous slurries of activated carbon at room temperature and atmospheric pressure. In order to analyze the reaction rate, the mechanism was assumed by the steps of nonhomogeneous catalytic reaction. The experimental result show that oxidation rate was controlled by the reaction between adsorbed molecular oxygen and sulfur dioxide on the catalyst surface. Ar room temperature, the equat5ion of reaction rate was given as $ro_2 = 2.49 \times 10^{-7} P_O_2^{0.604}$.

• 공업화학
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• 제34권3호
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• pp.313-317
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• 2023

본 연구에서는 이온교환 공정에서 사용된 제올라이트의 재이용을 위해 물리화학적 특성 분석 및 대기오염물질(VOCs, SO₂, CO₂) 흡착 성능을 평가하였다. SEM 및 XRD 분석을 통해 사용된 제올라이트의 표면 특성을 확인하였으며, XRF 분석을 통해 조성, BET 분석을 통해 비표면적을 측정하였다. 사용된 제올라이트의 표면 특성 변화는 없었지만 칼륨 및 칼슘의 함량이 증가하고 비표면적이 감소하였다. 사용된 제올라이트의 톨루엔, 황산화물, 이산화탄소 흡착 성능 평가를 수행하였으며, 기존 제올라이트 대비 성능이 증진됨을 확인하였다. 특히 톨루엔, 황산화물에 대해서는 흡착량이 각각 2.6배, 2.3배 증가하였다. 이는 사용된 제올라이트 조성 변화에 따라 각각 중합반응 증진, 염기점 증가에 의한 것으로 판단된다.

• 공업화학
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• 제23권4호
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• pp.383-387
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• 2012

This paper presents an easy way to prepare carbon dioxide sorbent by using commercially available fumed silica particles (AEROSIL). AEROSIL was impregnated with various concentration of polyethyleneimine (PEI) in methanol and $CO_2$ capture ability was analyzed by thermo gravity analysis (TGA). The $CO_2$ adsorption capacity of 50 wt% PEI-impregnated AEROSIL was 126.2 mg/g-sorbent at $75^{\circ}C$ and this capacity was substantially higher than that of the mesoporous silica such as HMS (101.0 mg/g-sorbent) and MSU-J (66.1 mg/g-sorbent).

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3749-3754
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• 2012

Nanoporous carbons with a high specific surface area were prepared directly from thermoplastic acrylic resin as carbon precursor and MgO powder as template by carbonization over the temperature range, $500-1000^{\circ}C$. The effect of the carbonization temperature on the pore structure and $CO_2$ adsorption capacity of the obtained porous carbon was examined. The textural properties and morphology of the porous carbon materials were analyzed by $N_2/-196^{\circ}C$ and $CO_2/0^{\circ}C$ adsorption/desorption isotherms, SEM and TEM. The $CO_2$ adsorption capacity of the prepared porous carbon was measured at $25^{\circ}C$ and 1 bar and 30 bar. The specific surface area increased from 237 to $1251m^2/g$, and the total pore volumes increased from 0.242 to $0.763cm^3/g$ with increasing the carbonization temperature. The carbonization temperature acts mainly by generating large narrow micropores and mesopores with an average pore size dependent on the level of carbonization of the MgO-templated nanoporous carbons. The results showed that the MgO-templated nanoporous carbons at $900^{\circ}C$ exhibited the best $CO_2$ adsorption value of 194 mg/g at 1 bar.

• 한국응용과학기술학회지
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• 제32권3호
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• pp.578-582
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• 2015

In this study, We evaluated the efficiency of the smart ventilation system being developed at the test-bed(KCL). Smart ventilation system improve the indoor air quality by absorbing carbon dioxide. It is reducing the infusion of outside air can be reduced to minimum energy consumption. To evaluate the energy savings and carbon dioxide removal efficiency. It was more effective when working with air conditioning and ventilation system at the same time.

• Carbon letters
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• 제12권1호
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• pp.44-47
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• 2011

Activated carbon fibers (ACFs) were prepared from cost effective commercial textiles through stabilization, carbonization, and subsequently activation by carbon dioxide. ACFs were characterized for surface area and pore size distribution by physical adsorption of nitrogen at 77 K. ACFs were also examined for various surface characteristics by scanning electron microscopy, Fourier transform infrared spectroscopy, and CHNO elemental analyzer. The prepared ACFs exhibited good surface textural properties with well developed micro porous structure. With improvement in physical strength, the commercial textile grade acrylic precursor based ACFs developed in this study may have great utility as cost effective adsorbents in environmental remediation applications.

