• Korean Journal of Soil Science and Fertilizer
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• v.16 no.4
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• pp.311-317
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• 1983

These studies were carried out to investigate the effects of rice straw on the leaching of chemical constituents in paddy soil. Rice plants were cultured in paddy soil to which rice straw was applied and then chemical properties of percolated water were analysed. The results were as follows. The leaching of calcium and magnesium was affected by rice straw application in the early stages of plant growth and by rice root activity in the late stages. The application of the straw promoted the reduction of the soil followed by increasing the leaching of iron and manganese. The leaching of potassium, ammonium-nitrogen and chloride was not due to the application of rice straw and the leaching of carbon dioxide increased with the application of rice straw, at the same time chemical properties seemed to be affected by rice root activity. Generally, cation and anion leached in the percolated water were equivalent. Calcium, magnesium, Fe as cation and $HCO_3$, $SO_4{^{-2}}$ as anion were important constituents in the percolated water from paddy soil.

• Korean Journal of Soil Science and Fertilizer
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• v.16 no.1
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• pp.36-41
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• 1983

These studies were carried out to investigate the effects of potassium salts on the changes of chemical properties in submerged soil. Rice plants were cultured in submerged soil using potassium salts. Obtained results were as follows. In the submerged soil cultured with rice plants the value of pH was higher in the potassium chloride plot than in the potassium sulfate plot. The leaching of cations such as calcium, magnesium, potassium and ammonium were higher in the potassium chloride plot than in the potassium sulfate plot. On the other hand, the leaching of phosphate ion was slightly higher in the potassium sulfate plot than in the potassium chloride plot. The leaching of iron was higher in the planted plot than in the non-planted plot, but that of silica was higher in the non-planted plot than in the planted plot. However, the leaching of iron and silica was not affected by potassium salts.

• Resources Recycling
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• v.31 no.5
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• pp.26-33
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• 2022

Molybdenum is widely used in many materials; thus, its recovery from ores and secondary resources has attracted considerable attention. In this study, the leaching of molybdenite ore using hydrochloric acid containing sodium chlorate as an oxidizing agent was studied. The effects of several variables, such as the concentrations of HCl and NaClO₃, reaction temperature and time, and pulp density, on the leaching of the ore were investigated. Under strong acidic and oxidizing conditions, the sulfide in the ore was dissolved as a sulfate ion, which formed gypsum with Ca(II), leading to a decrease in the leaching percentage of Mo(VI) from the ore. The leaching percentage of molybdenum was greater than 90%, while those of iron, calcium, and silicon were 38, 29, and 67%, respectively, under the optimum conditions: 2.0 M HCl, 0.5 M NaClO₃, pulp density of 5 g/L, temperature of 90 ℃, and treatment time of 60 min.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.4
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• pp.22-32
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• 2014

Durability is one of the most important and attractive subjects in concrete research field because not only durability of concrete is reduced by various degradation factors but also its reduction adversely influences the structural performance and service life of concrete structure. For this reason, a considerable amount of papers associated with concrete durability have been published and those researches were mainly focused on the changes of intrinsic properties of concrete due to chemicophysical degradations. However, the relationship between durability of concrete and structural behavior of concrete member has not been well established yet. In this study, calcium leaching degradation, a cause of concrete strength reduction, was dealt with. The experiments of compressive and flexural behavior of degraded concrete member were performed to evaluate the characteristics of structural behavior according to degradation level. Finally, the results from the experiments were compared with those obtained from nonlinear FEM analysis. The results from this study clearly showed that leaching degradation leads to decrease in compressive strength and compressive behavior evolves from brittle to ductile failure pattern during the degradation process. Load capacity and flexible rigidity of the degraded RC member decreased when the degradation level increased, in compressive zone. Additionally, it was found that the values from nonlinear FEM analysis, CDP model in ABAQUS, coincided well with the experimental results.

• Journal of the Korea Concrete Institute
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• v.23 no.5
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• pp.647-656
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• 2011

In radioactive waste repositories constructed in underground, concrete member could be in contact with groundwater for a long time. However, this pure water creates concentration gradients which lead to the diffusion of Ca ions from the pore water and the degradation of underground concrete. Therefore, this study is aimed at investigating the alteration of pore structure and loss of compressive strength associated with dissolution. The results showed that as the leaching period became longer, the pore volume within 50 nm to 500 nm in diameter is greatly increased. Also, the volume of pores larger than 200 nm rapidly increased during initial leaching time and those below 200 nm gradually increased. Furthermore, the compressive strength gradually decreased with increase of degraded thickness. The residual strength of the degraded concrete with OPC was in the range of 33% to 58%.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.10
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• pp.865-871
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• 2016

In recent years, traditional scaffold fabrication techniques such as gas foaming, salt leaching, sponge replica, and freeze casting in tissue engineering have significantly limited sufficient mechanical property and cell interaction effect due to only random pores. Fused deposition modeling is the most apposite technology for fabricating the 3D scaffolds using the polymeric materials in tissue engineering application. In this study, 3D slurry mould was fabricated with a blended biphasic calcium phosphate (BCP)/Silica/Alginic acid sodium salt slurry in PCL mould and heated for two hours at $100^{\circ}C$ to harden the blended slurry. 3D dual-pore BCP/Silica scaffold, composed of macro pores interconnected with micro pores, was successfully fabricated by sintering at furnace of $1100^{\circ}C$. Surface morphology and 3D shape of dual-pore BCP/Silica scaffold from scanning electron microscopy were observed. Also, the mechanical properties of 3D BCP/Silica scaffold, according to blending ratio of alginic acid sodium salt, were evaluated through compression test.

