• 공업화학
• /
• 제8권5호
• /
• pp.860-865
• /
• 1997

건강식품으로 각광받고 있는 현미유는 palmitic acid, linolenic acid, linoleic acid, oleic acid, stearic acid, tocopherol, squalene 등을 포함하고 있다. 본 연구에서는 국내산 현미겨로부터 초입계 이산화탄소를 이용하여 현미유를 추출하고, GC-MSD를 이용하여 조성을 분석하였다. 현미유의 추출량은 추출공정의 조작온도와 압력에 의존하였으며, 초임계 이산화탄소의 환산밀도에 따라 추출된 기름내 지방산의 조성이 변화되었다. 또한 70~80%의 기름이 4시간 정도의 조작시간내에 추출됨이 확인되었다. 특히 용매추출공정과 초임계유체 추출공정을 비교한 결과 초임계유체 추출공정에서 추출된 기름의 조성에서만 squalene이 포함되어 있음이 확인되었다.

• Journal of Electrochemical Science and Technology
• /
• 제6권3호
• /
• pp.95-105
• /
• 2015

In the present work, Carbon supported Pt₁₀₀, Pt₈₀Sn₂₀, Pt₈₀Ni₂₀ and Pt₈₀Sn₁₀Ni₁₀ electrocatalysts with different atomic ratios were prepared by ethylene glycol-reduction method to study the electro-oxidation of ethanol in membraneless fuel cell. The electrocatalysts were characterized in terms of structure, morphology and composition by using XRD, TEM and EDX techniques. Transmission electron microscopy measurements revealed a decrease in the mean particle size of the catalysts for the ternary compositions. The electrocatalytic activities of Pt₁₀₀/C, Pt₈₀Sn₂₀/C, Pt₈₀Ni₂₀/C and Pt₈₀Sn₁₀Ni₁₀/C catalysts for ethanol oxidation in an acid medium were investigated by cyclic voltammetry (CV) and chronoamperometry (CA). The electrochemical results showed that addition of Ni to Pt/C and Pt-Sn/C catalysts significantly shifted the onset of ethanol and CO oxidations toward lower potentials. The single membraneless ethanol fuel cell performances of the Pt₈₀Sn₁₀Ni₁₀/C, Pt₈₀Sn₂₀/C and Pt₈₀Ni₂₀/C anode catalysts were evaluated at room temperature. Among the catalysts investigated, the power density obtained for Pt₈₀Sn₁₀Ni₁₀/C (37.77 mW/cm² ) catalyst was higher than that of Pt₈₀Sn₂₀/C (22.89 mW/cm² ) and Pt₈₀Ni₂₀/C (16.77 mW/ cm² ), using 1.0 M ethanol + 0.5 M H₂SO₄ as anode feed and 0.1 M sodium percarbonate + 0.5 M H₂SO₄ as cathode feed.

• KSBB Journal
• /
• 제11권2호
• /
• pp.125-131
• /
• 1996

Bacillus amyloliquefacieus 01용한 회분식 배양시 탄소원인 maltose와 glucose에서 저해제 acetic a acid, lactic acid가 세포성장과 생성물 생성에 미치 는 영향에 대해 검토한 결과, acetic acid가 저해제 로 작용함을 확인하였고, acetic acid 첨가시 초기농 도가 증가할수록 세포성장은 현저하게 감소되었다. ${\alpha}$-Amylase 생성 최대치는 maltose $10g/\ell$ 의 경우 a acetic acid 초기농도 $0.5g/\ell$ 일때 24시간 배양시에 l25unit/ml로 가장 높았고, glucose $10g/\ell$ 의 경우 acetic acid 초기놓도 $2.0g/\ell$ 일때 20시간 배양시에 331.55unit/ml로 가장 높았다. Acetic acid 초기농 도가 과량 일때는 세포의 성장이 최저 상태이고, ${\alpha}$-amylase 생성도 급격히 감소하였다. 저해제로 ace­t tic acid 첨가시 탄소원인 maltose와 glucose를 비 교하면 glucose에서 maltose 보다는 세포가 더 성장되었고, ${\alpha}$-amylase의 생성도 더 많게 나타났으며, 두 가지 탄소원에 다같이 저해 작용을 나타냈다.

