• Title/Summary/Keyword: calcium carbonate-water

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The Effects of Laundering Conditions on Calcium Deposition on the Fabric (세척조건이 직물에의 Calcium 침착에 미치는 영향)

  • Moon Young Ae;Kahng He Won;Kim Sung Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.5 no.1
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    • pp.9-14
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    • 1981
  • The influence of laundering conditions on calcium deposition on the fabric was studied by repeated laundering the cotton fabric with soap in the hard water of 200 P.P.M. $CaCO_3$. The experimental variables were: 1) soap concentrations ($0.06\%$, $0.13\%$, $0.25\%$), 2) water contents in the fabric after hydroextraction. ($65\%$, $150\%$, $315\%$), 3) builders (Na-EDTA, sodium carbonate, sodium metasilicate), 4) washing cycle (5, 10, 15, 20 cycles). The fabric was washed for 15 minutes at $23\pm1^{\circ}C$ in a washing machine (Model; Gold Star Wp-2005) under the similar conditions with those of home laundering, and rinsed 5 times for 5 minutes. The amount of calcium deposits on the fabric was determined by the EDTA-Back titration method described by Wasserman and Basch. Results of this study were follows: 1) The amount of calcium deposits on the fabric increased with increasing wash cycles. 2) During the rinsing process, residual calcium content on the fabric increased with water content in the fabric after hydroextraction. 3) The amount of calcium deposits on the fabric decreased with the increasing soap concentration above the equivalent amount of calcium ion content in the water. 4) Sequestering agents and alkaline builders influenced the amount of calcium deposits on the fabric. The amount of calcium deposits on the fabric was in the order of sodium metasilicate, sodium carbonate, nonbuilder, and EDTA.

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Synthesis and Shape Control of Calcium Carbonate Fine Powders by Liquid-Gas Reaction Method (액상-기상 반응법에 의한 탄산칼슘 미분말의 합성과 형상제어)

  • 민경소;최상흘
    • Journal of the Korean Ceramic Society
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    • v.28 no.3
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    • pp.205-214
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    • 1991
  • Calcium carbonate fine powders were synthesized by blowing CO2 gas in CaO or Ca(OH)2 suspension, and the shapes of powders obtained were examined for each synthetic condition. When water was used as a solvent, ultrafine calcite powders with the average size of∼0.03$\mu\textrm{m}$ were obtained. When synthesized using methanol as a solvent, amorphous phase and spherical vaterite phase were obtained by suction filtering and non-filtering, respectively. Reaction did not occured in ethanol medium, but spherical vaterite phase was obtained by adding ethylene glycol in ethanol.

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THE EFFECT OF FILLERS ON THE DEINKING OF PHOTOCOPIED PAPER

  • Chen, Qing-min;Chang, Hou-min;Ethan K. Andrews;Heinz G. Olf
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.159-163
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    • 1999
  • Model experiments were conducted to investigate the effect of different fillers on the removal of toner ink. Combinations of different papers (commercial photocopy paper and filler-free paper), fillers (calcium carbonate, kaolin clay, and talc), and chemicals(1-octadecanol, stearic acid, oleic acid, and TOFA) and stearic acid were found to be effective in detachment and agglomeration of toner ink. Furthermore, pH had little effect on toner detachment and agglomeration, indicating both protonated fatty acids and their anions are equally effective. In the presence of either kaolin clay or talc, all these agglomerating agents are equally effective, although a slightly higher dosage(1% for clay and 2% for talc as compared with control) is required, presumably due to the adsorption of chemical by the filler. Calcium carbonate filler, on the other hand, has a significant and adverse effect on the fatty acids used but has little effect on 1-octadecanol with the exception of possible adsorption. While stearic acid is not effective, a much higher level of oleic acid or TOFA is needed when calcium carbonate fillers are present as compared to the filler-free case. Fatty acids react with calcium carbonate to form calcium salts. The availability of fatty acid anion for toner detachment and agglomeration is determined by the solubility of calcium salt of a given fatty acid. Calcium oleate is 10 times more soluble in water than calcium stearate.

