• Title/Summary/Keyword: carbon addition

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Effects of Mo, V addition on Linear Thermal Expansion Coefficient and Hardness of Low Thermal Expansion Cast Steel (주강계 저열팽창 주조합금의 열팽창 계수와 경도에 미치는 Mo, V 첨가의 영향)

  • Kim, Young-Han;Yoon, Eui-Park;Moon, Byoung-Moon;Hong, Young-Myung
    • Journal of Korea Foundry Society
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    • v.18 no.5
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    • pp.467-473
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    • 1998
  • For enhancing the mechanical properties of LTE (low thermal expansion) cast steel, systematic researches have been carried out. The effects of alloying elements such as vanadium, molybdenum and carbon on the hardness and linear thermal expansion coefficient were investigated. In the range of $0.5{\sim}2.3\;wt%$ carbon, addition of 1.73 wt% carbon caused hardness increase due to the formation of eutectic carbide having high hardness but over the range of 1.73 wt% carbon, hardness was decreased. Thermal expansion coefficient increases with carbon contents. In the LTE cast steel containing 0.6 wt% carbon, hardness increased up to 1.96 wt% vanadium addition. But over the range of 1.96 wt% vanadium hardness was decreased by coarse eutectic carbide. Thermal expansion coefficient of LTE cast steel containing 0.6 wt%carbon moderately increased with increasing vanadium contents. There was no significant variation of hardness and thermal expansion coefficient according to molybdenum content in LTE cast steel.

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The Role of Inorganic Compounds Additions on the Matrix Microtexture Control of C/C Composite (무기화합물 첨가에 의한 C/C복합재료의 매트릭스 조직제어)

  • ;安田榮
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1151-1158
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    • 1997
  • Fracture of uni-directional carbon fiber reinforced carbon matrix composite is strongly dependent on the orientation of basal plane in graphite matrix when it is limited within matrix. The orientation of basal planes are vertically stacked to carbon fiber which results in the weakness for applied tensile or shear force in thermosetting resin derived-carbon matrix composite. Microtextural control of the matrix was tried through chemical interaction between metal carbides and furan resin derived-carbon matrix. SiC and TiO2 addition made the orientation disordered. However, porosity increased due to decomposition of SiC. Interfacial bonding could be controlled by TiO2 addition, but carbon fiber was considerably reacted with TiC during thermal treatment higher than 2$600^{\circ}C$. Therefore, it is desirable to control the thermal treatment temperature at which decomposition of SiC was not serious and TiC/C was not formed eutectoid.

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Improvement of the electrochemical properties of low temperature synthesized carbon for anode materials in lithium-ion batteries (리튬이온전지의 음극 재료로서 저온합성탄소의 전기화학적 특성의 향상)

  • 이헌영;장석원;신건철;이성만;이종기;이승주;백홍구
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.55-61
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    • 2000
  • The electrochemical properties of hard carbon anodes in lithium ion batteries were improved by carbon coating using polyvinyl chloride (PVC). The reduction in irreversible capacity occured and the reversible capacity increased. It is suggested that the PVC carbon coating modifies the surface of hard carbon and reduces the surface reaction with species from air. The degree of the graphitization of PVC carbon was controlled by an addition of Ni, and the effect of the amount of Ni addition on the electrochemical properties was discussed.

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Effects of Additions of Activated Carbon on Productivity and Physico-Chemical Characteristics in Broilers (활성탄의 첨가가 육계의 생산성 및 이화학적 특성에 미치는 영향)

  • 김영직;박창일
    • Food Science of Animal Resources
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    • v.21 no.1
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    • pp.24-31
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    • 2001
  • The effects of addition of activated carbon to diet of broiler on productivity and meat quality of broilers were investigated. 48 broiler raised for six week. The addition level of activated carbon to each group was added 0, 0.6, 0.9 and 1.2%, respectively. During the experimental feeding period, weekly gain and feed intake of treatment fed diets contain 0.6 and 0.9 percent activated carbon were higher compared with those fed on control diet, though effects of diets containing graded levels of activated carbon on the feed efficiency were not found. When broilers were fed activated carbon on crude protein level of birds were higher compared with that of control diet. Also, crude fat of broilers fed diet containing activated carbon were shown to decrease compared with those fed of control diet(p<0.05). The pH from activated carbon diets was rather higher than that of control(p<0.05). The content of VBN and TBARS was not significantly different among all treatments. The heating loss has tend to decrease in activated carbon diet groups(p<0.05). The WHC tend to be increase in activated carbon diet groups(p<0.05). Blood cholesterol was no significantly different.

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Combustion Characteristics of Methane/Oxygen Gas in Pre-mixed Swirl Flame (메탄/순산소 예혼합 화염의 선회 특성)

  • Choi, Won-Seok;Kim, Han-Seok;Cho, Joo-Hyeong;Kim, Yong-Mo;Ahn, Kook-Young;Woo, Ta-Kwan
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.1979-1983
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    • 2008
  • The effects of carbon dioxide addition to oxygen have been investigated with swirl-stabilized premixed methane flame in a laboratory-scale pre-mixed combustor. The methane fuel and oxydant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of carbon dioxide addition to the methane fuel and different swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensity of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of dilution gas in the reaction zone.