• 한국건설순환자원학회논문집
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• 제11권4호
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• pp.299-306
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• 2023

현무암폐석을 활용한 투수믈록의 성능을 평가하기 위해 현무암폐석의 치환율을 0, 20, 40, 60 (%) 4가지 수준으로 변화시켜 시멘트 및 무시멘트 기반의 투수블록을 제작하여 휨강도, 압축강도, 투수 계수, 흡수율, 밀도, 이산화탄소 저감, 미세먼지 저감 등에 대하여 평가하였다. 그 결과, 휨강도, 압축강도와 밀도는 현무암 폐석의 치환율이 증가함에 따라 감소하였지만 치환율 20 %에서 휨강도가 KS규격에 만족하는 결과값을 보였다. 흡수율, 투수계수, 이산화탄소 저감. 미세먼지 저감 등은 현무암 폐석의 치환율이 증가함에 따라 증가하는 경향을 보였으며, 투수계수는 모든 치환율에서 KS규격을 만족하는 결과를 나타내었고 미세먼지, 이산화탄소 저감과 흡수율은 모든 치환율에서 높은 값을 나타났다. 따라서 시멘트를 사용하지 않아 시멘트 생산과정에서 바생하는 이산화탄소량을 감소시킬 수 있는 무시멘트 기반 투수블록에서 중요한 지표인 투수계수가 KS규격을 만족하였고 공기질 오염물질 저감 성능이 뛰어나기 때문에 휨강도 기준을 만족하는 현무암 폐석 치환율 20 % 내에서 활용한다면 기존의 투수블록이 가지고 있는 문제점을 해결할 수 있는 방안으로 사용할 수 있을 것으로 판단된다.

• 공업화학
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• 제27권1호
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• pp.80-85
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• 2016

넓은 비표면적과 큰 기공 부피를 갖는 실리카에 다양한 아미노실란 화합물을 in-situ 중합법을 통해 기능화 후 이산화탄소 흡착 특성을 확인하였다. 이산화탄소 흡착 기능기로 아민기가 포함된 아미노실란 화합물이 사용되었다. 흡착제의 흡착 특성 분석을 위해 질소 흡 탈착 실험과 원소분석, in situ FT-IR, TGA를 이용하였다. 흡착제 합성 전후를 비교하였을 때 폴리아미노실란이 기능화되면 표면적과 기공부피 및 크기가 감소하였으며 실리카 기공 부피의 70%에 해당하는 폴리아미노실란 화합물을 기능화 시켰을 경우 기공 부피의 100% 기능화 보다 이산화탄소 흡착능이 향상되었다. 흡착 온도를 비교하며 $30^{\circ}C$보다 $75^{\circ}C$에서 폴리아미노실란 화합물의 열팽창과 자유부피 증가로 흡착능이 증가하였고, 2NS/NPS-2의 경우 기공 부피 70% 기능화와 흡착 온도 $75^{\circ}C$에서 9.2 wt%의 높은 $CO_2$ 흡착능을 보였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.93-94
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• 2023

Through the industrial revolution that began in the 18th century, the amount of carbon dioxide in the atmosphere increased rapidly as humans used fossil energy such as coal and oil as fuel for steam engines and factory machines. The amount of carbon dioxide emitted while producing cement, the main material of concrete used in construction, is large enough to account for 5-8% of the world's carbon dioxide emissions. In this study, Non cement-based matrix were used to reduce carbon dioxide emissions from cement production. Red mud is an industrial by-product generated in the manufacturing process of aluminum hydroxide using bauxite, and more than 120 million tons are produced worldwide. In addition, red mud is a porous material that can be physically adsorbed, and causes a photocatalytic reaction of TiO₂ to remove harmful substances such as nitrogen oxide formaldehyde in the air and chemically adsorbs ammonia and hydrogen sulfide. Therefore, this study aims to examine the physical properties of the matrix by mixing red mud, an industrial by-product with good adsorption performance, into the Non cement-based matrix.

• Carbon letters
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• 제6권4호
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• pp.227-233
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• 2005

Carbonization products C1, C2, C3, C4 and C5 were prepared by the carbonization of date pit in limited air, at 500, 600, 700, 800 and $1000^{\circ}C$, respectively. C1-V-600, C3-V-600, C1-V-1000 and C3-V-1000 were prepared by thermal treatment of C1 and C3 under vacuum at 600 and $1000^{\circ}C$. The textural properties were determined from nitrogen adsorption at 77 K and from carbon dioxide adsorption at 298 K. The surface pH, the FTIR spectra and the acid and base neutralization capacities of some carbons were investigated. The amounts of surface oxygen were determined by out-gassing the carbon-oxygen groups on the surface as $CO_2$ and CO. The adsorption of water vapor at 308 K on C1, C2, C3 and C4 was measured and the decomposition of $H_2O_2$ at 308 K was also investigated on C1, C2, C3, C4 and C5. The surface area and the total pore volume decreased with the rise of the carbonization temperature from 500 to $1000^{\circ}C$. The adsorption of water vapor is independent on the textural properties, while it is related to the amount of acidic carbon-oxygen groups on the surface. The catalytic activity of $H_2O_2$ decomposition does not depend on the textural properties, but directly related to the amount of basic carbon-oxygen complexes out-gassed as CO, at high temperatures.