• Title/Summary/Keyword: carbon density

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Optimization of Microbial Electrosynthesis Using Rhodobacter sphaeroides for CO2 Upcycling (CO2 고부가화를 위한 로도박터 스페로이데스를 활용한 미생물 전기합성 최적화 연구)

  • Hui Su Kim;Hwi Jong Jung;Danbee Kim;Samgmin Lee;Jiye Lee;Jin-Suk Lee;Myounghoon Moon;Chang Hyun Ko;Soo Youn Lee
    • New & Renewable Energy
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    • v.19 no.4
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    • pp.20-26
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    • 2023
  • Emitted CO2 is an attractive material for microbial electrochemical CO2 reduction. Microbial electrochemical CO2 reduction (i.e., microbial electrosynthesis, MES) using biocatalysts has advantages compared to conventional CO2 reduction using electrocatalysts. However, MES has several challenges, including electrode performance, biocatalysts, and reactor optimization. In this study, an MES system was investigated for optimizing reactor types, counter electrode materials, and CO2-converting microorganisms to achieve effective CO2 upcycling. In autotrophic cultivation (supplementation of CO2 and H2), CO2 consumption of Rhodobacter sphaeroides was observed to be four times higher than that with heterotrophic cultivation (supplementation of succinic acid). The bacterial growth in an MES reactor with a single-chambered shape was two times higher than that with a double chamber (H-type MES reactor). Moreover, a single-chambered MES reactor equipped with titanium mesh as the counter electrode (anode) showed markedly increased current density in the graphite felt as a working electrode (cathode) compared to that with a graphite felt counter electrode (anode). These results demonstrate that the optimized conditions of a single chamber and titanium mesh for the counter electrode have a positive effect on microbial electrochemical CO2 reduction.

Characteristics of Harmful Cyanobacteria Occurrence and Toxin Residual in Agricultural Reservoirs of Southern Gyeonggi (경기남부권 농업용 저수지의 유해 남세균 발생 및 독소물질 잔류 특성)

  • Kim Minju;Kim Young-Kee
    • Journal of Korean Society on Water Environment
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    • v.40 no.1
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    • pp.1-10
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    • 2024
  • Algal blooms occur seasonally in the eutrophicated rivers or reservoirs, and some harmful cyanobacteria species produce toxic substances, which are directly or indirectly harmful to the ecosystem and terrestrial animals. So, the monitoring and control of harmful cyanobacteria occurrence and toxins residual in the aquasystem are important to preserve the water environment and secure public health. In this study, the four harmful cyanobacteria occurrences and toxic substance concentrations of two agricultural reservoirs in the southern part of Gyeonggi Province were investigated from August to October 2022. Among four harmful cyanobacteria (Microcystis sp., Anabaena sp., Oscillatoria sp., Aphanizomenon sp.), three kinds of cyanobacteria except Oscillatoria sp. were observed, and Microcystis sp. was the dominant cyanobacteria except for Anabaena sp. dominant result of a sample collected on October at reservoir B. The cell density of cyanobacteria was influenced by season and weather due to the length of daytime and concentrations of organic carbon and nitrogen. Three kinds of microcystin and anatoxin-a were quantitatively analyzed as total (in the cell body and water) and extracellular (in water) concentrations. The maximum total concentrations of anatoxin-a, microcystin-LR, microcystin-RR, and microcystin-YR were 0.1291 ㎍/L, 0.2776 ㎍/L, 0.3721 ㎍/L, and 0.0306 ㎍/L, respectively, in reservoir A and 0.3274 ㎍/L, 0.1495 ㎍/L, 0.2037 ㎍/L, and 0.0153 ㎍/L, respectively, in reservoir B.