• Composites Research
• /
• 제33권5호
• /
• pp.282-287
• /
• 2020

본 연구에서는 저 융점 폴리에틸렌 테레프탈레이트(PET) 섬유(Low melting PET fiber: LMF)가 복합화된 PET 시트의 고밀도화 공정을 통해 고강도 PET 시트를 제조하였다. 복합화된 LMF는 열처리 과정에서 용융되어 개개의 PET 섬유를 연결해 섬유간의 계면결합력을 향상시켰다. 또한 PET시트의 고밀도화는 거대기공밀도를 감소시키고 중첩된 PET 네트워크간의 결합력을 향상시켜 결과적으로 압축 전 LMF-PET 시트와 비교하여 연신율은 유지하면서 약 410% 향상된 인장강도를 보여주었다. 또한 강화된 결합력은 PET 섬유 네트워크의 수축을 방지하여 우수한 치수안정성을 나타내었다.

• Journal of Biosystems Engineering
• /
• 제37권1호
• /
• pp.44-50
• /
• 2012

Purpose: The characteristics of in-transit vibration stress and possible damage to packaged apples were examined. Methods: A simulated transportation environment with a specific power density profile was used for vibration impact experiments to determine the resulting decrease in packaged apple quality. Apples with or without vibration stress were stored at low temperature ($5{\pm}0.8^{\circ}C$, 75-85% relative humidity) for 30 days. Statistically significant differences (p ${\leq}$ 0.05) were found between apples with and without vibration stress for concentration of oxygen ($O_2$; 11.2% and 14.1%, respectively; initially $29{\pm}0.4%$), carbon dioxide ($CO_2$; 26.4% and 21.8%; initially $1{\pm}0.2%$), and ethylene (79.4 ${\mu}LL^{-1}$ and 55.6 ${\mu}LL^{-1}$; initially $14.1{\pm}0.6{\mu}LL^{-1}$) in the headspace of a gas-collecting container after 30 days of storage. Results: Significant differences were also measured for apples with and without vibration stress with respect to soluble solid content (15.4% and 14.9%, respectively; initially $12.9{\pm}0.8%$ and $13.1{\pm}1.1%$), weight loss (10.1% and 8.2%), and firmness (139.7 kPa and 163.3 kPa; initially $213.8{\pm}6.2$ kPa and $209.1{\pm}7.9$ kPa) after 30 days of storage. Conclusions: The vibration stress clearly accelerated the degradation of apple quality during storage, resulting in increased weight loss, soluble solid content, and headspace $CO_2$ and ethylene production, and decreased firmness and headspace $O_2$.

• 한국자동차공학회논문집
• /
• 제22권5호
• /
• pp.59-65
• /
• 2014

Diesel engines have the superior combustion efficiency and fuel economy that they are widely used for industry, heavyduty vehicles, etc. However, its exhaust emissions have become the major concerns due to their environmental impacts. Moreover, the depletion of fossil fuels is the main issue. Therefore, it is important to look for alternative sources of energy. Bio-diesel is one of the ideal energy which has proved to be ecofriendly for more than fossil fuels. The experimental tests analysed the engine performance and emission characteristics of a diesel engine using diesel and biodiesel blended of BD25, BD45 and BD65, in order to study the use of clean fuel to meet the increasingly stringent emission regulations. The engine performance was examined by using engine dynamometer while an exhaust gas analyzer was used to examine the emission characteristics. The effect of biodiesel on engine performance were lower to diesel through comparing their HP and torque but fuel consumption was slightly increased because of biodiesel has lower heating value and higher density than diesel. However, due to the better lubricity, the brake thermal efficiency of biodiesel was higher than diesel. The emission characteristics were strongly affected by the blending ratio of diesel and biodiesel. The results showed that the smoke opacity, hydrocarbons (HC) and carbon monoxide (CO) emissions decreased while the nitrogen oxides (NOX) slightly increased.

• 한국미생물·생명공학회지
• /
• 제21권4호
• /
• pp.354-365
• /
• 1993

A novel control method with automatic tuning of PID controller parameters has been developed for efficient regulation of dissolved oxygen concentration in fed-batch fermentations of Escherichia coli. Agitation speed and oxygen partial pressure in the inlet gas stream were chosen to be the manipulated variables. A heuristic reasoning allowed improved tuning decisions from the supervision of control performance indices and it coule obviate the needs for process assumptions or disturbance patterns. The control input consisted of feedback and feedforword parts. The feedback part was determined by PID control and the feedforward part is determined from the feed rate. The proportional gain was updated on-line by a set of heuristics rules based on the supervision of three performance indices. These indices were output error covariance, the average value of output error, and input covariance, which were calculated on-line using a moving window. The integral and derivative time constants were determined from the period of output response. The specific growth rate was maintained at a low level to avoid acetic acid accumulation and thus to achieve a high cell density. The specific growthe rate was estimated from the carbon dioxide evolution rate. In fed-batch fermentation, the simutaneous control of dissolved oxygen concentration (at 0.2; fraction of saturated value) and specific growth rate (at 0.25$hr^{-1}$) was satisfactory for the entire culture period in spite of the changes in the feed rate and the switching of control input.

