• 제목/요약/키워드: calcium aluminate

검색결과 103건 처리시간 0.023초

High-velocity impact of large caliber tungsten projectiles on ordinary Portland and calcium aluminate cement based HPSFRC and SIFCON slabs -Part I: experimental investigations

  • Korucu, H.;Gulkan, P.
    • Structural Engineering and Mechanics
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    • 제40권5호
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    • pp.595-616
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    • 2011
  • Impact experiments have been carried out on concrete slabs. The first group was traditionally manufactured, densely reinforced concrete targets, and the next were ordinary Portland and calcium aluminate cement based HPSFRC (High performance steel fiber reinforced concrete) and SIFCON (Slurry infiltrated concrete) targets. All specimens were hit by anti-armor tungsten projectiles at a muzzle velocity of over 4 Mach causing destructive perforation. In Part I of this article, production and experimental procedures are described. The first group of specimens were ordinary CEM I 42.5 R cement based targets including only dense reinforcement. In the second and third groups, specimens were produced using CEM I 42.5 R cement and Calcium Aluminate Cement (CAC40) with ordinary reinforcement and steel fibers 2 percent in volume. In the fourth group, SIFCON specimens including 12 percent of steel fibers without reinforcement were tested. A high-speed camera was used to capture impact and residual velocities of the projectile. Sample tests were performed to obtain mechanical properties of the materials. In the companion Part II of this study, numerical investigations and simulations performed will be presented. Few studies exist that examine high-velocity impact effects on CAC40 based HPSFRC targets, so this investigation gives an insight for comparison of their behavior with Portland cement based and SIFCON specimens.

수축 보상 모르타르의 현장 적용 연구 (An Application of Shrinkage Compensation Mortar in Construction Field)

  • 김기동;정성철;송명신;이경희
    • 콘크리트학회논문집
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    • 제12권3호
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    • pp.3-10
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    • 2000
  • In this study, we compared a plain mortar with the CAS-system shrinkage compensation mortar for Ondol that is Korean traditional heating system. The Ondol mortar is necessary to have properties as non-crack, fine flatness and stability for thermal changes. especially, mortar'crack prevention is to be most important property in Ondol mortar. To develope the stable material on the crack-prevention, we used to calcium-sulfo-aluminate(CSA)system in shrinkage compensation mortar. And so, we confirmed the effects of calcium-sulfo-aluminate(CSA) system for mortar's physical properties such as setting time, compressive strength and expansion ratio for crack prevention. The initial and final setting time of the CSA mortar is faster than plain mortar about 2hours. And, Compressive strength increased about 20% that plain mortar. The crack length per unit area, plain mortar is 0.426∼0.481m/m2. The Results of apartment construction field test, the shrinkage compensation mortar is excellent about the crack-reduce effect.

Calcium Sulfo Aluminate (CSA) Cement from Coal Ash Utilized as Barriers for Radioactive Waste Disposal

  • Ramakrishna, Chilakala;Thriveni, Thenepalli;Whan, Ahn Ji
    • 에너지공학
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    • 제27권1호
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    • pp.33-39
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    • 2018
  • In this paper, we reviewed briefly about the barrier materials for the radioactive waste disposal. The primary concept of the radioactive waste disposal is safety. The goal of the radioactive waste management is to assure that the environment is not adversely affected and also public. There are a wide variety of materials are available for the radioactive waste disposal or storage. Among those coal fly ash is one of the significant materials are used as a barrier material. Here we reported, the Calcium sulfo aluminate (CSA) from coal fly ash is effectively suitable for the radioactive waste disposal. This is one of the ways of utilization of waste and manufactured the valuable materials for future indeeds.

High-velocity impact of large caliber tungsten projectiles on ordinary Portland and calcium aluminate cement based HPSFRC and SIFCON slabs -Part II: numerical simulation and validation

  • Gulkan, P.;Korucu, H.
    • Structural Engineering and Mechanics
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    • 제40권5호
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    • pp.617-636
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    • 2011
  • We present the numerical implementation, simulation, and validation of the high-velocity impact experiments that have been described in the companion article. In this part, numerical investigations and simulations performed to mimic the tests are presented. The experiments were analyzed by the explicit integration-based software ABAQUS for improved simulations. Targets were modeled with a damaged plasticity model for concrete. Computational results of residual velocity and crater dimensions yielded acceptable results.

Effects of Calcium Aluminate Compounds on Hydration of BFS

  • Song, Hyeon-jin;Kang, Seung-Min;Jeon, Se-Hoon;Kim, Jung-Won;Song, Myong-Shin
    • 한국세라믹학회지
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    • 제52권6호
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    • pp.483-488
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    • 2015
  • Blast furnace slag(BFS) is well known for its hardening mechanism in ordinary Portland cement with alkali activation due to its latent hydraulic property. The possibility of using calcium compound as activator for BFS has been investigated in this study. The hydration properties of calcium compound activated BFS binders were explored using heat of hydration, powder X-ray diffraction and compressive strength testing. Heat of hydration results indicate that the hydration heat of BFS is lower than OPC paste by about 50%. And ettringite as hydration product was formed continuously as the calcium sulfate was decreased. The maximum compressive strength of hardened BFS mortar at 28 days is confirmed to be 83% as compared with hardened OPC mortar.