Development of Corrosion Evaluation Index Calculation Program of Raw Water and Evaluation on Corrosivity of Tap Water using the Calcium Carbonate Saturation Index (상수원수의 부식평가 지수 산정 프로그램 개발 및 탄산칼슘 포화지수에 의한 수돗물의 부식성 평가)

  • Hwang, Byung-Gi;Woo, Dal-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.1
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    • pp.177-185
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    • 2009
  • In this study, we developed the program to calculate the corrosion evaluation index for examining the corrosivity of raw water. When it was applied to the Han river and Nakdong river system, sulfuric acid ion, which accelerated corrosion, was higher in Nakdong river system than Han river system while calcium and hardness, which restrained corrosion, was the same way. Summarization of the LI and CCPP calculation result by the developed corrosion evaluation model showed that water quality of Han river system had strong tendency to corrode (is strongly corrosive). Moreover, this study evaluated the corrosivity of calcium carbonate saturation index by adding the chemicals to tap water. Saturation status was maintained in the order of $Ca(OH)_2$ > NaOH > ${Na_2}{CO_3}$ > $CaCO_3$ in the case of LI and RI.

The Effect of Water-Soluble Calcium Supplements on Calcium Metabolism and Bone Metabolism of Growing Rats

  • Jang, Se-Young;Jeong, Yong-Jin;Kwon, Teak-Kyu;Seo, Ji-Hyung;Park, Eun-Mi
    • Preventive Nutrition and Food Science
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    • v.12 no.4
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    • pp.217-221
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    • 2007
  • Within the elderly population, the use of calcium supplements and the intake of calcium from food are on the rise in order to maintain health. Calcium is absorbed as an ion in vivo, leading to speculation that absorption efficiency is affected by the solubility of the calcium consumed. In our study, the bioavailability of two types of calcium supplements with different solubilities was evaluated. Experimental animals were fed water-soluble or insoluble calcium supplements for 6 weeks. We found that blood alkali phosphatase activity, osteocalcin content, and urine crosslinks values were not different between the groups. Similarly, the degree of apparent calcium absorption between the two calcium supplements was not significantly different. The bone mineral density and bone mineral content of the femur and the tibia increased in the group that consumed insoluble calcium compared with those of the water-soluble calcium supplemented group. However, when considering body weight, the bone mineral density value for all areas, including the spine, was significantly higher in the group that consumed the water-soluble calcium supplement.

Sediments of the Continental Shelf off the Southern Coasts of Korea

  • Park, Yong Ahn;Song, Moo Young
    • 한국해양학회지
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    • v.1
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    • pp.16-24
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    • 1971
  • Over 40 bottom sediment samples were collected from the southern sea of Korea. The detailed textural characteristic of the sediments, percent calcium carbonate and heavy and light mineralogy were determined. Seaward of these sediments is a nearly broad belt of sandy sediments. In a broad outline it is considered to constitute a near-shore deposits left from a Pleistocene time of eustatically lowered level of sea water, because the sediments on the outer half of the continental shelf are much coarser than that nearer shore. The carbonate content increases strongly to the southeast and northwest of Cheju Island. It is believed that the high calcium carbonate content can be largely attributed to the availability of carbonate materials.

