• Title/Summary/Keyword: capacity spectrum

검색결과 435건 처리시간 0.026초

3D-foam 구조의 구리-주석 합금 도금층을 음극재로 사용한 리튬이온배터리의 전기화학적 특성 평가 (Electrochemical Properties of 3D Cu-Sn Foam as Anode for Rechargeable Lithium-Ion Battery)

  • 정민경;이기백;최진섭
    • 한국표면공학회지
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    • 제51권1호
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    • pp.47-53
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    • 2018
  • Sn-based lithium-ion batteries have low cost and high theoretical specific capacity. However, one of major problem is the capacity fading caused by volume expansion during lithiation/delithiation. In this study, 3-dimensional foam structure of Cu-Sn alloy is prepared by co-electrodeposition including large free space to accommodate the volume expansion of Sn. The Cu-Sn foam structure exhibits highly porous and numerous small grains. The result of EDX mapping and XPS spectrum analysis confirm that Cu-Sn foam consists of $SnO_2$ with a small quantity of CuO. The Cu-Sn foam structure electrode shows high reversible redox peaks in cyclic voltammograms. The galvanostatic cell cycling performances show that Cu-Sn foam electrode has high specific capacity of 687 mAh/g at a current rate of 50 mA/g. Through SEM observation after the charge/discharge processes, the morphology of Cu-Sn foam structure is mostly maintained despite large volume expansion during the repeated lithiation/delithiation reactions.

Seismic performance of RC buildings subjected to past earthquakes in Turkey

  • Inel, Mehmet;Meral, Emrah
    • Earthquakes and Structures
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    • 제11권3호
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    • pp.483-503
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    • 2016
  • This study aims to evaluate seismic performance of existing low and mid-rise reinforced concrete buildings by comparing their displacement capacities and displacement demands under selected ground motions experienced in Turkey as well as demand spectrum provided in 2007 Turkish Earthquake Code for design earthquake with 10% probability of exceedance in 50 years for soil class Z3. It should be noted that typical residential buildings are designed according to demand spectrum of 10% probability of exceedance in 50 years. Three RC building sets as 2-, 4- and 7-story, are selected to represent reference low-and mid-rise buildings located in the high seismicity region of Turkey. The selected buildings are typical beam-column RC frame buildings with no shear walls. The outcomes of detailed field and archive investigation including approximately 500 real residential RC buildings established building models to reflect existing building stock. Total of 72 3-D building models are constructed from the reference buildings to include the effects of some properties such as structural irregularities, concrete strength, seismic codes, structural deficiencies, transverse reinforcement detailing, and number of story on seismic performance of low and mid-rise RC buildings. Capacity curves of building sets are obtained by nonlinear static analyses conducted in two principal directions, resulting in 144 models. The inelastic dynamic characteristics are represented by "equivalent" Single-Degree-of- Freedom (ESDOF) systems using obtained capacity curves of buildings. Nonlinear time history analysis is used to estimate displacement demands of representative building models idealized with (ESDOF) systems subjected to the selected ground motion records from past earthquakes in Turkey. The results show that the significant number of pre-modern code 4- and 7-story buildings exceeds LS performance level while the modern code 4- and 7-story buildings have better performances. The findings obviously indicate the existence of destructive earthquakes especially for 4- and 7-story buildings. Significant improvements in the performance of the buildings per modern code are also obvious in the study. Almost one third of pre-modern code buildings is exceeding LS level during records in the past earthquakes. This observation also supports the building damages experienced in the past earthquake events in Turkey.

성능수준 만족을 위한 가새헝 소성 감쇠기의 설계 (Design of Unbend Braces to Satisfy Given Performance Acceptance Criteria)

  • 김진구;김유경;최현훈
    • 한국지진공학회논문집
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    • 제5권6호
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    • pp.47-54
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    • 2001
  • 가새형 소성 감쇠기는 에너지 소산 이력거동을 통해 강한 지진하중을 받는 구조물의 구조적 손상을 방지하거나 감소시킨다. 본 연구에서는 성능수준 만족을 위한 가새형 소성 금비기의 직접적인 설계 방법을 개발하였다. 많은 해석 시간이 요구되는 비선형 동적 시간이력해석 대신 비선형 정적해석법인 능력스펙트럼법을 이용하여 주어진 성능을 만족하기 위하여 필요한 유효 감쇠비를 구한 후 이를 이용하여 가새형 소성 감쇠기의 크기를 구하였다. 각 설계변수의 영향을 파악하기 위하여 단자유도계에서 구조물의 주기, 요구되는 탄성강도에 대한 항복강도의 비, 항목 후 강성비, 가새형 소성 감쇠기의 항복응력 등을 변수로 하여 해석을 수행하였다. 본 연구를 통해 제안된 방법을 5층과 10층 건물에 적용하여 검증하였다. 시간이력해석 결과, 제안된 방법에 따라 설계된 가새형 소성 감쇠기를 설치한 예제 구조물의 최대응답은 주어진 목표변위와 잘 일치하였다.

