• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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• pp.57-59
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• 1998

The headspace method has been acknowledged as a cost-effective and convenient method to analyze volatile organic compounds(VOCs) in soil. The headspace analysis is based on equilibrium partitioning of VOCs among water, air and soil in a closed system. However, the headspace method cannot be applied to soils where most of the VOCs remain sorbed even at high temperature. In this study, it was investigated how the sorption characteristics of VOCs varied with soil with different organic carbon contents and temperature. This study showed that all the VOCs were volatilized, not sorved, only in the soil with 5% organic carbon at 45$^{\circ}C$ or higher. Some fraction of VOCs remained in soil with 8% organic carbon at $65^{\circ}C$ of higher. Most of the VOCs remained sorbed in soil with 12% organic content even at 95$^{\circ}C$. This result suggested that the headspace method can be applied only to soils with little organic carbon content (less than 5%). In this case, 45$^{\circ}C$ seems to be high enough to volatilize all the VOCs from soil. Large particles still showed a significant sorption capacity for VOCs from soil. Large Particles still showed a significant sorption capacity for VOCs despite of their low level of organic carbon content. It was also shown that the organic carbon sorption coefficients (Koc) of VOCs varied with soils with different organic carbon content. This suggests that not only the organic matter content of soil but also the property of the organic matter in soil influence the sorption of VOCs to soil.

• Bulletin of the Korean Chemical Society
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• 제35권2호
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• pp.597-600
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• 2014

In this work, the electromagnetic interference shielding effectiveness (EMI-SE) of carbon nanotube/carbon fiber-reinforced HDPE matrix composites are investigated with various preparation conditions, such as the carbon fiber and carbon nanotube content, the presence of metal additives, as well as mixing speed and time. It was found that the EMI-SE of the composites increased with filler contents and metal additives. These results indicate that the content and length of carbonaceous fillers determine the electric networks in the composites, resulting in the control of the EMI-SE of the composites.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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• pp.136-137
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• 2005

To measure elastic properties of semiconducting materials in power cable, we have investigated modulus of EBA/carbon black composite showed by changing the content of carbon black. The specimen was primarily kneaded in material samples of pellet form for 5 minutes on rollers ranging between 70[$^{\circ}C$] and 100[$^{\circ}C$]. Then this was produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm]. The contents of conductive carbon black were 20, 30 and 40[wt%], respectively. The modulus experiment was measured by DMA 2980. The ranges of measurement temperature were from -50[$^{\circ}C$] to 100[$^{\circ}C$] and measurement frequency is 1 [Hz]. The modulus of specimens was increased according to an increment of carbon black content And modulus was rapidly decreased at the glass transition temperature. The tan$\delta$ of specimens was decreased according to an increment of carbon black content.

• 열처리공학회지
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• 제28권4호
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• pp.171-180
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• 2015

The variation in microstructure and texture during continuous annealing was examined in a series of 1.6% Mn-0.1% Cr-0.3% Mo-0.005% B steels with carbon contents in the range of 0.010 to 0.030%. It was found that microstructure of hot band consisted of ferrite and pearlite as a consequence of high coiling temperature, and eutectoid carbon content was between 0.011% and 0.016%. Martensite ranged in volume fraction from 1.5% to 4.0% when annealed at $820{\circ}C$ according to the typical continuous annealing cycle. The critical martensite content for the continuous yielding was about 4% from stress-strain curves. The continuous yielding was obtained in the 0.030% carbon steel and 0.010% to 0.020% carbon steels revealed some yield point elongation ranging from 0.8% to 2.2% in as-annealed conditions. Higher tensile strength in the higher carbon steel is due to both increase in the martensite volume fraction and ferrite grain refinement. Decreasing the carbon content to 0.01% strengthened the intensities of ${\gamma}$-fiber textures, resulting in the increase in the $r_m$ value, which was caused by the lower volume fraction of martensite. The higher carbon steels showed the lower $r_m$ value of about 1.0.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2005년도 추계학술대회 논문집
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• pp.193-197
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• 2005

Influences of microstructure on high-cycle fatigue (HCF) limit of high carbon $(>0.7wt.\;\%)$ steel filaments used for tires have been investigated. A series of the fatigue tests was carried out depending on carbon content by using Hunter-type tester at a frequency of 60 Hz at a tension/compression stress of 900 to 1500 MPa. Microstructural changes of the filaments were identified in the lateral direction by using transmission electron microscopy (TEM). It was found that the mechanical properties, such as fatigue limit and tensile strength, were improved with increasing carbon content, which was mainly attributed to decreased lamellar spacing and cementite thickness. However, the fatigue ratio, which is defined as the ratio of the fatigue limit to the tensile strength, was reduced in a higher carbon range of 0.8 to $0.9\;wt.\%$, while the fatigue ratio was nearly constant in a lower carbon range of 0.7 to $0.8\;wt.\%$. Overall mechanical properties of the filaments, depending on carbon content, have been discussed in terms of the microstructural parameter change of lamellar spacing and cementite thickness. In addition, the variation of cementite morphology on the fatigue crack propagation of high carbon $(0.9wt.\;\%)$ filaments will be discussed.