The Study of Physico-chemcal Characteristics of Municipal Solid Waste (MSW) in Gangwon Area (강원지역 도시폐기물의 물리·화학적 특성 연구)

  • Lee, Keon-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.2
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    • pp.101-111
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    • 2009
  • In this study, the physico-chemical characteristics of municipal solid waste (MWS) which was treated in gangwon area were investigated. It is necessary to measure the characteristics of municipal solid waste for build a waste treatment and RDF facility and for data-base and total managing of the landfill. It was found that the average density of solid wastes is in the range of $101.8{\sim}199.8kg/m^3$. This MSW was composed of 30.7% of food wastes, 36.3% of papers, 15.8% of plastics & vinyls, 1.9% of textiles, 3.2% of wood and 1.5% of rubber & leathers respectively. Most of MSW are composed of food, paper and plastic waste and the combustible waste is more than 90%. For three components, moisture is 44.6%, combustible component is 47.7% and ash is 7.7% respectively. The chemical elements are carbon, oxygen, and hydrogen on the dry basis of wastes. The low heating value of the MSW measured by calorimeter was obtained as 2,631 kcal/kg, and the high heating value of the MSW was obtained as 3,310 kcal/kg.

Effect of Functionalized BR Content on the Wear Particulate Matters and Physical Properties in TBR Tire Tread Compounds

  • Junhwan Jeong;Sanghoon Song;Jin Uk Ha;Daedong Park;Jaeyun Kim;Yeongmin Jung;Donghyuk Kim;Kiwon Hwang;Sungwook Chung;Wonho Kim
    • Elastomers and Composites
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    • v.59 no.2
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    • pp.64-72
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    • 2024
  • As air pollution continues to increase owing to increasing traffic centered in urban areas, the tire industry is researching methods to reduce particulate matter. In this study, functionalized lithium butadiene rubber (F-LiBR) was applied to a natural rubber (NR)/butadiene rubber (BR) blend compound often used in truck bus radial (TBR) tire treads. The effect of the functional group that can react with carbon black (CB) in BR was investigated in terms of the dispersion of CB and the compound performance, including the generation of particulate matter. Compounds that were substituted with F-LiBR exhibited enhanced interaction with CB, resulting in excellent filler dispersion. Although F-LiBR exhibited lower crosslinking density and inferior abrasion resistance due to its high vinyl content, the compound with 30 phr of F-LiBR was advantageous in terms of its rolling resistance due to the excellent filler dispersion, which was also effective in reducing the amount of generated particulate matter (up to 56% reduction for PM2.5, and 67% reduction for PM10). The results confirmed the benefits of the introduction of functional groups into TBR tire tread compounds, which can aid in improving the fuel efficiency and reducing particulate matter generation.

The evaluation for the usability ofthe Varian Standard Couch modelingusing Treatment Planning System (치료계획 시스템을 이용한 Varian Standard Couch 모델링의 유용성 평가)

  • Yang, yong mo;Song, yong min;Kim, jin man;Choi, ji min;Choi, byeung gi
    • The Journal of Korean Society for Radiation Therapy
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    • v.28 no.1
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    • pp.77-86
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    • 2016
  • Purpose : When a radiation treatment, there is an attenuation by Carbon Fiber Couch. In this study, we tried to evaluate the usability of the Varian Standard Couch(VSC) by modeling with Treatment Planning System (TPS) Materials and Methods : VSC was scanned by CBCT(Cone Beam Computed Tomography) of the Linac(Clinac IX, VARIAN, USA), following the three conditions of VSC, Side Rail OutGrid(SROG), Side Rail InGrid(SRIG), Side Rail In OutSpine Down Bar(SRIOS). After scan, the data was transferred to TPS and modeled by contouring Side Rail, Side Bar Upper, Side Bar Lower, Spine Down Bar automatically. We scanned the Cheese Phantom(Middelton, USA) using Computed Tomography(Light Speed RT 16, GE, USA) and transfer the data to TPS, and apply VSC modeled previously with TPS to it. Dose was measured at the isocenter of Ion Chamber(A1SL, Standard imaging, USA) in Cheese Phantom using 4 and 10 MV radiation for every $5^{\circ}$ gantry angle in a different filed size($3{\times}3cm^2$, $10{\times}10cm^2$) without any change of MU(=100), and then we compared the calculated dose and measured dose. Also we included dose at the $127^{\circ}$ in SRIG to compare the attenuation by Side Bar Upper. Results : The density of VSC by CBCT in TPS was $0.9g/cm^3$, and in the case of Spine Down Bar, it was $0.7g/cm^3$. The radiation was attenuated by 17.49%, 16.49%, 8.54%, and 7.59% at the Side Rail, Side Bar Upper, Side Bar Lower, and Spine Down Bar. For the accuracy of modeling, calculated dose and measured dose were compared. The average error was 1.13% and the maximum error was 1.98% at the $170^{\circ}beam$ crossing the Spine Down Bar. Conclusion : To evaluate the usability for the VSC modeled by TPS, the maximum error was 1.98% as a result of compassion between calculated dose and measured dose. We found out that VSC modeling helped expect the dose, so we think that it will be helpful for the more accurate treatment.