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Ophthalmic Application of Hydrogel Polymer Containing Carbon Nanomaterials

  • Seok, Jae-Wuk;Geum, Yong-Pil;Shin, Dong-Seok;Sung, A-Young
    • Journal of Integrative Natural Science
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    • v.12 no.4
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    • pp.116-121
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    • 2019
  • This experiment is to evaluate the physical properties of the hydrogel lens with the addition of carbon-based nanomaterials, Graphene oxide and Carbon nanotube, and to confirm the improvement of strength. Hyaluronic acid, a hydrophilic substance, was used as an additive by using HEMA (2-hydroxyethyl methacrylate) and ethylene glycol dimethacrylate (EGDMA) as a base monomers. Graphene oxide and two types of Carbon nanotubes(Amide functionalized and Carboxilic acid functionalized) were added 0.1%, 0.3%, 0.5%, respectively, and the physical properties were analyzed by measuring water content, refractive index, breaking strength and SEM image. In the case of the sample added with each carbon nano material, the water content tended to increase for all three materials. The breaking strength tended to increase in Graphene oxide and Carbon nanotube; Carboxilic acid functionalized, but in the case of Carbon nanotube; amide fuctionalized, the breaking strength tended to decrease. However, Carbon nanotube; amide fuctionalized had the highest breaking strength among the three nano materials. Thus, the addition of certain carbon nanomaterials seems to be appropriate for improving the strength of hydrogel lenses.

Influence of Nb Addition and Austenitizing Temperature on the Hardenability of Low-Carbon Boron Steels (저탄소 보론강의 경화능에 미치는 Nb 첨가와 오스테나이트화 온도의 영향)

  • Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.577-582
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    • 2015
  • The present study is concerned with the influence of niobium(Nb) addition and austenitizing temperature on the hardenability of low-carbon boron steels. The steel specimens were austenitized at different temperatures and cooled with different cooling rates using dilatometry; their microstructures and hardness were analyzed to estimate the hardenability. The addition of Nb hardly affected the transformation start and finish temperatures at lower austenitizing temperatures, whereas it significantly decreased the transformation finish temperature at higher austenitizing temperatures. This could be explained by the non-equilibrium segregation mechanism of boron atoms. When the Nb-added boron steel specimens were austenitized at higher temperatures, it is possible that Nb and carbon atoms present in the austenite phase retarded the diffusion of carbon towards the austenite grain boundaries during cooling due to the formation of NbC precipitate and Nb-C clusters, thus preventing the precipitation of $M_{23}(C,B)_6$ along the austenite grain boundaries and thereby improving the hardenability of the boron steels. As a result, because it considerably decreases the transformation finish temperature and prohibits the nucleation of proeutectoid ferrite even at the slow cooling rate of $3^{\circ}C/s$, irrespective of the austenitizing temperature, the addition of 0.05 wt.% Nb had nearly the same hardenability-enhancing effect as did the addition of 0.2 wt.% Mo.

Bridge effect of carbon nanotubes on the electrical properties of expanded graphite/poly(ethylene terephthalate) nanocomposites

  • Kim, Ki-Seok;Park, Soo-Jin
    • Carbon letters
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    • v.13 no.1
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    • pp.51-55
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    • 2012
  • In this work, expanded graphite (EG)-reinforced poly(ethylene terephthalate) (PET) nanocomposites were prepared by the melt mixing method and the content of the EG was fixed as 2 wt%. The effect of multi-walled carbon nanotubes (MWCNTs) as a co-carbon filler on the electrical and mechanical properties of the EG/PET was investigated. The results showed that the electrical and mechanical properties of the EG/PET were significantly increased with the addition of MWCNTs, showing an improvement over those of PET prepared with EG alone. This was most likely caused by the interconnections in the MWCNTs between the EG layers in the PET matrix. It was found that the addition of the MWCNTs into EG/PET led to dense conductive networks for easy electron transfers, indicating a bridge effect of the MWCNTs.

Enhanced Electromagnetic Properties of Nickel Nanoparticles Dispersed Carbon Fiber via Electron Beam Irradiation (전자선 안정화에 의한 니켈 나노 입자가 분산된 탄소섬유의 전자기적 특성 향상)

  • Lee, Yeong Ju;Kim, Hyun Bin;Lee, Seung Jun;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.9 no.1
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    • pp.15-20
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    • 2015
  • Carbon fiber has received much attention owing to its properties, including a large surface-to-volume ratio, chemical and thermal stability, high thermal and electrical conductivity, and high mechanical strengths. In particular, magnetic nanopowder dispersed carbon fiber has been attractive in technological applications such as the electrochemical capacitor and electromagnetic wave shielding. In this study, the nickel-oxide-nanoparticle dispersed polyacrylonitrile (PAN) fibers were prepared through an electrospinning method. Electron beam irradiation was carried out with a 2.5 MeV beam energy to stabilize the materials. The samples were then heat-treated for stabilization and carbonization. The nanofiber surface was analyzed using a field emission scanning electron microscope (FE-SEM). The crystal structures of the carbon matrix and nickel nanopowders were analysed using X-ray diffraction (XRD). In addition, the magnetic and electrical properties were analyzed using a vibrating sample magnetometer (VSM) and 4 point probe. As the irradiation dose increases, the density of the carbon fiber was increased. In addition, the electrical properties of the carbon fiber improved through electron beam irradiation. This is because the amorphous region of the carbon fiber decreases. This electron beam effect of PAN fibers containing nickel nanoparticles confirmed their potential as a high performance carbon material for various applications.

Enhancement of Electrocatalytic Activity upon the Addition of Single Wall Carbon Nanotube to the Redox-hydrogel-based Glucose Sensor

  • Kim, Suk-Joon;Quan, Yuzhong;Ha, Eunhyeon;Shin, Woonsup
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.33-37
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    • 2021
  • In electrochemical glucose sensing, the enhancement of the sensitivity and the response time is essential in developing stable and reliable sensors, especially for continuous glucose monitoring. We developed a method to increase the sensitivity and to shorten the response time for the sensing upon the appropriate addition of single wall carbon nanotube onto the osmium polymer-based hydrogel electrode. Also, the background stabilization is dramatically enhanced.