소량의 $SiO_2$가 첨가된 Calcium Aluminate 유리의 특성 및 구조 (Characteristics and Structural Evolution of Low-Silica Calcium Aluminate Glasses)

  • 심성헌;허종;김유성
    • 한국세라믹학회지
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    • 제31권7호
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    • pp.695-702
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    • 1994
  • Current study was undertaken to explain the structural evolution and corresponding changes in the properties of calcium aluminate glasses with the variation of SiO2 doping concentration. Calcium aluminate glasses in the compositional ranges of (100-x)(0.6CaO+0.4Al2O3)+xSiO2(where x=0~60) were fabricated. DTA analysis confirmed an anomalous behavior in glass transition temperature (Tg) with the maximum of 887$^{\circ}C$ and minimum of 859$^{\circ}C$ when x=5 and 50, respectively. densities and refractive indices monotonically decreased with increasing SiO2 content and IR transmitting cutoff shifted to shorter wavelength side when the amount of added SiO2 exceeded 5 mole%. IR fundamental vibration absorption peaks showed the change that NBOs were inclined to SiO4 tetrahedron in the low-silica region and NBO per SiO4 tetrahedra changed from 2 to 0 with increasing silica content. Based on the analysis of IR fundamental vibration absorption peaks, the model of the structural change can be proposed in three step: 1) SiO4 scavenged the NBOs located at AlO4-tetrahedra, which resulted in the increased of Tg values, 2) NBOs located in the main network again with a decrease in Tg, and 3) dominated by the decrease in the relative amount of NBOs in the glass system, where Tg re-increased.

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OPC의 분말도 및 SO3 함량이 시멘트 광물계 급결제를 사용한 숏크리트 결합재 물성에 미치는 영향 (The Effect of Blaine and SO3 Contents of OPC on Shotcrete Binder with Calcium Aluminate Accelerator)

  • 강봉희;김규용;최재원;구경모;황봉춘
    • 한국구조물진단유지관리공학회 논문집
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    • 제24권2호
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    • pp.78-85
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    • 2020
  • 숏크리트용 콘크리트는 일반적으로 1종 보통 포틀랜드시멘트(이하 OPC)를 100% 사용한 레미콘 제품에 현장에서 별도로 숏크리트용 급결제를 약 5% 혼합하는 방식으로 사용된다. 본 연구에서는 국내에서 사용률이 높은 시멘트 광물계 급결제(calcium aluminate)를 사용한 숏크리트용 결합재로서 OPC의 분말도 및 SO3 함량이 모르타르 관입저항 및 압축강도, 페이스트 수화물 및 공극구조에 미치는 영향을 시험 및 분석하여 재령별 수화물의 생성량과 공극구조가 숏크리트의 모르타르 성능에 미치는 영향을 파악하였다. 향후 숏크리트용 결합재로서 최적화된 OPC를 제조하는데 활용할 수 있을 것으로 기대된다.

고로슬래그 분말 및 석회석 분말이 시멘트 광물계 급결제를 사용한 숏크리트 결합재 물성에 미치는 영향 (The Effect of Addition of Blast-furnace Slag Powder and Limestone powder on Shotcrete Binder with Calcium Aluminate Accelerator)

  • 강봉희;김규용;최재원;구경모;황봉춘
    • 한국구조물진단유지관리공학회 논문집
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    • 제24권2호
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    • pp.86-93
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    • 2020
  • 숏크리트용 콘크리트는 일반적으로 1종 보통 포틀랜드시멘트(이하 OPC)를 100% 사용한 레미콘 제품에 현장에서 별도로 숏크리트용 급결제를 약 5% 혼합하는 방식으로 사용된다. 본 연구에서는 국내에서 사용률이 높은 시멘트 광물계 급결제(calcium aluminate)를 사용한 숏크리트용 결합재로서 기존 OPC에 슬래그분말(이하 SP), 석회석분말(이하 LSP)를 첨가하여 혼합시멘트를 사용할 때의 응결 및 압축강도, 페이스트 수화물 및 공극구조에 미치는 영향을 시험 및 분석하여 재령별 수화물의 생성량과 공극구조가 숏크리트의 모르타르 성능에 미치는 영향을 파악하였다. 향후 숏크리트용 결합재로서 최적화된 결합재를 제조하는데 활용할 수 있을 것으로 기대된다.

칼슘알루미네이트계 급결재와 증점제를 사용한 그라우트의 특성 및 환경영향 평가 (Properties and Environmental Effects Estimation of Grout Using Set Accelerating Agent Made From Calcium Aluminate and Viscosity Agent)

  • 허형석;이성태;노재호
    • 한국구조물진단유지관리공학회 논문집
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    • 제16권4호
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    • pp.122-129
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    • 2012
  • 이 연구에서는 시멘트계 광물로 제조된 그라우트의 사용에 의해 발생되는 환경문제인 pH의 증가와 중금속오염을 MC계와 킬레이트고분자를 이용하여 평가하고자 하였다. 그라우트 재료로 보통포틀랜드시멘트와 슬래그시멘트를 사용하였고 급결재로 칼슘알루미네이트계 급결성재료의 혼합물을 사용하였으며, 중금속과 pH의 발생을 방지하기 위해 증점제를 사용하였다. 측정결과, 킬레이트고분자를 사용할 경우에 그라우트에 의한 pH의 증가가 최소화되었으며 중금속($Cr^{6+}$)은 용출되지 않았다. 그 이외의 경우에는 pH의 증가와 중금속 용출이 뚜렷이 증가하였다. 또한, 재령에 따른 중금속 발생량은 용출시험 1일에서 전 용출량의 약 97% 이상이 용출되었고 이후는 추가 발생되지 않는 것으로 나타났다. 이 연구의 결과로부터 pH의 증가와 $Cr^{6+}$과 같은 중금속의 용출을 제어하기 위해서 BSC와 킬레이트고분자를 사용하는 것이 아주 유용함을 알 수 있었다.