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Distribution and Favorable Conditions for Mycelial Growth of Cordyceps pruinosa in Korea (한국에 자생하는 붉은자루동충하초(Cordyceps pruinosa)의 분포와 균사생장에 적합한 조건)

  • Shin, Jae-Chul;Shrestha, Bhushan;Lee, Won-Ho;Park, Young-Jin;Kim, Soo-Young;Jeong, Gwang-Ryel;Kim, Ho-Kyung;Kim, Tae-Woong;Sung, Jae-Mo
    • The Korean Journal of Mycology
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    • v.32 no.2
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    • pp.79-88
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    • 2004
  • Cordyceps pruinosa grows upon dead pupae of Lepidoptera and produces one or $3{\sim}4$ club-shaped stromata per host. The stromata have distinct club-shaped head and long stalk. The length of stromata varies from $1{\sim}3\;cm$. Apical head consists of densely crowded semi-immersed perithecia, which are $360{\sim}400\;{\times}\;180{\sim}200\;{\mu}m$ in size. Asci are $150\;{\mu}m$ in length and $2.8{\sim}3\;{\mu}m$ in diameter. Ascospores, which are $124{\sim}141\;{\mu}m$ in length, have thin thread-like structures in the middle with part-spores attached on both sides. Each ascospore does not separate into part-spores after dispersal, but each part-spore germinates and together develops a colony. The imperfect form produces phialides of $15{\sim}24\;{\times}\;2{\sim}3\;{\mu}m$ size, with spherical or spindle shaped conidia of $4{\sim}6\;{\times}\;1.8{\sim}2.4\;{\mu}m$ size, The anamorph was identified as Mariannaea elegans Samson. YMA and SDAY agar media with pH 7 was produced abundant mycelial growth with high density. Best mycelial growth was observed when dextrin was used as a carbon source. Lactose, saccharose and sucrose also produced high mycelial growth. Peptone, yeast extract and tryptone produced abundant mycelial growth, when used as nitrogen sources. Highest mycelial growth and density was observed when C/N ratio was 1 : 1 at the concentration of 12.5 g/l each. $KH_2PO_4$ was the best mineral source for mycelial growth. Highest mycelial dry wt. was produced in YM and SDAY broths. Optimum inoculum for 100 ml of liquid broth was 6 mycelial discs. Similarly, optimum liquid culture period was 7 days.

Responses of Native Trees Species in Korea under Elevated Carbon Dioxide Condition - Open Top Chamber Experiment (상부 개방형 온실을 이용한 대기 중 이산화탄소 농도 증가가 우리나라 자생 수종에 미치는 형태적, 생리적 영향)