• 상하수도학회지
• /
• 제12권2호
• /
• pp.31-41
• /
• 1998

As the leakage of crude oil from tankers breaks out frequently, it caused a serious problem for ocean pollution and calls for developing treatments to handle the leaked crude oil and mitigate the pollution. Thus it is required to develop new purification technolgies and appropriate treatment systems which have sufficient treatment capability in order to cope with the anticipated ocean pollution. In this experiment, A and B type heavy oils were used to make the emulsion of both water containing heavy oil and sea-water containing heavy oil. The following are the main results from this study ; 1. When A and B type heavy oils were added to the original sea-water and treatedin the homogrenizer respectively, the particle of oil beacame smaller in both cases. Under the same condition, while the initial oil density of sea-water containing B-heavy oil is higher than of emulsion with A-heavy oil, the particle of A-heavy oil is finer than that of B-heavy oil. 2. When A and B type heavy oils were added to distilled water and treated in the homogenizer respectively, the particle was more dispersed and finer than that in the case of sea-water in both cases. In this result, the water containing oil formed more stable emulsion than the sea-water containing oil. 3. In this experiment, all emulsions showed oil in water types. 4. Since the oil particle is larger in the sea-water than in the distillated water, interms of elimination of oil, it is thought to be more important to give Membrane treatment after implementing sandfilter, activity carbon, coagulation-sedimentation and floating separation as pre-treatment.

• 펄프종이기술
• /
• 제48권1호
• /
• pp.127-133
• /
• 2016

This study is performed that furniture and interior materials of MDF's (Medium Density Fiberboard) biodegradation properties, and the goal of this study is investigation of possibility of waste-MDF's composting after landfilling. To investigate biodegradation, this study was performed according to KS M ISO 14855-1, and there were two different soil conditions including a compost condition and an activated vermiculite condition as artificial soil. This experiment was tested for 40 days. The measurement of carbon-dioxide generation was processed every 24 hour in 1-2 week, and every 48 hour after 3 week. In the same days, MDF showed 24.4% of biodegradation in compost condition, and 6.2% in activated vermiculite. Also, the reference material of TLC (thin-layer chromatography) grade cellulose showed 26.4%, 11.4% in compost and activated vermiculite respectively. The dilution plate method was performed for biological analysis in the study. This experiment was used for investigation of inoculum's (Bacillus licheniformis) activity. As the result of bioassay, compost has more other germs include inoculum than activated vermiculite in the first week. Especially in the 2nd week, the reference material under the compost condition showed the most germ's activity, and also the biodegradation was the highest. Consequentially, compost condition was able to reduce a performing period of biodegradation testing than activated vermiculite. However, activated vermiculite could be stabilizing errors between repetition.

• 한국재료학회지
• /
• 제26권8호
• /
• pp.430-437
• /
• 2016

Aluminum oxide ($Al_2O_3$) thin films were grown by atomic layer deposition (ALD) using a new Al metalorganic precursor, dimethyl aluminum sec-butoxide ($C_{12}H_{30}Al_2O_2$), and water vapor ($H_2O$) as the reactant at deposition temperatures ranging from 150 to $300^{\circ}C$. The ALD process showed typical self-limited film growth with precursor and reactant pulsing time at $250^{\circ}C$; the growth rate was 0.095 nm/cycle, with no incubation cycle. This is relatively lower and more controllable than the growth rate in the typical $ALD-Al_2O_3$ process, which uses trimethyl aluminum (TMA) and shows a growth rate of 0.11 nm/cycle. The as-deposited $ALD-Al_2O_3$ film was amorphous; X-ray diffraction and transmission electron microscopy confirmed that its amorphous state was maintained even after annealing at $1000^{\circ}C$. The refractive index of the $ALD-Al_2O_3$ films ranged from 1.45 to 1.67; these values were dependent on the deposition temperature. X-ray photoelectron spectroscopy showed that the $ALD-Al_2O_3$ films deposited at $250^{\circ}C$ were stoichiometric, with no carbon impurity. The step coverage of the $ALD-Al_2O_3$ film was perfect, at approximately 100%, at the dual trench structure, with an aspect ratio of approximately 6.3 (top opening size of 40 nm). With capacitance-voltage measurements of the $Al/ALD-Al_2O_3/p-Si$ structure, the dielectric constant of the $ALD-Al_2O_3$ films deposited at $250^{\circ}C$ was determined to be ~8.1, with a leakage current density on the order of $10^{-8}A/cm^2$ at 1 V.