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The Comparison of Analytical Methods for Gypsum and Gypsum Slurry (석고 및 석고 슬러리에 대한 분석방법의 비교)

  • Kim, Kyeongsook;Yang, Seugran;Park, Hyunjoo;Lim, Chunsik
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.158-165
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    • 2000
  • The purity of gypsum and quantitation of impurities of flue gas gypsum will not only play an important role in deciding of the optimal condition during a trial run of FGD (flue gas desulfurization), but also can be utilized in quality control of gypsum. The purity of gypsum can be determined from combined water, sulfur trioxide and calcium concentration. We found that the thermal analysis by TGA (thermogravimetric analysis) was the most accurate and convenient method to determine the purity of gypsum. This method will be done in a hour and the results were reproducible. On the other hand, the best way of the analysis of impurities in gypsum was fusion method using $LiBO_2$ as a fusion agent. We also determined the amount of $CO_2$ gas to analyze magnesium carbonate and calcium carbonate contents. The analyses of combined water by TGA, fusion method followed by ICP-AES (inductively coupled plasmaatomic emission spectroscopy) and determination of $CO_2$ amount can lead to more accurate and convenient method for gypsum analysis.

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A Study on the Properties of Microbial Cementation Soil for Engineering Applicability (미생물 고결토의 공학적 특성 연구)

  • Oh, Jong-Shin;Hwang, Soung-Won;Kang, Hee-Bog;Kang, Keon-Soo;Kim, Jong-Ryeol
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.1332-1343
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    • 2008
  • The purpose of this study was to investigate the feasibility of using sedimentation calcium carbonate production based on microorganism activities in the strength manifestation of various soil conditions including ground. For analysis and comparison of microbial cementation soil's strength, unconfined compression test was executed by each content of soil(S), water(W), microorganism(B), microorganism and deposit (BF), microorganism, admixture and deposit(BCF) at specimen. The result, the strength of SB(soil+microorganism) and SBF(soil+microorganism+deposit) increased about 8%, 15% than SW(soil+water). Also, initial strength increased. But the strength of SBC(soil+microorganism+admixture) and SBCF(soil+microorganism+deposit+admixture) increased about 71%, 115% than SW(soil+water). The results of the SEM analysis, leading to the formation of an adhesive substance layers at the surface and resulting in firm particle configuration. The XRD examination of the sediment resulting from the reaction between the microorganism and the deposit control agent confirmed the presence of a type of calcium carbonate ($CaCo_3$) vaterite, which affects soil strength formation, as well as sodium silicate, silicides and so forth. This indicates that microorganism plays an important role in the production of carbonate ($CaCo_3$), sodium silicate and silicides. It affects to revelation of ground strength.

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ALC 의 내구성 및 물성개선에 관한 연구

  • 이범재;홍성수;황의환;조헌영;노재성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.65-70
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    • 1993
  • The effect of particle size of Al powder, water repellent agent and finishing agent on frost resistance, absorption ratio and structure of micropore was examined to improve the physical properties and durability of ALC. According as the amount added of water repellent agent was increased, frost resistance was improved and absorption ratio was decreased. From one side freezing /thaw test, finishing agent which has a low vapor permeation located the crack at close indoor point of ALC specimen. ALC produced from fine Al powder has a low volume reduction by scalling and a sound appearance after freezing/thawing test and top surface freezing test, The crystal of tobermorite in ALC matrix was converted to calcium carbonate by carbonation which was accelerated with the decreasing of water content. Since the micropore of ALC was filled up by calcium carbonate, void ratio was reduced and crack was detected after complete carbonation.

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A Study on Experimental Analysis of Semi-Continuous Settling Tank using Characteristics of Solid Sedimentation in the Binary $CaCO_3$-Water Slurry (탄산칼슘-물 이성분계 슬러리의 침강 특성을 이용한 반연속식 침전탑의 실험적 해석에 관한 연구)

  • 안원술;노승백;김정배;박상원;최창균
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.659-667
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    • 1998
  • In the present paper, batch and semi-continuous settling characteristics of a binary calcium carbonate-water system were investigated. Using experimental data of batch settling characteristics, a graphical analysis for a semi-continuous thickening column was developed and compared with experimental results on the basis of Kynch theory, only where the feed velocity line was within the limits of Kynch theorem III. The analysis showed good agreement with experiments. Quite erroneous results, however, was observed for the analysis of a sludge region on the underloaded operation, which was considered due to the deviation from the limits of theory.

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