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증분동적해석을 이용한 철골모멘트골조의 지진취약도 함수 (Seismic Fragility Functions for Steel Moment Resisting Frames using Incremental Dynamic Analyses)

  • 이승원;이원호;김형준
    • 한국전산구조공학회논문집
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    • 제27권6호
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    • pp.509-516
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    • 2014
  • 일반적으로 지진취약도를 평가할 때 사용되는 해석방법 중 하나인 역량스펙트럼 방법은 증분동적해석에 비해 해석의 정확성이 떨어지는 제한점이 있다. 본 연구에서는 증분동적해석이 가장 정확도가 높은 해석기법이라는 점에 착안하여 증분동적해석을 이용한 지진취약도 곡선의 도출과정을 제안하였다. 타당성 비교를 위하여 역량스펙트럼 방법과 제안된 방법으로 도출한 취약도 곡선을 비교하여 두 해석기법에 의한 지진취약도 곡선의 경향을 분석하였다. 그 결과 Slight damage와 Moderate damage의 경우 두 해석방법이 유사한 곡선 경향을 보이나 Extensive damage와 Complete damage의 경우에는 IDA방법에 의한 곡선이 더 가파른 경향을 보였다. 이는 구조물의 거동을 이상화하여 극한점 이후 구조물의 저항 강도가 떨어지지 않는다고 가정하는 역량스펙트럼 방법의 영향을 받는 것으로 사료된다.

철근콘크리트 벽체구조물의 지진응답에 대한 비선형 해석기법의 영향 (Effect of Nonlinear Analysis Procedures for Seismic Responses of Reinforced Concrete Wall Structure)

  • 송종걸;장동휘;정영화
    • 대한토목학회논문집
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    • 제26권4A호
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    • pp.659-675
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    • 2006
  • 근래에 비선형 정적해석법에 기초를 둔 성능-기반 방법이 각광을 받으면서 개선되고 있다. 역량스펙트럼 방법과 변위계수법이 비선형 정적해석법 중에서 대표적이라고 할 수 있다. 새로 건설되거나 기존의 구조물에 대하여 내진설계와 내진성능 평가에 대한 비선형 정적해석법의 적용성을 평가하기 위해서는 우선적으로 역량스펙트럼 방법과 변위계수법의 정확성이 평가되어야 한다. 비선형 정적해석법의 정확성은 근거리 및 원거리 지진하중에 대한 철근 콘크리트 벽체 구조물의 진동대 실험결과와 비교하여 평가하였다. 또한, 단자유도계, 등가단자유도계와 다자유도계에 대한 비선형 동적해석기법에 의해 평가된 지진응답도 진동대 실험결과와 비교하여 평가하였다.

알로에 베라 겔 가공부산물로서의 섬유질 분획의 성분 및 물리화학적 특성 (Physicochemical Properties of Fibrous Material Fraction from By-product of Aloe vera Gel Processing)

  • 백진홍;이신영
    • 산업식품공학
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    • 제14권2호
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    • pp.118-126
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    • 2010
  • The fibrous material fraction as a by-product from the commercial aloe vera gel processing was obtained and freeze dried. The physicochemical characteristics such as the proximate composition, crystalline/surface structures and several physical functionalities including the water holding capacity (WHC), swelling capacity (SW), oil holding capacity (OHC), emulsion/foam properties and viscosity properties of this powdered sample (100 mesh) were investigated and analyzed by comparison with commercial $\alpha$-cellulose as a reference sample. The total dietary fiber content of powdered sample was very high as much as 87.5%, and the insoluble dietary and soluble dietary fiber content ratios were 77.6 and 22.4%, respectively. The FT-IR spectrum of powdered sample showed a typical polysaccharide property and exhibited a x-ray diffraction pattern for cellulose III and IV like structure. SW (8.24${\pm}$0.15 mL/g), WHC(6.40${\pm}$0.19 g water/g solid) and OHC(10.32${\pm}$0.29 g oil/g solid) of freeze dried aloe cellulose were about 3.3, 1.4 and 2 times higher than those of commercial $\alpha$-cellulose, respectively. Aloe cellulose (~2%, w/v) alone had no foam capacity while improved the foam stability of protein solution (1% albumin+0.5% $CaCl_{2}$) by factor of 300%. Emulsion capacity of 2%(w/v) aloe cellulose was about 70% level of 0.5%(w/v) xanthan gum, but its emulsion stability was about 1.2 times higher than that of xanthan gum. Also, aloe cellulose containing CMC (carboxyl methyl cellulose) of 0.3%(w/v) showed a very good dispersity. Aloe cellulose dispersion of above 1%(w/v) exhibited higher pseudoplasticity and concentration dependence than those of $\alpha$-cellulose dispersion, indicating the viscosity properties for new potential usage such as an excellent thickening agent.