• Journal of the Mineralogical Society of Korea
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• v.27 no.4
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• pp.207-222
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• 2014

In order to recover the metallic copper powder from the mine-waste rock, heap bioleaching, Fe removal and electrowinning experiments were carried out. The results of heap leaching with the mine-waste rock sample containing 0.034% Cu showed that, the leaching rate of Cu were 61% and 62% in the bacteria leaching and sulfuric acid leaching solution, respectively. Sodium hydroxide (NaOH), hydrogen peroxide ($H_2O_2$) and calcium hydroxide ($Ca(OH)_2$) were applied to effectively remov Fe from the heap leaching solution, and then $H_2O_2$ was selected for the most effective removing Fe agent. In order to prepare the electrolytic solution, $H_2O_2$ were again treated in the heap leaching, and Fe removal rates were 99% and 60%, whereas Cu removal rates were 5% and 7% in the bacteria and sulfuric acid leaching solutions, respectively. After electrowinning was examined in these leaching solution, the recovery rates of Cu were obtained 98% in bacteria and obtained 76% in the sulfuric leaching solution. The dendritic form of metallic copper powder was recovered in both leaching solutions.

• The Journal of Natural Sciences
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• v.13 no.1
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• pp.83-96
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• 2003

Effect of Nutrient Concentrations, fertigation frequency, and learching percentage on crop growth and nutrient concentrations in root media were evaluated. The treatment of each irrigation with $50 mg.L^{-1}$ of nitrogen in stage 2 and increase to $80 mg.L^{-1}$ nitrogen in stage 3 had the highest crop growth at 34 days after sowing among treatments tested. Feeding with low nutrient concentrations and elevated frequency decreased crop growth. In treatments of each leaching percentage, feeding with low nutrient concentrations and elevated frequency resulted in increased tissue nutrient contents. The less tissue potassium content and higher calcium and magnesium contents were observed in treatment of 50% leach than those in 0% leach. All treatment tested had soil solution pH higher than 6.8. Electrical conductivity in treatments of 50% leach were lower than those of 0% leach. Feeding with low nutrient concentrations and elevated feeding frequency in each leaching percentage resulted in increased electrical conductivity in soil solution of root media. Trends of medium nutrient concentrations were similar to those of electrical conductivity.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.7
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• pp.665-675
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• 2010

The effects of chemical binders (ladle slag, ordinary portland cement (OPC), hydroxyapatite and calcium hydroxide) on the solidification/stabilization of heavy metals (Cd, Cu, Ni, Pb, Zn) in sewage sludge were evaluated by chemical leaching tests such as EDTA extraction, TCLP and sequential extraction. The results of EDTA extraction showed that heavy metal concentrations in sewage sludge were highly reduced after solidification/stabilization with slag, cement or calcium hydroxide. However, EDTA interrupted solidification/stabilization of heavy metals by hydroxyapatite. The TCLP-extracted heavy metal concentrations in sewage sludge after solidification/stabilization with chemical amendments were highly reduced. However, Cu concentration in the sewage sludge solidified/stabilized with slag, cement or calcium hydroxide increased because the pH of TCLP solution was higher than 7. Mixtures of sludge 1 : slag 0.2 : calcium hydroxide 0.1 (wt ratio) showed the least leachability in batch TCLP and EDTA extraction. The results of sequential extraction (SM&T, formaly BCR) indicated that the distribution of heavy metals changed from exchangable and carbonate fractions to strongly bound organic fraction. It was found that maximum leachate concentrations of Ba, Cd, Cr and Pb from sewage sludge amended with slag and calcium hydroxide were far below US EPA TCLP regulations.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.4
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• pp.297-306
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• 2014

Recently nano-materials are gaining more importance in the construction industry due to its enhanced energy efficiency, durability, economy, and sustainability. Nano-silica addition to cement based materials can control the degradation of the fundamental calcium-silicate-hydrate reaction of concrete caused by calcium leaching in water as well as block water penetration and therefore lead to improvements in durability. In this paper, the influence of synthesized nano silica from locally available rice husk on the mechanical properties and corrosion resistant properties of OPC (Ordinary Portland Cement) has been studied by conducting various experimental investigations. Micro structural properties have been assessed by conducting Scanning Electron Microscopy, Thermo gravimetry and Differential Thermal Analysis, X-Ray Diffraction analysis, and FTIR studies. The experimental results revealed that NS reacted with calcium hydroxide crystals in the cement paste and produces Calcium Silicate Hydrate gel which enhanced the strength and acts as a filler which filled the nano pores present in concrete. Hence the strength and corrosion resistant properties were enhanced than the control.