• Carbon letters
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• 제5권3호
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• pp.118-126
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• 2004

MCMB (Mesocarbon microbeads) is a kind of anode material for lithium-ion secondary battery. MCMB charge/discharge cycle stability is one of the important criterion at lithium-ion battery operation. In this study, the cycling stability of a lithium-ion secondary battery has been examined. MCMB was made by the direct solvent extraction method. After the MCMB was carbonized and graphitized, the measurement of charge/discharge capacity and efficiency were carried out. In the result, discharge capacity of MCMB in the initial cycle was above 290.0 mAh/g. After the second cycle, efficiency of charge/discharge MCMB was about 98%. These results were similar to the commercial MCMB product.

• 대한환경공학회지
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• 제36권11호
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• pp.725-732
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• 2014

식물정화공법(Phytoremediation)은 식물을 이용하여 오염된 토양 또는 폐수의 유해한 오염물질을 흡수, 제거, 안정화, 무독화 시키는 기술을 의미하며, 친환경적, 경제적인 오염정화 방안이다. 포플러는 생장이 빠른 속성수종으로써 수분과 양분을 흡수하는 능력이 우수하여 각종 오염물질을 효과적으로 흡수제거하므로, 유기오염물질, 중금속 등 유해물질 제거에 높은 효율을 보이고 있다. 본 연구에서는 식물정화공법의 부산물로 발생되는 포플러를 원료로 이용한 활성탄 제조시스템을 대상으로 전과정평가 기법에 의해 환경에 미치는 영향을 분석하고자 하였다. 최적의 탄화 및 활성화 조건에서 이동식 소규모의 로터리킬른 회전로를 사용하여 에너지소비를 최소화 하였을 때 환경편익이 가능한 것으로 추정되었다. 시스템경계확장방법을 적용하여 야자각을 원료로 한 활성탄 제조시스템의 환경영향의 회피분석결과 자원고갈을 제외한 환경영향 범주에서 마이너스 효과를 보이므로 잠재적 가능성이 있는 것으로 사료된다.

• 한국해양공학회지
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• 제6권1호
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• pp.113-121
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• 1992

In this study, the variation of fatigue strength in CF/PEEK and CF/EPOXY, the matrix and interfacial strength of which differ from each other, has been studied from the viewpoint of microfracture behavior. The results obtained are as follows; According as the fatigue strength moves from the lower cycle range to the higher cycle range, that of CF/PEEK shows higher curve than that of CF/EPOXY does. In the early stage of fatigue life, the characteristic of fatigue crack in CF/PEEK is mainly the fracture of longitudinal fiber, while that in CF/EPOXY is the fracture of transverse fiber. The difference of fatigue strength in these materials can be explained by the fracture criteria of transverse fiber and longitudinal fiber.

• Journal of Electrochemical Science and Technology
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• 제10권2호
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• pp.99-103
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• 2019

A derivative of 1,4-Naphthoquinone coded HBU671 was synthesized and used in addition to activated carbon as composite electrode for supercapacitor application. From the electrochemical properties analysis, a specific capacitance of about $300F\;g^{-1}$ exhibited almost two times of that of activated carbon at a scan rate of $100mV\;s^{-1}$ and a potential window of - 0.2 - 1V. This improvement is due to the inherent redox reaction in HBU671. Cycle test also proved that this composite is still stable even after 1000 cycle within the applied potential window and it is highly recommended for practical application.

• 한국수소및신에너지학회논문집
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• 제34권1호
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• pp.83-89
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• 2023

In this study, a computer simulation work has been performed for the separation of electronic grade highly pure carbon dioxide more than 7 N purity through a cryogenic distillation process. For the cold utility as a cooling medium for a condenser of the cryogenic distillation column, propylene was utilized as a refrigerant in the vapor-recompression refrigeration cycle. Through this work, it was concluded that the cryogenic distillation column with two stage compression and refrigeration cycle were essential to obtain a highly-pure liquefied CO₂.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.28.1-28.1
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• 2011

We deposited the carbon films on Ni substrates by thermal atomic layer deposition (th-ALD), for the first time, using carbon tetrabromide ($CBr_4$) precursors and H2 reactants at two different temperatures (573 K and 673 K). Morphology of carbon films was characterized by scanning electron microscopy (SEM). The carbon films having amorphous carbon structures were analyzed by X-ray photoemission spectroscopy (XPS) and Raman spectroscopy. As the working temperature was increased from 573 K to 673 K, the intensity of C1s spectra was increased while that of O1s core spectra was reduced. That is, the purity of carbon films containing bromine (Br) atoms was increased. Also, the thin amorphous carbon films (ALD 3 cycle) were transformed to multilayer graphene segregated on Ni layer, through the post-annealing and cooling process.

• Carbon letters
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• 제15권3호
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• pp.162-170
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• 2014

Pitch is an attractive raw material for carbon fiber precursors due to its low cost stemming from its availability as a residue of coking and petroleum processes. Ford Motor Company reported a carbon fiber target price of $11.0/kg by using a fast cycle-time manufacturing method with carbon fiber in an inexpensive format, allowing for an average retail price of gasoline of $3.58/gallon. They also recommended the use of carbon fiber with strength of 1700 MPa, modulus of 170 GPa, and 1.5% elongation. This study introduced a ca. $5.5{\mu}m$ carbon fiber with 2000 MPa tensile strength obtained from a precursor through simple distillation of petroleum residue. Petroleum pitch based carbon nanofibers prepared via electrospinning were characterized and potential applications were introduced on the basis of their large specific surface area and relatively high electrical conductivity.