Development of an integrated approach for Algerian building seismic damage assessment

  • Boukri, Mehdi;Farsi, Mohammed Naboussi;Mebarki, Ahmed;Belazougui, Mohamed
    • Structural Engineering and Mechanics
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    • 제47권4호
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    • pp.471-493
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    • 2013
  • This paper presents a framework for seismic damage evaluation for Algerian buildings adapted from HAZUS approach (Hazard-United States). Capacity and fragility curves were adapted to fit the Algerian building typologies (Reinforced Concrete structures, Confined or Non-Confined Masonry, etc). For prediction purposes, it aims to estimate the damages and potential losses that may be generated by a given earthquake in a prone area or country. Its efficiency is validated by comparing the estimated and observed damages in Boumerd$\grave{e}$s city, in the aftermath of Boumerd$\grave{e}$s earthquake (Algeria: May $21^{st}$ 2003; $M_w$ = 6.8). For this purpose, observed damages reported for almost 3,700 buildings are compared to the theoretical predictions obtained under two distinct modelling of the seismic hazard. In one hand, the site response spectrum is built according to real accelerometric records obtained during the main shock. In the other hand, the effective Algerian seismic code response spectrum (RPA 99) in use by the time of the earthquake is considered; it required the prior fitting of Boumerd$\grave{e}$s site PGA (Peak Ground Acceleration) provided by Ambraseys' attenuation relationship.

메인과 다이버시티 신호사이 위상차를 이용한 공간 다이버시티 결합방법 (Space Diversity Combining Scheme Using Phase Difference between Main and Diversity Signals)

  • 정길영
    • 한국ITS학회 논문지
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    • 제14권5호
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    • pp.44-51
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    • 2015
  • 모바일 데이터의 급속한 성장으로 인해 대용량의 백홀 구축 요구가 대두되었으며, 비용 효율 관점에서 쉽게 적은 비용을 가지고 백홀을 신속하게 구축할 수 있는 기술은 점대점 마이크로웨이브이다. 점대점 마이크로웨이브 링크에서의 공간 다이버시티 방법은, 두 개의 수신 안테나에서 오는 신호를 결합시킴으로 페이딩효과를 상쇄시켜 성능을 향상시키는 것이다. 기존의 신호 결합방법으로는 최대 전력 방법과 최소 왜곡 방법이 제안되었다. 하지만, 선택적 페이딩 채널에서 두 기법 모두가 알고리즘의 강건성 관점에서 성능저하가 보고되었다. 그래서, 본 논문에서 현실적 관점에서 효율적이며 더 성능이 향상된 신호결합 기법을 제안하고, 시뮬레이션을 통해 제안된 방법이 신호의 스펙트럼 관점에서 상당한 성능의 향상이 있음을 보인다.

A Conditional Clustering Scheme for Hybrid NOMA in Millimeter Wave Communication System

  • Nguyen, Thanh Ngoc;Jeon, Taehyun
    • International journal of advanced smart convergence
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    • 제8권4호
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    • pp.34-39
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    • 2019
  • Millimeter-wave (mmWave) and Non-orthogonal multiple access (NOMA) are expected to be the major techniques that lead to the next generation wireless communication. NOMA provides a high spectrum efficiency by sharing of spatial resources among users in the same frequency band. Meanwhile, millimeter-wave gives a huge underutilized bandwidth at extremely high frequency band (EHF) which covers 30GHz to 300GHz. These techniques have been proven in several recent literatures to achieve high data rates. The combination of NOMA and millimeter-wave techniques further improves average sum capacities, as well as reduces the interference compared to conventional wireless communication systems. In this paper, we focus on hybrid NOMA system working in millimeter-wave frequency. We propose a clustering algorithm used for a hybrid NOMA scheme to optimize the usage of wireless resources. The proposed clustering algorithm adds several conditions in grouping users and defining clusters to increase the probability of the successful superposition decoding process. The performance of the proposed clustering algorithm is investigated in hybrid NOMA system and compared with the conventional orthogonal multiple access (OMA) scheme.

Characteristics with Casting Molding of Functional EPDM Through Grafting Polymerization

  • Yoon, Yoo Mi;Kim, Donghyun;Kim, Jeong Hoe;Kim, Minseub;Lee, Won Ki;Park, Chan Young
    • Elastomers and Composites
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    • 제52권3호
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    • pp.194-200
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    • 2017
  • After the grafting of methacrylic acid (MA) to ethylene propylene diene monomer (EPDM), a new peak at $1704cm^{-1}$ corresponding to the carboxylic acid group was observed in the infrared (IR) spectrum. This characteristic MA molecule peak grew larger as the MA contents were increased. After casting films were prepared from pure EPDM and MA-grafted EPDM, differential scanning calorimeter (DSC) measurements were made the pure EPDM exhibited a melting point of approximately $45^{\circ}C$ while that of the MA-grafted EPDM was $135{\sim}140^{\circ}C$. As the graft ratio of MA increased, the absorbed heat capacity increased at temperatures near $135{\sim}140^{\circ}C$, indicating that an increased amount of MA reacted. Furthermore, owing to the addition of crystalline MA, it is expected that strength of the elastomer will improve as the graft ratio increases, as a result of the increased number of hard segments.