  • Ryu, Daun;Bae, Jinho;Park, Juhan;Cho, Sungsik;Moon, Minkyu;Oh, Chang-Young;Kim, Hyun Seok
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.16 no.3
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    • pp.199-212
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    • 2014
  • The physiological responses of three common temperate species, Pinus densiflora, Fraxinus rhynchophylla, Sorbus alnifolia to elevated $CO_2$ was investigated using open top chambers with different $CO_2$ concentrations. Morphological (stomatal size, density and area) and physiological characteristics (maximum rates of photosynthesis, carboxylation and electron transport) were compared among trees grown under ambient, ambient ${\times}1.4$ (~550 ppm) and ambient ${\times}1.8$ (~700 ppm) $CO_2$ concentrations for last four years. Morphological responses were different among species. F. rhynchophyllar increased their stomatal size and S. alnifolia had higher stomatal density under elevated $CO_2$ than ambient. Stomatal area decreased in P. densiflora, whereas it increased in S. alnifolia. However, the maximum photosynthesis rate increased in all species up to 43.5% by S. alnifolia under elevated $CO_2$ and the enhancement increased with time. Even with four years of exposure to elevated $CO_2$, there was no sign of acclimation in the maximum carboxylation rate and the maximum electron transport rates in all species. Especially, S. alnifolia even showed the temporary increase of photosynthetic capacities in spring, when leaf nitrogen concentration was high with new leaf development. There was no significant differences in diameter growth rate in any species due to high variation in their tree sizes, however accumulated diameter and biomass for four years showed significantly increment in all species under elevated $CO_2$. For example, S. alnifolia showed 59% increase in diameter at the ambient ${\times}1.8$ (~700 ppm) compared to ambient.

Soil Physical and Chemical Properties of Kaolinite Opencast Mines and Adjacent Red Pine Forests in Sancheong-gun (산청군 고령토(백토) 노천 광산 채굴지와 인접 소나무 임분의 토양 물리·화학적 성질)

  • Kim, Kyung Tae;Baek, Gyeongwon;Choi, Byeonggil;Ha, Jiseok;Kim, Choonsig
    • Journal of Korean Society of Forest Science
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    • v.109 no.4
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    • pp.382-389
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    • 2020
  • Soil properties in opencast mines are a key factor in reclamation (revegetation) of mining areas. In this study we determined the soil physical and chemical properties of kaolinite tailings, reclaimed areas, and adjacent natural red pine (Pinus densiflora S. et Z.) forests in kaolinite opencast mines in Sancheong-gun, Gyeongsangnam-do. Six sites were chosen for collection of soil samples to determine soil physical and chemical properties at a soil depth of 10 cm. Soil bulk density was significantly higher (P < 0.05) in the kaolinite tailings (1.51 g·cm-3) than in the reclaimed areas (1.19 g·cm-3) and red pine forests (0.93 g·cm-3), whereas air phase in the kaolinite tailings (14.2%) was significantly lower than in the red pine forests (32.6%). Clay content in the red pine forests was significantly higher than in the reclaimed areas (18.7%) or kaolinite tailings (14.8%), whereas soil structural stability index was significantly lower in the reclaimed areas (1.61%) and kaolinite tailings (0.87%) than in the red pine forests (7.75%). Soil pH was significantly higher in the kaolinite tailings (pH 6.68) and reclaimed areas (pH 6.27) than in the red pine forests (pH 5.31). Soil organic carbon and total nitrogen were significantly higher in the red pine forests (C: 36.03 mg·g-1; N: 2.08 mg·g-1) than in the reclaimed areas (C: 5.00 mg·g-1; N: 0.31 mg·g-1) than in the kaolinite tailings (C: 2.12 mg·g-1; N: 0.07 mg g-1). The amount of available phosphorus was not significantly different among the three treatments. The concentration of exchangeable potassium was significantly lower in the kaolinite tailings (0.08 cmolc·kg-1) than in the reclaimed areas (0.21 cmolc·kg-1) and red pine forests (0.30 cmolc·kg-1). These results indicate that, because of high soil bulk density and low soil organic carbon, total nitrogen, available phosphorus, and exchangeable potassium in kaolinite tailings and reclaimed mining areas, soil nutrient management is needed in order to reclaim the vegetation in these type of areas.