• 한국지구과학회지
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• 제35권3호
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• pp.192-202
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• 2014

이 연구의 목적은 탄소 순환 관련 탄소 배출 시나리오를 통해 고등학교 학생들의 질량 보존의 개념을 확인하는 것이다. 이 연구를 위해 총 76명의 고등학교 2학년 학생들이 참여하였다. 연구 참여자들에게 2013년의 대기 중 이산화탄소 값이 2110년까지 ${\pm}15%$의 변화로 450 ppm와 340 ppm으로 점진적으로 증가 또는 감소되는 두 개의 시나리오를 제시하였다. 시나리오에 따라 연구 참여자들에게 이산화탄소의 배출량 궤적을 그리게 한 후, 이를 설명하게 하였다. 그 결과는 다음과 같다. 대부분의 연구 참여자들은 탄소 배출 시나리오에 따른 이산화탄소 배출량과 자연적 순수 제거량에 대한 질량 보존의 추론보다는 이산화탄소 배출량은 앞으로도 계속해서 증가할 것이라는 결과를 나타내었다. 이는 연구 참여자들이 고등학교 지구과학 교과서의 탄소 배출과 관련된 그래프들 즉, 산업혁명 이후 최근까지의 인위적 이산화탄소 배출량 그래프, 대기 중 이산화탄소 농도 그래프, 평균 지구의 온도에 대한 그래프를 통해 이산화탄소 배출량이 계속해서 증가할 것이라는 패턴 매칭(pattern matching)을 생각하게 되었다는 것을 의미한다.

• 한국토양비료학회지
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• 제47권6호
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• pp.457-463
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• 2014

This study was carried out to find out major factors to mitigate carbon emission using Life Cycle Assessment (LCA). System boundary of LCA was confined from sowing to packaging during vegetable production. Input amount of agri-materials was calculated on 2007 Income reference of white radish, chinese cabbage and chive produced at open field and film house published by Rural Development Administration. Domestic data and Ecoinvent data were used for emission factors of each agri-material based on the 1996 IPCC guideline. Carbon footprint of white radish was 0.19 kg $CO_2kg^{-1}$ at open fields, 0.133 kg $CO_2kg^{-1}$ at film house, that of chinese cabbage was 0.22 kg $CO_2kg^{-1}$ at open fields, 0.19 kg $CO_2kg^{-1}$ at film house, and that of chive was 0.66 kg $CO_2kg^{-1}$ at open fields and 1.04 kg $CO_2kg^{-1}$ at film house. The high carbon footprint of chive was related to lower vegetable production and higher fuel usage as compared to white radish and Chinese cabbage. The mean proportion of carbon emission was 35.7% during the manufacturing byproduct fertilizer; white radish at open fields was 50.6%, white radish at film house 13.1%, Chinese cabbage at outdoor 38.4%, Chinese cabbage at film house 34.0%, chive at outdoor 50.6%, and chive at film house 36.0%. Carbon emission, on average, for the step of manufacturing and combustion accounted for 16.1% of the total emission; white radish at open fields was 4.3%, white radish at film house 15.6%, Chinese cabbage at open fields 6.9%, Chinese cabbage at film house 19.0%, chive at open fields 12.5%, and chive at film house 29.1%. On the while, mean proportion of carbon footprint for the step of $N_2O$ emission was 29.2%; white radish at open fields was 39.2%, white radish at film house 41.9%, Chinese cabbage at open fields 34.4%, Chinese cabbage at film house 23.1%, chive at open fields 28.8%, and chive at film house 17.1%. Fertilizer was the primary factor and fuel was the secondary factor for carbon emission among the vegetables of this study. It was suggested to use Heug-To-Ram web-service system, http://soil.rda.go.kr, for the scientific fertilization based on soil testing, and for increase of energy efficiency to produce low carbon vegetable.

• 공업화학
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• 제29권5호
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• pp.594-603
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• 2018

본 연구는 VOC 제거 기술인 TSA 공정에서 제올라이트 13X와 활성탄이 채워진 두 종류의 탑을 사용하여 원료농도, 질소 유량, 수증기 유량, 탑 온도 등 조업조건의 영향을 분석하였다. 본 연구의 TSA 사이클은 흡착단계, 수증기 탈착단계, 건조 및 냉각단계로 구성되었다. 2% 벤젠 농도에서 제올라이트 13X와 활성탄의 사이클 당 전체 흡착량은 각각 4.44 g과 3.65 g으로 활성탄보다 충전밀도가 큰 제올라이트 13X가 더 많은 양의 벤젠을 흡착할 수 있었다. 수증기 탈착의 결과에서 수증기 유량을 증가시키고 탑의 외부 가열로 온도를 높이면 탈착시간이 짧아지고 배출되는 벤젠의 농도가 높아지는 것으로 나타났다. 2% 벤젠 농도에서 수증기 유량을 75 g/hr로 증가시키면 탈착시간이 1 hr에서 최대 33 min까지 단축되어 상대적으로 건조 및 냉각단계의 시간이 늘어나 수증기 제거와 탑 냉각을 충분히 진행할 수 있었다. 탑 온도를 높이면 탈착량이 증가하나 $150^{\circ}C$ 이상에서는 에너지소비는 증가하는 반면 탈착량은 거의 일정했다. 연속 사이클 조업에서 재생단계 완료 시 잔존하게 되는 벤젠의 비율이 늘어나면 흡착제 working capacity 감소의 원인이 될 수 있다. 제올라이트 13X를 이용해 연속 사이클 공정실험을 수행한 결과 탑 내부에 잔존하는 벤젠의 비율이 4번째 사이클 이후 일정한 값으로 유지되었다.