• 한국표면공학회지
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• 제21권2호
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• pp.53-67
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• 1988

The high temperature corrosion of Fe-C alloys were studied at I atm SO gas in the temperature range 500~80$0^{\circ}C$ by means of a thermogravimetric analysis. The Na2SO4 induced high tempwrature corrosion rate was also measured at atm O2 gas under above the temperature renge. The reaction products were identified with the aid of X-ray diffraction technique, and micostruction of the alloy/scale interface was observed with a optical microscope and SEM. The experimental results were disussed by the themodeynamic calcutions. Under above the experimental condition. the reaction rates decrbon with increasing carbon content. The transfer of Fe ion was limited by a residue of carbon precipitated at alloy scale interface due to the oxidation of Fe-C alloys at alloy surface. The effect of cold working on reaction rate was different between the Fe containing low carbon and Fe-C Alloy containing carbon above 0,73 wt%. In a cold worked iron containing low carbon content, the crystallization of metal surface leads to the poor adherence between the alloy and the cavity formed between the alloy and scale. The outward diffusion of ion through the scale is estimated to be hindered by the cavity formed between the scale, consequently decreasing reaction rate. In the case Fe-C containing carbon above 0.73 Wt% alloy, the reaction rate was little affected by cold working, because the effect of content on reaction rats is greater than the effect of cold working.

• 한국세라믹학회지
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• 제20권2호
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• pp.166-172
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• 1983

In this study the sillicon-alloyed isotropic pyrolytic carbon was deposited in the tumbling bed from the pyrolysis of propane and silicon tetrachloride and investigated whether the silicon-alloyed isotropic pyrolytic carbon deposited in this study was usable as bionaterial or not. The silicon-allyed isotropic pyrolytic carbon was varied by controlling the process variables such as propane con-concentration and the argon flow rate flowing in to the silicon tetrachloride bubbler at a fixed reaction bed tempera-ture of 120$0^{\circ}C$ a rotation of reaction tube of 40 rpm a bed particle weight of 7.5 g and a total flow rate of 21/min; the propane concentration was varied from 10 to 70 and the argon flow rate flowing into the silicon tetrachloride bubble from 0 to 1000 cc/min. The results show that the silicon-alloyed isotropic pyrolytic carbon was obtained at all conditions investigated, . And then the alloyed silicon content is rangion from 7 to 14.5 wt%. The density and deposition rate of deposited silicon-alloyed isotropic carbon increased axxording to silicon content and propane concentration. And the apparent crystal-size(Lc) of pyrolytic carbon is not changed with silicon content. The density and apparant crystallite size are respec-tively in the range of 1.94 to 2.06 and 20 to 25$\AA$ It is shown that the silicon-alloyed isotropic pyrolytic carbon ob-tained in this experiment is usable as biomaterial.

• 한국표면공학회지
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• 제36권1호
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• pp.34-41
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• 2003

Effects of additives and plating conditions of high speed electroplating were investigated. The Sn content in electrodeposit was highly decreased with increasing current density from $10A/dm^2$ to $50A/dm^2$, and the current efficiency on the cathode was decreased. The carbon content in the electrodeposit was decreased with increasing current density from $10A/dm^2$ to $30A/dm^2$, however the carbon content was highly increased in the range of $40A/dm^2$$∼50A/dm^2$. The formation of tetravalent tin and stannic oxide sludge was prevented by the addition of gallic acid in the bath. The changing of Sn content in the electrodeposit is caused by the addition of gallic acid.

• Carbon letters
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• 제22권
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• pp.36-41
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• 2017

Biodegradable epoxy (B-epoxy) was prepared from diglycidyl ether of bisphenol A and epoxidized linseed oil. The mechanical properties of B-epoxy composites reinforced with multi-walled carbon nanotubes (MWCNTs/B-epoxy) were examined by employing dynamic mechanical analysis, critical stress intensity factor ($K_{IC}$) tests, and impact strength tests. The electromagnetic interference shielding effectiveness (EMI-SE) of the composites was evaluated using reflection and absorption methods. Mechanical properties of MWCNTs/B-epoxy were enhanced with an increase in the MWCNT content, whereas they deteriorated when the MWCNT content was >5 parts per hundred resin (phr). This can likely be attributed to the entanglement of MWCNTs with each other in the B-epoxy due to the presence of an excess amount of MWCNTs. The highest EMI-SE obtained was ~16 dB for the MWCNTs/B-epoxy composites with a MWCNT content of 13 phr at 1.4 GHz. The composites (13 phr) exhibited the minimum EMI-SE (90%) when used as shielding materials at 1.4 GHz. The EMI-SE of the MWCNTs/B-epoxy also increased with an increase in the MWCNT content, which is a key factor affecting the EMI-SE.

• 한국재료학회지
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• 제29권12호
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• pp.735-740
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• 2019

The purpose of this study is to fabricate an ophthalmic lens by copolymerizing two types of carbon nanotubes and hydrophilic hydrogel lens materials, and to investigate its application as an ophthalmic lens material by analyzing its physical properties and antimicrobial effect. For polymerization, HEMA (2-hydroxyethyl methacrylate), EGDMA (ethylene glycol dimethacrylate), a crosslinking agent, and AIBN (azobisisobutyronitrile), an initiator, are used as a basic combination, and a single-walled carbon nanotube and a single-walled, carboxylic-acid-functionalized carbon nanotube are used as additives. To analyze the physical properties, the water content, refractive index, breaking strength, and antimicrobial effect of the fabricated lenses are measured. The fabricated lenses satisfies all the basic properties of the basic hydrogel ophthalmic lens. The water content increases with increasing amount of additive and decreases with addition of 0.2 % ratio of nanoparticles. The refractive index is inversely proportional to the water content result. As a result of the antimicrobial test of the fabricated lens, the addition of carbon nanotubes shows an excellent antimicrobial effect. Therefore, it is considered that the fabricated lens can be applied as a functional material for basic ophthalmic hydrogel lenses.