A Comparision Study of LDPE Pyrolysis over Resin Additives and Inorganic Compounds of Silica Alumina Type (수지첨가제와 실리카알루미나 계열 무기물이 LDPE 수지의 열분해에 미치는 영향 비교 연구)

  • Bak, Young-Cheol;Choi, Joo-Hong;Kim, Nam-Kyung
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.596-602
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    • 2006
  • The effects of resin additives and inorganic compounds addition on the thermal decomposition of low density polyethylene(LDPE) resin have been studied in a thermal analyzer(TGA, DSC) and a small batch reactor. The silica-alumina type compounds tested were kaolinite, bentonite, perlite, diatomaceous earth, activated clay and clay. The resin additives were antiforgging-agent and longevity-agent. As the results of TGA experiments, addition of antifogging-agent, longevity-agent and clay increased the temperature of the maximum reaction rate($T_{max}$). The silica-alumina type inorganic materials increased the pyrolysis reraction rate in the order of activated clay, diatomaceous earth, bentonite, perlites, and kaolinite. In the DSC experiments, addition of antifogging-agent and clay decreased the heat of fusion and the heat of pyrolysis reaction. Bentonite decreased 20% of the heat of fusion and 25% of the heat of pyrolysis reaction. In the batch system experiments, the mixing of clay retarded the initial producing rate of fuel oil, but increased the yield of fuel oil. Addition of bentonite increased the yield of fuel oil from LDPE resin. Mixing of antifogging-agent and longevity-agent produced the fuel oil having lower carbon number. The amounts of the carbon number below 12 in fuel oil decreased with adding the clay. That below 23 in fuel oil increased with mixing of bentonite, perlite, kaolinite, and activated clay. But the mixing of diatomaceous earth did not affect the carbon contents of fuel oil from pure LDPE resin. In the silica-alumina type inorganic material used in this experiments, bentonite was the most effective from the pyrolysis heat, yields, and the characteristics of fuel oil.

Carbon Storage of Natural Pine and Oak Pure and Mixed Forests in Hoengseong, Kangwon (횡성지역 천연 소나무와 참나무류 순림 및 혼효임분의 탄소 저장량 추정)

  • Lee, Sue Kyoung;Son, Yowhan;Noh, Nam Jin;Heo, Su Jin;Yoon, Tae Kyung;Lee, Ah Reum;Sarah, Abdul Razak;Lee, Woo Kyun
    • Journal of Korean Society of Forest Science
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    • v.98 no.6
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    • pp.772-779
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    • 2009
  • This study was conducted to estimate the carbon (C) contents in pure and mixed stands of pine (Pinus densiflora) and oak (Quercus spp.) trees for establishing the C inventory of forest ecosystems. A total of fifteen 20 m${\times}$20 m pure and mixed stands of pine and oak trees were chosen in natural forests in Hoengseong, Kangwon based on the basal area of all trees ${\geq}$ 5 cm DBH: three of 95% of pine and 5% oak trees [pine stand], three of 100% of oak trees [oak stand], and nine of 20 to 70% of pine and 80 to 30% of oak trees [mixed stand]. To estimate C contents in the study stands, biomass in vegetation, forest floor and coarse woody debris (CWD) were calculated and C concentrations in vegetation, forest floor, CWD and soil (0-30 cm) were analyzed. There was no significant difference in vegetation C contents among the stands; 147.6 Mg C/ha for the oak stand, 141.4 Mg C/ha for the pine stand and 115.8 Mg C/ha for the mixed stand. Forest floor C contents were significantly different among the stands (p<0.05); 12.7 Mg/ha for the pine stand, 9.9 Mg/ha for the oak stand, and 8.4 Mg/ha for the mixed stand. However, CWD C contents were not significantly different among the stands (p>0.05); 2.2 Mg/ha for the mixed stand, 1.7 Mg/ha for the oak stand, and 1.1 Mg/ha for the pine stand. Soil C contents up to 30 cm depth were not significantly different among the study stands; 44.4 Mg C/ha for the pine stand, 41.6 Mg C/ha for the mixed stand, and 33.3 Mg C/ha for the oak stand. Total ecosystem C contents were lower in the mixed stand than those in the pure stands, because vegetation C contents which occupied almost total ecosystem C contents were lower in the mixed stand than those in the pure stands; 199.6 Mg C/ha for the pine stand, 192.5 Mg C/ha for the oak stand and 169.1 Mg C/ha for the mixed stand. Lower vegetation C contents in the mixed stand might be influenced by interspecific competition between pine and oak trees and intraspecific competition among the oak trees resulted from high stand density. We suggest that forest management such as thinning to enhance C storage is indispensible for minimizing the competition in forest ecosystems.